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The spin character of the splitting of the Shockley surface state on Au(111) is directly verified by measurements of the in-plane and out-of-plane spin polarizations in angle-resolved photoemission spectra. The two parabolic sub-bands that are momentum-shifted with respect to each other, reveal a distinct, opposite spin polarization that within the errors lies in the surface plane. The measured in-plane orientation of the spin vectors is consistent with the simple spin structure expected from a nearly-free-electron model, where the polarization axis is tangential to the Fermi surface of the surface state. [Copyright &y& Elsevier]

Photoelectron diffraction (PED) effects in magnetic solids are described within a one-electron non-relativistic model. The theory presented permits a straightforward calculation of spin-resolved PED patterns, whereby different spin arrangements in a magnetic solid may be considered. Both spin–orbit interaction and exchange interaction with the spin-polarized valence band have been taken into account in the description of the initial core state. The multiple scattering of the excited photoelectron wave is treated within a multiple-scattering cluster model. The theory may be applied to explain PED effects in magnetic solids in comparison to the nonmagnetic case. [Copyright &y& Elsevier]