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[Display omitted] • Obtaining CuCo 2 O 4 /CF that can realize the dual function of catalytic and cathodic. • Different morphological features and hydrophilicity were exhibited at different hydrothermal temperatures. • Cu(II)/Cu(I) and Co(III)/Co(II) reactive centers provide excellent catalytic performance. Cobalt-based oxide CuCo 2 O 4 -loaded CuCo 2 O 4 /carbon felt (CF) composite cathodes were synthesized by hydrothermal deposition of a precursor of Cu/Fe oxides on CF followed by roasting in air. The material serves both catalytic and cathodic dual functions in the heterogeneous electro-Fenton (EF) process. Through XRD (X-ray diffraction), FTIR (Fourier transform infrared spectroscopy), XPS (X-ray photoelectron spectroscopy), SEM (scanning electron microscope), and catalytic experiments, it was concluded that CuCo 2 O 4 loading was successful and the highest hydrophilic 180-CuCo 2 O 4 /CF was obtained by varying the hydrothermal temperature without destroying the original structure. 180-CuCo 2 O 4 /CF accomplished 98.03 % degradation in 60 min, and it was found to maintain high degradation capacity in the pH 3 ∼ 9 range in experiments where the experimental parameters were varied. Compared to monometallic oxides, Cu and Co dual active centers are integrated in CuCo 2 O 4 , giving it diverse redox properties and oxidation states. As a result, the CuCo 2 O 4 /CF material can realize the dual function of catalytic and cathodic, which provides a new development direction in practical wastewater treatment. [ABSTRACT FROM AUTHOR]