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Hypogene caves in the Plavecký hradný vrch Hill (Western Slovakia, Central Europe) were formed by waters ascending along faults in fractured Triassic carbonates related to the horst-graben structure at the contact of the Malé Karpaty Mountains and the NE part of the Vienna Basin. The Plavecká jaskyňa and Pec caves mostly contain horizontal passages and chambers with flat corrosion bedrock floors, fissure discharge feeders, wall water-table notches, replacement pockets, as well as a few other speleogens associated with sulfuric acid speleogenesis. The low-temperature sulfuric acid development phases of the Plavecká Jaskyňa are also indicated by the presence of sulfate minerals (i.e., gypsum and jarosite). Subaerial calcite popcorn rims were precipitated from water condensation at the edges of feeding fissures that were still active as thermal vents when the water table dropped. Hydrogen sulfide involved in the sulfuric acid speleogenesis was likely derived from anhydrites and/or hydrocarbon reservoirs with sulfate-saline connate waters in the fill of the adjacent Vienna Basin. It ascended to the surface along deep-rooted sub-vertical fault zones at the contact of the Vienna Basin with neighboring mountains. Three cave levels at 295 to 283 m asl in the Pec Cave, and five levels at 225 to 214 m asl in the Plavecká jaskyňa corresponded to phases of stable local erosional base levels in the bordering part of the Vienna Basin, most likely during periods of strongly decelerated and/or interrupted subsidence. Cave levels separated by vertical differences of only a few meters may also be related to the Pleistocene climatic cycles. The subhorizontal parts of the Pec Cave are probably of late Early Pleistocene age (>0.99-1.07 Ma?). The two highest levels of the Plavecká jaskyňa developed during the early Middle Pleistocene (>600 ka). Fine-grained sediments in the passage at 225 m asl with normal magnetic polarity contain jarosite. The middle level of the Plavecká jaskyňa at 220 m asl was formed in the mid-Middle Pleistocene, while the lower and lowermost levels formed in the late Middle Pleistocene (>270 ka). The water table in the lowermost cave level probably dropped after the tectonic reactivation of the Podmalokarpatská zníženina Depression just in the front of a marginal horst structure of the Malé Karpaty Mountains. [ABSTRACT FROM AUTHOR]

Cold Wind Cave, located at elevations ranging between 1,600 and 1,700 m a. s. l. in the main range of the Nízke Tatry Mountains (Slovakia), is linked in origin with the adjacent Dead Bats Cave. Together, these caves form a major cave system located within a narrow tectonic slice of Triassic sediments. Both caves have undergone complex multiphase development. A system of sub-horizontal cave levels characterized by large, tunnel-like corridors was formed during the Tertiary, when elevation differences surrounding the cave were less pronounced than today. The central part of the Nízke Tatry Mountains, together with the cave systems, was uplifted during the Neogene and Lower Pleistocene, which changed the drainage pattern of the area completely. The formation of numerous steep-sloped vadose channels and widespread cave roof frost shattering characterized cave development throughout the Quaternary. In the Cold Wind Cave, extensive accumulations of loose, morphologically variable crystal aggregates of secondary cave carbonate ranging in size between less than 1 mm to about 35 mm was found on the surface of fallen limestone blocks. Based on the C and O stable isotope compositions of the carbonate (δ13C: 0.72 to 6.34 ‰, δ18O: -22.61 to -13.68 ‰ V-PDB) and the negative relation between δ13C and δ18O, the carbonate crystal aggregates are interpreted as being cryogenic cave carbonate (CCC). Published models suggest the formation of CCC in slowly freezing water pools, probably on the surface of cave ice, most probably during transitions from stadials to interstadials. Though the formation of these carbonates is likely one of the youngest events in the sequence of formation of cave sediments of the studied caves, the 230Th/234U ages of three samples (79.7±2.3, 104.0±2.9, and 180.0±6.3 ka) are the oldest so far obtained for CCC in Central Europe. This is the first description of CCC formation in one cave during two glacial periods (Saalian and Weichselian). [ABSTRACT FROM AUTHOR]

The Ochtiná Aragonite Cave (Western Carpathians) represents a unique natural phenomenon. It originated under particular lithological and hydrogeological conditions of the Ochtiná Karst in which several isolated lenses of Paleozoic crystalline limestone, partly metasomatically altered to ankerite, are enclosed by phyllites. Meteoric water seepage through non-carbonate rocks dissolved limestone and caused the oxidation of ankerite to Fe oxyhydroxides. Carbon dioxide produced during ankerite oxidation enhanced limestone dissolution. The maze cave consists of parallel fault-controlled linear passages and chambers interconnected by transverse horizontal passages. Phreatic and epiphreatic solution morphologies resulted from slowly moving or standing water. These include flat ceilings (Laugdecken), facets, lateral notches, convection ceiling cupola-shaped depressions, and spongework-like hollows. Flat ceilings were developed in several altitude positions, each of them probably closely below the slightly oscillated water table. Primary phreatic cupola-shaped depressions, truncated by flat ceilings, represent relics of the oldest cavities (pre-Quaternary? to Early Pleistocene). Inward-sloping smooth facets were not developed only in passages with flat ceilings, but also in the passages and halls with a vaulted ceiling. The asymmetrical shape of cusped depressions above the facets were documented in detail by a high-resolution cave topography with terrestrial laser scanning and digital photogrammetry. Middle--Late Pleistocene accumulation phases, identified by magnetostratigraphy of cave sediments and U-series dating of speleothems, are associated with phreatic and later epiphreatic development. The deposition on the bottom bedrock began before 1.8 Ma. The Brunhes/Matuyama boundary (0.773 Ma) and Jaramillo magnetozone (0.990-1.071 Ma) were recorded in the profile in the Oválna chodba Passage. Slow depositional rate (~0.09 cm/kyr) calculated from magnetostratigraphy resulted from slow water movement in confined conditions in marbles completely enclosed by phyllites and no direct relation to the surface. Only occasionally turbid water was loaded in extremely fine-grained infiltration material and autochthonous Fe oxyhydroxides. The depositional rate in Mn-rich layer was much slower (~0.03 cm/kyr). Additional U-series dating confirmed that old aragonite generations (with ages about 500-450 ka and 143-121 ka) were partly corroded by repeated floods during Late Pleistocene humid episodes. Aragonite younger than 13.5 ka is not corroded. [ABSTRACT FROM AUTHOR]