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Evolutionary algorithms are metaheuristic algorithms that provide quasioptimal solutions in a reasonable time. They have been applied to many optimization problems in a high number of scientific areas. In this survey paper, we focus on the application of evolutionary algorithms to solve optimization problems related to a type of complex network likemobilemultihop ad hoc networks. Since its origin, mobile multihop ad hoc network has evolved causing new types of multihop networks to appear such as vehicular ad hoc networks and delay tolerant networks, leading to the solution of new issues and optimization problems. In this survey, we review the main work presented for each type of mobile multihop ad hoc network and we also present some innovative ideas and open challenges to guide further research in this topic.