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In clinical and scientific research on emotion recognition using physiological signals, selecting the appropriate segment is of utmost importance for enhanced results. In our study, we optimized the electrodermal activity (EDA) segment for an emotion recognition system. Initially, we obtained EDA signals from two publicly available datasets: the Continuously annotated signals of emotion (CASE) and Wearable stress and affect detection (WESAD) for 4-class dimensional and three-class categorical emotional classification, respectively. These signals were pre-processed, and decomposed into phasic signals using the 'convex optimization to EDA' method. Further, the phasic signals were segmented into two equal parts, each subsequently segmented into five nonoverlapping windows. Spectrograms were then generated using short-time Fourier transform and Mel-frequency cepstrum for each window, from which we extracted 85 features. We built four machine learning models for the first part, second part, and whole phasic signals to investigate their performance in emotion recognition. In the CASE dataset, we achieved the highest multi-class accuracy of 62.54% using the whole phasic and 61.75% with the second part phasic signals. Conversely, the WESAD dataset demonstrated superior performance in three-class emotions classification, attaining an accuracy of 96.44% for both whole phasic and second part phasic segments. As a result, the second part of EDA is strongly recommended for optimal outcomes. [ABSTRACT FROM AUTHOR]