1. A new Bi0.5Na0.5TiO3 based lead-free piezoelectric system with calculated end-member Bi(Zn0.5Hf0.5)O3.
- Author
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Feng Liu, Wahyudi, Olivia, and Yongxiang Li
- Subjects
- *
PIEZOELECTRIC materials , *COERCIVE fields (Electronics) , *PIEZOELECTRICITY , *SOLID state physics , *X-ray diffraction - Abstract
The phase structure, dielectric and piezoelectric properties of a new lead-free piezoelectric system (1-x)Bi0.5Na0.5TiO3-x-xBi(Zn0.5Hf0.5)O3 [(1-x)BNT-xBZH, x=0, 0.01, 0.02, 0.03, and 0.04] were investigated. The structure of Bi(Zn0.5Hf0.5)O3 was calculated using first-principles method and (1-x)BNT-xBZH ceramics were fabricated by conventional solid-state process. At room temperature, a morphotropic phase boundary (MPB) from rhombohedral to pseudocubic is identified near x=0.02 by the analysis of X-ray diffraction patterns. The ceramics with MPB near room temperature exhibit excellent electrical properties: the Curie temperature, maximum polarization, remnant polarization, and coercive field are 340 °C, 56.3 μC/cm2, 43.5 μC/cm2, and 5.4 kV/mm, respectively, while the maximum positive bipolar strain and piezoelectric coefficient are 0.09% and 92 pC/N, respectively. In addition, a linear relationship between the MPB phase boundary composition and the calculated tetragonality of non-BNT end-member was demonstrated. Thus, this study not only shows a new BNT-based lead-free piezoelectric system but also suggest a new way to predict the composition at MPB a priori when designing new lead-free piezoelectric system. [ABSTRACT FROM AUTHOR]
- Published
- 2014
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