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Start Over Author "Zhang, Jian-Han" Topic ionic conductivity Journal journal of alloys & compounds

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1 results on '"Zhang, Jian-Han"'

1. Synthesis, structure, physicochemical characterization and electronic structure of thio-lithium super ionic conductors, Li4GeS4 and Li4SnS4.

Author

MacNeil, Joseph H., Massi, Danielle M., Zhang, Jian-Han, Rosmus, Kimberly A., Brunetta, Carl D., Gentile, Taylor A., and Aitken, Jennifer A.

Subjects
*LITHIUM compounds, *ELECTRONIC structure, *IONIC conductivity, *TIN compounds, *INORGANIC synthesis, *HIGH temperature metallurgy
Abstract

Highlights: [•] The title compounds were prepared by a high-temperature, direct-combination route. [•] The room temperature structure of Li4SnS4 is reported in space group Pnma. [•] The Li(2)S4 tetrahedra invert upon going from the RT to low temperature structure. [•] Electronic structure calculations indicate the Li–S bonding to be primarily ionic. [•] Li4GeS4 and Li4SnS4 have shown to be stable up to ∼850 and 950°C respectively. [ABSTRACT FROM AUTHOR]

Published
2014
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