1. Unlocking the potential of lignin: Towards a sustainable solution for tire rubber compound reinforcement.
- Author
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Hait, Sakrit, Kumar, Labeesh, Ijaradar, Jyotirmaya, Ghosh, Anik Kumar, De, Debapriya, Chanda, Jagannath, Ghosh, Prasenjit, Das Gupta, Saikat, Mukhopadhyay, Rabindra, Wießner, Sven, Heinrich, Gert, and Das, Amit
- Subjects
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STRAINS & stresses (Mechanics) , *COUPLING agents (Chemistry) , *SUSTAINABLE engineering , *AUTOMOBILE tires , *REINFORCEMENT of rubber , *LIGNINS , *RUBBER - Abstract
This study tackles the persistent challenge of producing highly reinforced lignin-rubber composites, emphasizing the transformation of agro-industrial residues into value-added products. To address this challenge, we introduce a novel approach termed "in-situ surface modification utilizing a thermo-chemo-mechanical approach" which incorporates the utilization of biomass-derived kraft lignin and a thermally stable organofunctional surface modifier, specifically (3-aminopropyl) triethoxysilane. The resulting material exhibits unprecedented tensile strength (∼15 MPa) along with ∼300 % elongation at break, while typical gum rubber offers 1–2 MPa tensile strength. Additionally, for the other tensile properties like 100 %, and 200 % tensile modulus, the improvement is 7-fold (∼5.6 MPa) and 10-fold (∼11.3 MPa), respectively. Furthermore, this composite presents a higher degree of reinforcement than a passenger car radial (PCR) tire model compound (tensile strength ∼14.5 MPa, 100 % tensile modulus ∼2.2 MPa, and 200 % tensile modulus ∼5.6 MPa) comprised of silica and polysulfide-based coupling agent, with exactly a similar loading of filler. The dynamic mechanical and stress relaxation behavior of the composites are critically discussed concerning the dispersion of the lignin in the sSBR/BR rubber matrix. The morphological orientation and involved chemical interaction in the presence of a surface modifier are also studied in detail. Tear fatigue analysis using pure shear specimens indicates superior fracture toughness at a lower tearing energy regime compared to silica-filled PCR tire compounds. Overall, this study showcases the potential of lignin-reinforced elastomers, offering a promising route for sustainable engineering materials and commercial viability. [Display omitted] • High mechanical performance of Lignin-rubber composites by thermo-chemo-mechanical mixing. • Better dispersion of the lignin particle in butadiene rubber at higher temperature. • Composite shows ∼15 MPa of tensile strength, like Passenger Car Radial tire compound. • Excellent fracture toughness at low tearing energy regime. • Lignin, an alternative to conventional fillers, especially for the tire applications. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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