7,647 results
Search Results
2. Reactive molecular dynamics research on influences of water on aging characteristics of PMIA insulation paper
- Author
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Fei Yin, Lihan Wang, Yin Shen, and Chao Tang
- Subjects
010302 applied physics ,Materials science ,Moisture ,Thermal decomposition ,General Physics and Astronomy ,02 engineering and technology ,Activation energy ,021001 nanoscience & nanotechnology ,01 natural sciences ,Decomposition ,Molecular dynamics ,Chemical engineering ,Insulation system ,0103 physical sciences ,Molecule ,Fiber ,0210 nano-technology - Abstract
The diffusion of moisture in the meta-aramid fiber (PMIA) oil-paper insulation system and the thermal decomposition of PMIA insulation paper in different moisture contents were studied via molecular dynamics simulations. The results showed that the PMIA insulation paper had a stronger ability to absorb water molecules than the insulating oil; therefore, water molecules in the insulating oil diffuse to the insulation paper, which further affects the thermal decomposition of the PMIA insulation paper. The activation energy of the water-bearing composite model was 129.96 kJ/mol, which was 5.5% lower than that of the pure PMIA (137.61 kJ/mol). It indicated that moisture could promote PMIA decomposition. The micromechanism of the enhanced thermal decomposition of PMIA with moisture contents could be described as follows: The O–H bond of the water can easily break to generate H atoms and hydroxyl radicals (•OH). The strong activity of H atoms allows it to easily combine with the ammonia base at the end of PMIA to generate NH3. Additionally, the free •OH radical can easily combine with the amido and carbonyl bonds at two ends of PMIA, undergo an oxidation reaction, and generate an oxhydryl. Therefore, it can reduce the chemical stability of the PMIA chain and further drive thermal decomposition. Statistical data on fragments generated by the thermal decomposition of the water-bearing PMIA composite system show that the main products include H2, C/H/O-containing molecules, hydrocarbon molecules, N-bearing molecules, and free radicals.
- Published
- 2020
3. Fabrication and characterization of graphene-based paper for heat spreader applications
- Author
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Ali A. Muhsan and Khalid Lafdi
- Subjects
010302 applied physics ,Materials science ,F300 ,Graphene ,F200 ,General Physics and Astronomy ,H800 ,02 engineering and technology ,Chemical vapor deposition ,021001 nanoscience & nanotechnology ,Hot pressing ,01 natural sciences ,Evaporation (deposition) ,law.invention ,Thermal conductivity measurement ,Thermal conductivity ,law ,0103 physical sciences ,Heat spreader ,Thin film ,Composite material ,0210 nano-technology - Abstract
In this work, in-plane thermal conductivity measurement was carried out on graphene-based papers. Graphene-based papers were fabricated using various processing techniques such as chemical vapor deposition (CVD), hot pressing of graphene slurry, and evaporation induced self-assembly. The prepared materials were characterized using scanning electron microscopy, Raman spectroscopy, and X-ray diffraction. In-plane thermal conductivity measurement was performed via a steady state thin film thermal conductivity apparatus. The in-plane thermal conductivity measurements show that the CVD based sample has the highest thermal conductivity. COMSOL Multiphysics was used to simulate the in-plane thermal conductivity of graphene-based papers.
- Published
- 2019
4. Model for electrostatic imaging of forensin evidence via discharge through Mylar-paper path
- Author
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Seward, George H.
- Subjects
Electrostatics -- Research ,Electric fields -- Research ,Semiconductor films -- Research ,Perturbation (Quantum dynamics) -- Research - Abstract
A study was conducted to describe a framework that can be utilized to determine the physics of electrostatic detection equipment. Indented writing, erasure and fingerprints were considered as samples of commonly found perturbations in paper specimens. Results indicated that electric perturbations influenced the magnitude of the electric field in Mylar films. Findings also showed that fingerprint images are independent of specimen orientation.
- Published
- 1998
5. Improvements of mechanical properties of multilayer open-hole graphene papers
- Author
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Junhua Zhao, Yeyuan Li, Chunhua Zhu, Yuxuan Xia, and Ning Wei
- Subjects
010302 applied physics ,Materials science ,Nanocomposite ,Graphene ,General Physics and Astronomy ,02 engineering and technology ,Edge (geometry) ,021001 nanoscience & nanotechnology ,01 natural sciences ,law.invention ,Molecular dynamics ,law ,Covalent bond ,0103 physical sciences ,Ultimate tensile strength ,Shear strength ,Composite material ,0210 nano-technology ,Stress concentration - Abstract
Holes and defects can greatly reduce the mechanical properties of multilayer graphene sheets under different loading conditions due to the stress concentration near the hole edge in each in-plane sheet and the lack of interlayer carbon–carbon bonds between the layers. Here, we report a novel design of multilayer open-hole graphene papers (MLGPs) formed through interlayer covalent bonding at the hole edges of multilayer open-hole graphene sheets (MLGSs) under high temperature using molecular dynamics (MD) simulations. Our MD results show that the hybrid sp2–sp3 interlayer bonds of MLGPs can significantly improve their both tensile strength and interlayer shear strength. The tensile strength and interlayer shear strength of MLGPs increase by around 20% and 3 times by comparison with those of MLGSs with the same number of layers, respectively, which mainly depends on the uniformity of their interlayer bond distribution. This study can provide an effective way to improve the mechanical performances of multilayer graphene sheets with flaws and also offer corresponding guidance for the design of MLGS-based nanocomposites.
- Published
- 2019
6. X-ray microtomography and laser ablation in the analysis of ink distribution in coated paper
- Author
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Heikki Häkkänen, Jussi Timonen, Kaj Backfolk, Petri Sirviö, Markko Myllys, and Jouko Korppi-Tommola
- Subjects
Topography ,Coated paper ,Laser ablation ,X-ray microtomography ,Materials science ,ta114 ,Inkwell ,business.industry ,medicine.medical_treatment ,General Physics and Astronomy ,Surface structure ,Laser ,Ablation ,Image analysis ,law.invention ,Optics ,law ,medicine ,Profilometer ,ta216 ,business ,Tomography ,Image resolution - Abstract
A novel method was developed for studying the ink-paper interface and the structural variations of a deposited layer of ink. Combining high-resolution x-ray tomography with laser ablation, the depth profile of ink (toner), i.e., its varying thickness, could be determined in a paper substrate. X-ray tomography was used to produce the 3D structure of paper with about 1 μm spatial resolution. Laser ablation combined with optical imaging was used to produce the 3D structure of the printed layer of ink on top of that paper with about 70 nm depth resolution. Ablation depth was calibrated with an optical profilometer. It can be concluded that a toner layer on a light-weight-coated paper substrate was strongly perturbed by protruding fibers of the base paper. Such fibers together with the surface topography of the base paper seem to be the major factors that control the leveling of toner and its penetration into a thinly coated paper substrate.
- Published
- 2015
7. Electrically and magnetically dual-driven Janus particles for handwriting-enabled electronic paper
- Author
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H. Hirama, Toru Torii, and Yusuke Komazaki
- Subjects
Materials science ,law ,Magnet ,Microfluidics ,General Physics and Astronomy ,Magnetic nanoparticles ,Nanoparticle ,Nanotechnology ,Janus particles ,Electronic paper ,law.invention ,Voltage ,Superparamagnetism - Abstract
In this work, we describe the synthesis of novel electrically and magnetically dual-driven Janus particles for a handwriting-enabled twisting ball display via the microfluidic technique. One hemisphere of the Janus particles contains a charge control agent, which allows the display color to be controlled by applying a voltage and superparamagnetic nanoparticles, allows handwriting by applying a magnetic field to the display. We fabricated a twisting ball display utilizing these Janus particles and tested the electric color control and handwriting using a magnet. As a result, the display was capable of permitting handwriting with a small magnet in addition to conventional color control using an applied voltage (80 V). Handwriting performance was improved by increasing the concentration of superparamagnetic nanoparticles and was determined to be possible even when 80 V was applied across the electrodes for 4 wt. % superparamagnetic nanoparticles in one hemisphere. This improvement was impossible when the concentration was reduced to 2 wt. % superparamagnetic nanoparticles. The technology presented in our work can be applied to low-cost, lightweight, highly visible, and energy-saving electronic message boards and large whiteboards because the large-size display can be fabricated easily due to its simple structure.
- Published
- 2015
8. Advanced mechanical properties of graphene paper
- Author
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Bei Wang, Xiaoping Shen, Guoxiu Wang, and Ali Reza Ranjbartoreh
- Subjects
Materials science ,Carbon steel ,Graphene ,General Physics and Astronomy ,Young's modulus ,engineering.material ,law.invention ,symbols.namesake ,Flexural strength ,law ,Ultimate tensile strength ,symbols ,engineering ,Graphite ,Composite material ,Applied Physics ,Tensile testing ,Graphene oxide paper - Abstract
Graphene paper (GP) has been prepared by flow-directed assembly of graphene nanosheets. The mechanical properties of as-prepared GPs were investigated by tensile, indentation, and bending tests. Heat treated GPs demonstrate superior hardness, ten times that of synthetic graphite, and two times that of carbon steel; besides, their yielding strength is significantly higher than that of carbon steel. GPs show extremely high modulus of elasticity during bending test; in the range of a few terapascal. The high strength and stiffness of GP is ascribed to the interlocking-tile microstructure of individual graphene nanosheets in the paper. These outstanding mechanical properties of GPs could lead to a wide range of engineering applications. © 2011 American Institute of Physics.
- Published
- 2011
9. Model for electrostatic imaging of forensic evidence via discharge through Mylar-paper path
- Author
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George H. Seward
- Subjects
Optics ,business.industry ,Chemistry ,Analytical chemistry ,General Physics and Astronomy ,Surface charge ,business ,Electrostatics ,Poole–Frenkel effect ,Surface states - Abstract
A model for the electrostatic detection apparatus is presented. An electrostatic potential models the effects of indented writing, erasures, and fingerprints. Poole–Frenkel emission from Mylar surface states is employed to model the discharge process. Experimental evidence is provided which supports the model. The role of the Mylar sheet is identified. The electric effect of indented writing is identified as a surface charge created by paper-to-paper friction.
- Published
- 1998
10. Paper-based ultracapacitors with carbon nanotubes-graphene composites
- Author
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Alexey Shashurin, Cameron Brand, Jian Li, Mark Reeves, Michael Keidar, Xiaoqian Cheng, and Jianwei Sun
- Subjects
Supercapacitor ,Nanocomposite ,Materials science ,Scanning electron microscope ,Graphene ,General Physics and Astronomy ,Carbon nanotube ,law.invention ,Electric arc ,symbols.namesake ,law ,symbols ,Composite material ,Raman spectroscopy ,Sheet resistance - Abstract
In this paper, a paper-based ultracapacitors were fabricated by the rod-rolling method with the ink of carbon nanomaterials, which were synthesized by arc discharge under various magnetic conditions. Composites of carbon nanostructures, including high-purity single-walled carbon nanotubes (SWCNTs) and graphene flakes were synthesized simultaneously in a magnetically enhanced arc. These two nanostructures have promising electrical properties and synergistic effects in the application of ultracapacitors. Scanning electron microscope, transmission electron microscope, and Raman spectroscopy were employed to characterize the properties of carbon nanostructures and their thin films. The sheet resistance of the SWCNT and composite thin films was also evaluated by four-point probe from room temperature to the cryogenic temperature as low as 90 K. In addition, measurements of cyclic voltammetery and galvanostatic charging/discharging showed the ultracapacitor based on composites possessed a superior specific capacitance of up to 100 F/g, which is around three times higher than the ultracapacitor entirely fabricated with SWCNT.
- Published
- 2014
11. Biocellulose-based flexible magnetic paper
- Author
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Sjl Ribeiro, Eloiza da Silva Nunes, Marcelo Nalin, M. Jafellici, Rodrigo Fernando Costa Marques, Wesley Renato Viali, Junkal Gutierrez, Hernane da Silva Barud, and Agnieszka Tercjak
- Subjects
Nanocomposite ,Materials science ,technology, industry, and agriculture ,General Physics and Astronomy ,Nanoparticle ,Nanotechnology ,Magnetization ,chemistry.chemical_compound ,Membrane ,chemistry ,Chemical engineering ,Bacterial cellulose ,Permeability (electromagnetism) ,Magnetic nanoparticles ,Superparamagnetism - Abstract
Biocellulose or bacterial cellulose (BC) is a biocompatible (nano) material produced with a three-dimensional network structure composed of microfibrils having nanometric diameters obtained by the Gluconacetobacter xylinus bacteria. BC membranes present relatively high porosity, allowing the incorporation or synthesis in situ of inorganic nanoparticles for multifunctional applications and have been used as flexible membranes for incorporation of magnetic nanocomposite. In this work, highly stable superparamagnetic iron oxide nanoparticles (SPION), functionalized with polyethylene glycol (PEG), with an average diameter of 5 nm and a saturation magnetization of 41 emu/g at 300 K were prepared. PEG-Fe2O3 hybrid was dispersed by mixing a pristine BC membrane in a stable aqueous dispersion of PEG-SPION. The PEG chains at PEG-SPION's surface provide a good permeability and strong affinity between the BC chains and SPION through hydrogen-bonding interactions. PEG-SPION also allow the incorporation of higher content of nanoparticles without compromising the mechanical properties of the nanocomposite. Structural and magnetic properties of the composite have been characterized by XRD, SEM, energy-dispersive X-ray spectroscopy (EDX), magnetization, Raman spectroscopy, and magnetic force microscopy.
- Published
- 2015
12. Temperature-dependence of electrical and dielectric properties of papers for electrophotography
- Author
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Kaj Backfolk, Jonas Sidaravicius, T. Lozovski, Petri Sirviö, Robertas Maldzius, and J. B. Rosenholm
- Subjects
Permittivity ,Materials science ,Condensed matter physics ,business.industry ,General Physics and Astronomy ,Xerography ,Dielectric ,Conductivity ,law.invention ,Surface conductivity ,Electrical resistivity and conductivity ,law ,Dielectric loss ,business ,Thermal energy - Abstract
The temperature-dependence of the electrical and dielectric properties of paper substrates was studied using experimental papers with different NaCl contents, different thicknesses, and different grammages. Physical processes related to the charging potential, charge decay rate, conductivity, dielectric constant, and dielectric loss of papers are dependent on thermal energy, and this dependence on temperature can be described by exponential expressions. The ion content of paper not only determines the level of these properties at a given temperature, as expected but also influences their temperature-dependence. Frequency analysis of the dielectric loss confirms that new structures are formed in paper by the addition of NaCl. The results may be applicable to the design of materials and equipment, e.g., for the electrophotographic printing processes.
- Published
- 2010
13. Radiation effects in single-walled carbon nanotube papers
- Author
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Ryne P. Raffaelle, Scott R. Messenger, Brian J. Landi, Christopher M. Schauerman, Robert J. Walters, and Cory D. Cress
- Subjects
Materials science ,General Physics and Astronomy ,Carbon nanotube ,Alpha particle ,Conductivity ,Radiation ,Molecular physics ,law.invention ,Ionizing radiation ,Condensed Matter::Materials Science ,law ,Physics::Atomic and Molecular Clusters ,Radiation damage ,Charge carrier ,Irradiation ,Atomic physics - Abstract
The effects of ionizing radiation on the temperature-dependent conductivity of single-walled carbon nanotube (SWCNT) papers have been investigated in situ in a high vacuum environment. Irradiation of the SWCNT papers with 4.2MeV alpha particles results in a steady decrease in the SWCNT paper conductivity, resulting in a 25% reduction in room temperature conductivity after a fluence of 3×1012 alpha particles/cm2. The radiation-induced temperature-dependent conductivity modification indicates that radiation damage causes an increase in the effective activation barrier for tunneling-like conductivity and a concomitant increase in wavefunction localization of charge carriers within individual SWCNTs. The spatial defect generation within the SWCNT paper was modeled and confirms that a uniform displacement damage dose was imparted to the paper. This allows the damage coefficient (i.e., differential change in conductivity with fluence) for alpha particles, carbon ions, and protons to be compared with the corresp...
- Published
- 2010
14. Preface to Special Topic: Selected Papers from the International Conference on the Study of Matter at Extreme Conditions, SMEC 2011
- Author
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Jiuhua Chen, Naurang L. Saini, and Haozhe Liu
- Subjects
Engineering ,business.industry ,General Physics and Astronomy ,Engineering ethics ,Statistical physics ,business - Published
- 2012
15. X-ray texture analysis of paper coating pigments and the correlation with chemical composition analysis
- Author
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R. Kansanaho, Matti Murtomaa, Vesa-Pekka Lehto, Jorma Roine, and Mikko Tenho
- Subjects
Materials science ,General Physics and Astronomy ,Mineralogy ,engineering.material ,Talc ,Electron spectroscopy ,Calendering ,chemistry.chemical_compound ,Calcium carbonate ,chemistry ,Coating ,medicine ,engineering ,Nanometre ,Texture (crystalline) ,Composite material ,Chemical composition ,medicine.drug - Abstract
The present research experiments the applicability of x-ray texture analysis in investigating the properties of paper coatings. The preferred orientations of kaolin, talc, ground calcium carbonate, and precipitated calcium carbonate particles used in four different paper coatings were determined qualitatively based on the measured crystal orientation data. The extent of the orientation, namely, the degree of the texture of each pigment, was characterized quantitatively using a single parameter. As a result, the effect of paper calendering is clearly seen as an increase on the degree of texture of the coating pigments. The effect of calendering on the preferred orientation of kaolin was also evident in an independent energy dispersive spectrometer analysis on micrometer scale and an electron spectroscopy for chemical analysis on nanometer scale. Thus, the present work proves x-ray texture analysis to be a potential research tool for characterizing the properties of paper coating layers.
- Published
- 2007
16. Modeling of electromechanical behavior of chitosan-blended cellulose electroactive paper (EAPap)
- Author
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Joo-Hyung Kim, Jaehwan Kim, and Sang-Dong Jang
- Subjects
Computer Science::Robotics ,Chitosan ,chemistry.chemical_compound ,Materials science ,Cantilever ,chemistry ,Electric field ,General Physics and Astronomy ,Artificial muscle ,Cellulose ,Composite material ,Actuator ,Computer Science::Other - Abstract
Electromechanical bending actuation of chitosan-blended cellulose (CBC) electroactive paper (EAPap) was studied using a theoretical model, followed by an experimental comparison. The bending displacement of the model was calculated based on an ion traveling phenomenon and multilayered cantilever beam. By comparing the bending model and experimental data, we found that the bending model could predict the electromechanical actuation behavior as well as redistribution of ions inside of CBC EAPap under different humidity levels and electric fields. The bending actuation model of EAPap can be useful to investigate the electromechanical actuation behavior of EAPap devices such as artificial muscles, microrobots, and other various actuators.
- Published
- 2009
17. Synthesis, characterizations, and field emission studies of crystalline Na2V6O16 nanobelt paper
- Author
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S. H. Lim, Yanwu Zhu, Chorng Haur Sow, Wei Ji, and Jianyi Lin
- Subjects
Field electron emission ,Materials science ,X-ray photoelectron spectroscopy ,Scanning electron microscope ,Electric field ,X-ray crystallography ,Analytical chemistry ,General Physics and Astronomy ,Spectroscopy ,Electron spectroscopy ,Current density - Abstract
Crystalline Na2V6O16∙3H2O nanobelts have been synthesized by refluxing V2O5 and NaF and self-weaved into a sheet of paper via a vacuum filtration process. Scanning electron microscopy, x-ray diffraction, and x-ray photoelectron spectroscopy were used to characterize the morphology, structure, and chemical composition of the nanobelt papers. The dehydrated Na2V6O16 nanobelts are excellent field emission candidates, with a low turn-on field of 6.8V∕μm, a large current density up to 2.5mA∕cm2 at an electric field of 10V∕μm, and a very uniform distribution of emission sites.
- Published
- 2006
18. Preface to Special Topic: Selected Papers from The Eleventh International Conference on Surface X-Ray and Neutron Scattering
- Author
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Mark L. Schlossman, Michael J. Bedzyk, Paul F. Lyman, and Jonathan Lang
- Subjects
Nuclear physics ,Surface (mathematics) ,Chemistry ,Neutron diffraction ,X-ray ,General Physics and Astronomy ,Surface structure ,Neutron scattering ,Atomic physics - Published
- 2011
19. Preface to Special Topic: Plenary and Invited Papers from the 30th International Conference on the Physics of Semiconductors, Seoul, South Korea, 2010
- Author
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Jisoon Ihm and Hyeonsik Cheong
- Subjects
Semiconductor materials ,General Physics and Astronomy ,Engineering ethics ,Engineering physics - Published
- 2011
20. Simulation studies of internal mechanisms in the static deflection of a cellulose electroactive paper actuator
- Author
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S. D. Jang, F. Mbaye, Prathap Basappa, J. C. Hall, Jaehwan Kim, and Ravindra P. Joshi
- Subjects
Permittivity ,Transverse plane ,symbols.namesake ,Materials science ,Absorption of water ,Deflection (engineering) ,symbols ,General Physics and Astronomy ,Young's modulus ,Composite material ,Actuator ,Elastic modulus ,Piezoelectricity - Abstract
Studies of voltage-induced deflections in electroactive paper (EAPap) have been carried out. On the experimental side, measurements of bias-dependent deflections and strain, water absorption as a function of time, and relative humidity were obtained for the cellulose EAPap actuator. In addition, model simulations have also been carried out to probe and quantify the role of the various internal mechanisms responsible for the deflection. Our simulation predictions yield good agreement with the measured deflection data for the EAPap. The modeling suggests that internal ion content and its migration, water absorption leading to a nonuniform permittivity, random variations in the transverse piezoelectric-coupling coefficient d31,i, and the modulus of elasticity all collectively contribute to the EAPap deflection electrophysics. It also appears that higher sensitivity, with a minimal bias dependence, could be achieved by deliberately adding ions during EAPap processing.
- Published
- 2008
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