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Chrome tanning system has been faced with great challenges from potential environmental and human health risks and environmental pressures in the leather industry. The development of chrome-free tanning system towards eco-friendly leather manufacture is the main strategy to solve them from the source. However, appropriate assessments of the physical and environmental properties of a new tanning process remain challenging. In this work, we compared the physical performances and environmental impacts of two nanosilicates-based chrome-free combination tanning systems with conventional chrome tanning system in practical fur leather processing. The objective of this study was to obtain comprehensive insights into the nanosilicates-based chrome-free combination tanning systems from both technical and environmental perspectives. All fur leathers possessed similar and integrated fleece structures, ensuring high glossy and flexibility of final fur leather articles. Tara tannin-Zeolite (TA-ZE) combination tanning system was chosen as the most promising one for manufacturing garment leather articles. The resultant leathers were endowed with favorable physical properties (e.g., tear strength of 15.9 N, elongation at break of 42.3%, shrinkage temperature of 98.6 °C) and no restricted Cr(VI) and free formaldehyde. Life cycle assessment (LCA) results revealed that the TA-ZE combination tanning system exhibited better environmental impacts than other options. The main novelties included the contribution to avoiding the use of high-risk tanning chemicals by presenting a better technical and environmental alternative in the leather processing and the application of LCA to environmentally evaluate the leather processing. We envision these findings can offer comprehensive insights into emergent chrome-free combination tanning systems for designing and rationalizing feasible fur leather processing towards eco-friendly leather manufacture. [Display omitted] • Physical performances and environmental impacts of fur leather manufacture were compared. • TA-ZE tanning system produced the fur leathers with more favorable technical properties. • TA-ZE combination tanning system exhibited better environmental results. • LCA was needed to assure that chrome free tanning alternatives were environmentally better. [ABSTRACT FROM AUTHOR]

This paper investigates the impacts of weather shocks on athlete performance, focusing on soccer players in the Chinese Soccer Super League over three consecutive seasons from 2014 to 2016. Utilizing daily meteorological data, we construct the temperature and precipitation bin variables to explore the marginal effects on the physical and cognitive performance of soccer players. The empirical findings document a sizeable impact of high temperatures and heavy precipitation on players' performance indicators, including physical performance and cognitive performance. Specifically, relative to conditions with temperatures below 15 °C, the total running distances, the number of passes, and the number of fouls for soccer players significantly decrease by 7.6%, 6.0%, and 23.1%, respectively, when temperatures exceed 30 °C. The results for precipitation bins show that relative to conditions with precipitation below 0.1 mm, the total running distances, the number of passes, and the number of fouls for soccer players significantly decrease by 1.2%, 8.2%, and 4.7%, respectively, when precipitation exceeds 50 mm. Moreover, the heterogeneity analysis reveals that the negative effects of high temperatures and heavy precipitation are more pronounced and significant for older players, for matches performed away from home, and for matches performed in areas with higher temperatures or more precipitation. Evidence of player adaptations suggests that players from regions with higher temperatures or more precipitation perform better in terms of physical and cognitive abilities when playing in areas with lower temperatures or less precipitation compared to players from regions with lower temperatures or less precipitation when they compete in areas with higher temperatures or more precipitation. Finally, policy suggestions are proposed to mitigate the impact of weather shocks on soccer players and to promote the sustainability of the soccer industry. [ABSTRACT FROM AUTHOR]

The concrete industry has been responsible for significant depletion of natural resources and at end-of-life significantly contributes to global waste production. To date experimental studies have typically explored the use of single generation recycled aggregates (RA) in concrete production, however, to move towards a circular economy the concrete industry needs to embrace the use of multi-generation recycled aggregate concrete (MGRAC). In this paper the physical and mechanical performance of 45 concrete mix designs over 4 generations of concrete production is explored. At each generation a series of mixes are conducted at various water to cement ratios (w/c) and with a range of blends of virgin and recycled aggregates from differing generations to capture the impact on material properties. The physical and mechanical properties are quantified for both the aggregates and the concretes at each generation. The results show that the physical properties and some mechanical properties of the concrete and RA decrease with respect to virgin aggregate concrete and virgin aggregate but, implementing a 50% replacement of VA can slow down intergenerational degradation. Furthermore, the blending RA from a range of generations can also slow intergenerational degradation but to a lesser extent. Effective aggregate properties are determined, and direct relationships confirmed indicating potential for informed mix design based on an understanding of a few simple aggregate properties. [ABSTRACT FROM AUTHOR]

To dispose of the construction spoil (CS) sustainably, using alkali-activated slag (AAS) to solidify CS and prepare solidified construction spoil (SCS) as building materials has great potential. The effects of alkali concentration (Na 2 O%), modulus, binder-soil ratio (B/S), liquid-solid ratio, and sand content on the fluidity, compressive strength, water resistance, and carbon emission factor of SCS were studied via orthogonal experimental methods. It was found that the increasing fluidity was mainly affected by the increasing sand content and liquid-solid ratio, and the increasing compressive strength, water resistance, and carbon emission factor were mainly affected by the increasing Na 2 O% and B/S. Compared with cement, using AAS can reach higher fluidity, compressive strength, and water resistance, and lower carbon emissions of SCS. Finally, considering the influence of sand content on the properties of SCS, the sand washing decisions during the disposal process were reevaluated via life cycle assessment (LCA). Compared to transportation and landfill, preparing SCS with or without washing sand can significantly reduce equivalent carbon emissions, and the latter can result in lower equivalent carbon emissions and better working and physical performance of SCS than the former. From practical engineering considerations, it was suggested that the CS with low sand content doesn't need to wash sand. [ABSTRACT FROM AUTHOR]