1. Superconductivity up to 10 K in the Sr(Pd1-xPtx)2Ge2 layer system.
- Author
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Chen, I. A., Huang, C. H., Chen, C. W., You, Y. B., Tai, M. F., Ku, H. C., and Hsu, Y. Y.
- Subjects
SUPERCONDUCTIVITY ,ELECTRIC conductivity research ,LATTICE dynamics ,SUPERCONDUCTORS ,ELECTRICAL conductors - Abstract
Metastable filamentary superconductivity with Tc = 10.2 K was observed in SrPt2Ge2. This is the highest Tc reported outside the iron-based 122-layer compounds. The stable phase for this compound is a non-superconducting monoclinic LaPt2Ge2-type structure with lattice parameters a = 0.4401(4) nm, b = 0.4435(4) nm, c = 0.9764(10) nm, β = 90.5°-90°. Weak diamagnetic shielding signal indicates that superconductivity is not from the major monoclinic phase, but from the minor BaFe2As2-type body-center-tetragonal (122-bct) phase with a=0.44 nm, c=0.98 nm,β=90°. Investigation on the pseudoternary system Sr(Pd1-xPtx)2Ge2 suggests that the stable bct to monoclinic structure phase transition occurs near x = 0.15. For x<0.15 with bct phase, bulk Tc increases from 3.2 K for SrPd2Ge2 to 3.6 K for SrPd
1.8 Pt0.2 Ge2 . For x>0.15 with metastable filamentary bct phase, Tc increases from 7.5 K for x = 0.5 to 9.2 K for x = 0.7 and reaches a Tc maximum of 10.2 K for SrPt2Ge2. High Tc is due to a strong quasi-2D Pt-Ge-Pt 5dxz,yz -4p-5dxz,yz hybridization in the Pt-Ge layer with squeezed-along-c-axis PtGe4 tetrahedral crystal field and Pt-5d8 spin-orbital interaction in the metastable filamentary bct phase and is another example of multi-band (dxz /dyz /dxy ) non-conventional s-wave superconductor. [ABSTRACT FROM AUTHOR]- Published
- 2013
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