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The socioeconomic development of any region requires electricity for operating the various sectors of the economy. Sometimes energy is scarce, not only because of the lack of energy resources, but also because energy policy is inadequate or non-existent. This paper examines the situation in the province of Namibe, Angola, characterising the energy sector, and proposing an energy mix for the security of electricity supply, environmental protection and sustainable economic development. Using the Long-range Energy Alternative and Planning System, energy scenarios were simulated and the greenhouse gas emissions (GHGs) for the period 2014 -2040 calculated and analysed. The most sustainable scenario, in terms of energy mix diversification and GHG reduction, as well as the least costly (considering electricity production and carbon costs), has an increase of hydro capacity and the insertion of wind, solar photovoltaic, thermoelectric sources and natural gas. Given the intermittency of photovoltaic and wind systems, natural gas appears in this scenario as a way to avoid interruptions in the electricity supply. This scenario is the one with the largest production reserve margin of 24.47 %, and emissions are avoided at 386 550 tCO2eq compared to the base scenario in 2040. Energy policymakers can take this scenario as a model to assist in making decisions on how power capacities can be installed over the planned time for the desired energy output. [ABSTRACT FROM AUTHOR]