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Abstract: In this paper an investigation on the performance of a commercial Proton Exchange Membrane (PEM) fuel cell, installed at the laboratory of the University of Bologna, is carried out, taking into account the anodic exhaust management and its effects on the flooding phenomenon. To address the problem of flooding, it is necessary to run periodically the purge process of the Fuel Fell (FC). Indeed, in this study the periodic anodic purge process in dead-end mode has been investigated. This operation is performed by opening a particular control valve, the Outlet Purge Valve (OPV), located along the anodic exhaust line. The purge process has been analyzed at different FC power output levels. For each FC power level the optimized behavior of the FC operation was found, by regulating the time of flooding. The aim of this analysis is to optimize the purge process to reduce the amount of hydrogen discharged with water, in order to increase the FC efficiency. An investigation on the benefits in terms of fuel utilization factor and costs, resulting from optimization of the FC purge process, is shown in the paper. [Copyright &y& Elsevier]

Abstract: Solid Oxide Fuel Cells (SOFC) are very promising energy conversion devices, producing electricity and heat from a fuel directly via electrochemical reactions. The electrical efficiency of SOFCs is particularly high, so that such systems are very attractive for integration in complex polygeneration systems. In this paper, the integration of SOFC systems with solar thermal collector is investigated seeking to design a novel polygeneration system producing: electricity, space heating and cooling and domestic hot water, for a university building located in Naples (Italy), assumed as case study. The polygeneration system is based on the following main components: concentrating parabolic through solar collectors, a double-stage LiBr–H2O absorption chiller and an ambient pressure SOFC fuel cell. The system also includes a number of additional components required for the balance of plant, such as: storage tanks, heat exchangers, pumps, controllers, cooling tower, etc. The SOFC operates at full load, producing electric energy that is in part self-consumed for powering building lights and equipments, and in part is used for operating the system itself; the electric energy in excess is eventually released to the grid and sold to the public Company that operates the grid itself. The system was designed and then simulated by means of a zero-dimensional transient simulation model, developed using the TRNSYS software; the investigation of the dynamic behavior of the building is also included. The results of the case study were analyzed for different time bases, from both energetic and economic points of view. Finally, a thermoeconomic optimization is also presented aiming at determining the optimal set of system design parameters. The economic results show that the system under investigation may be profitable, provided that it is properly funded. However, the overall energetic and economic results are more encouraging than those claimed for other similar polygeneration systems in the recent literature. [Copyright &y& Elsevier]