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Ternary liquid-liquid equilibria were experimentally determined for eight systems composed of an ionic liquid + n -hexane + an organic compound implicated in the racemic resolution of rac -2-pentanol ( rac -2-pentanol, vinyl butyrate, rac -2-pentyl butyrate or butyric acid) at a temperature of 303.15 K and pressure of 0.1 MPa. The following ionic liquids were used: 1-ethyl-3-methylimidazolium bis{(trifluoromethyl)sulfonyl}imide, [emim + ][NTf 2 − ], and 1-hexyl-3-methylimidazolium bis{(trifluoromethyl)sulfonyl}imide, [hmim + ][NTf 2 − ]. The binodal curves and the tie line of the conjugate phases compositions were determined through measurement of the refractive index for the ionic liquid-rich phase and by using gas chromatography for the hexane-rich phase, enabling their potential to be assessed for selective extraction of organic compounds from a mixture of ionic liquid reaction media for the resolution of rac -2-pentanol. Liquid phase activity coefficients were calculated using the Non-Random Two-Liquid equation and the tie line theoretical data calculated from the model are in good agreement with the experimental data. As yet, the literature contains no data for the systems studied in this paper. [ABSTRACT FROM AUTHOR]

This paper reports experimental values of dynamic viscosity for four binary systems of 1-ethyl-3-methylimidazolium tetrafluoroborate, [Emim][BF4], with dimethyl sulfoxide (DMSO), acetonitrile (ACN), ethylene glycol (EG) and 1,4-dioxane over the temperature ranges from 293.15 K to 353.15 K at p = 0.1 MPa. All binary mixtures were completely miscible over the entire range of mole fraction, except the system with 1,4-dioxane. The viscosity results have been correlated by the one parameter Grunberg–Nissan and Fang and He equations and the two-parameter McAllister, Eyring-UNIQUAC, Eyring-NRTL and Eyring-Wilson models and the results were compared. Additionally, the viscosity deviations, Δ η , and the excess Gibbs energy of activation for viscous flow, G ∗ E , were calculated and fitted to the Redlich–Kister equation. The results show that all Δ η values are negative over the whole composition range and the G ∗ E values are positive, except for the system with EG. The results of the excess functions are discussed in terms of molecular interactions. [ABSTRACT FROM AUTHOR]

In this paper, a densimeter based on vibrating tube principle is used to determine experimentally the density of 1-butyl-2,3-dimethylimidazolium tris(pentafluoroethyl)trifluorophosphate and 1-butyl-2,3-dimethylimidazolium bis(trifluoromethylsulfonyl)imide at temperatures between (278.15 and 398.15) K and at pressures up to 120 MPa. The apparatus was calibrated by using water, vacuum and bromobenzene. The Tammann–Tait equation of state was used to correlate ( p , T , ρ ) results with standard deviations around 2 · 10 −4 g · cm −3 . Other volumetric properties, such as isothermal compressibility and isobaric thermal expansivity, were obtained from this equation. For each ionic liquid, the α p isotherms present a crossing point within the experimental pressure range. Besides, the effect that the C2-methylation in the imidazolium cation provokes on density values is analyzed. The prediction ability of the group contribution methods of Gardas and Coutinho and Jacquemin et al. were tested with the experimental densities. [ABSTRACT FROM AUTHOR]