1. Chemical interdiffusion in binary systems; interface barriers and phase competition.
- Author
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Danielewski, Marek, Wierzba, Bartek, Gusak, Andriy, Pawełkiewicz, M., and Janczak-Rusch, J.
- Subjects
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DIFFUSION , *BINARY number system , *LATTICE theory , *THERMAL diffusivity , *EQUILIBRIUM , *MOLECULAR volume , *STOICHIOMETRY - Abstract
The problem of simultaneous growth and competition of intermediate phases during reactive diffusion is formulated and solved. In this paper, we compare existing models of steady state reaction diffusion and introduce the new one basing on the bi-velocity method. We extend old problem and propose method based on material (lattice) fixed frame of reference. It allows computing the material velocity in the reacting system in which reactions at several moving interfaces occur. All reactions lead to the lattice shift due to the difference of intrinsic diffusivities and different molar volumes. The following peculiarities are taken into account: (1) the deviation from local equilibrium at all interfaces; (2) the mobilities of the components in the bulk and interphase zone; and (3) the molar volumes of the components. We show the kinetic of the reactions, the non parabolic regime, the multiphase scale growth and present the practical application of the method. [ABSTRACT FROM AUTHOR]
- Published
- 2011
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