1. Size effects in the formation of an uncompensated ferromagnetic moment in NiO nanoparticles
- Author
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Mikhail N. Volochaev, S. I. Popkov, D. A. Balaev, Oleg N. Martyanov, V. L. Kirillov, A. A. Krasikov, and A. A. Dubrovskiy
- Subjects
010302 applied physics ,Materials science ,Condensed matter physics ,Spins ,Non-blocking I/O ,General Physics and Astronomy ,Nanoparticle ,02 engineering and technology ,021001 nanoscience & nanotechnology ,01 natural sciences ,Magnetic field ,Condensed Matter::Materials Science ,Magnetization ,Ferromagnetism ,0103 physical sciences ,Antiferromagnetism ,Condensed Matter::Strongly Correlated Electrons ,Particle size ,0210 nano-technology - Abstract
The magnetic properties of samples of NiO nanoparticles with average sizes of 23, 8.5, and 4.5 nm were investigated. Using the magnetization curves measured in strong (up to 250 kOe) pulsed magnetic fields, the contributions of the free spin and ferromagnetic subsystems were extracted. It has been found that the ferromagnetic contribution increases with a decrease in the nanoparticle size and is proportional to the fraction of uncompensated exchange-coupled spins. It is demonstrated that the uncompensated spins form in the antiferromagnetic NiO oxide due to an increase in the fraction of surface atoms in the nanoparticles with decreasing particle size and defects in the bulk of particles.
- Published
- 2019
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