1. Pump–probe dissociative ionization of NaI and CsI aggregated with CH[sub 3]CN.
- Author
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Stibbe, Darian T., Charron, Eric, Brenner, Valerie, Millie´, Philippe, and Suzor-Weiner, Annick
- Subjects
IONIZATION (Atomic physics) ,IODINE compounds ,ACETONITRILE ,ULTRASHORT laser pulses - Abstract
Recent experiments have investigated the dissociative ionization of NaI and CsI, each aggregated with a molecule of acetonitrile CH[sub 3]CN, using two femtosecond laser pulses. The first, the pump pulse, excites the NaI or CsI diatom to a dissociative state. The second, the probe pulse, then ionizes the sodium or cesium atom after a variable delay time, and the resulting ion is detected. In the case of NaI, the ion signal is characterized by a single maximum. For CsI, however, an oscillatory signal is observed. By performing two-dimensional wave packet propagations, we are able to reproduce this behavior, which can be explained using simple physical arguments. [ABSTRACT FROM AUTHOR]
- Published
- 2002
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