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In this work, chitosan-grafted-poly(acrylic acid) (CS-g-PAA) was synthesized for use as a Co2+ adsorbent and circularly utilized as a peroxymonosulfate (PMS) activator in the degradation of rhodamine B (RhB) dye. CS-g-PAA demonstrated 3.7 times higher adsorption capacity toward Co2+ than pristine chitosan. The impact of the adsorption conditions was evaluated. The pseudo-second-order kinetic model and the Langmuir isotherm model best described the adsorption process. Under optimum conditions, the adsorption capacity of CS-g-PAA for Co2+ was 212 mg/g. The Co2+-adsorbed CS-g-PAA hydrogel was further utilized in the RhB degradation process. The effects of catalyst dosage, initial RhB concentration, pH, and the coexistence of anions on the degradation of RhB were studied. The hydrogel catalyst could remove 98 % of RhB within 5 min, at a degradation rate of 0.624 per min. Electron paramagnetic resonance (EPR) analysis and the radical scavenger experiment suggested that SO 4 •−, HO•, 1O 2 , and O 2 •− were involved in the degradation. Furthermore, when tested in various water systems, high degradation efficiencies of 98 % were attained after 20 min. The hydrogel catalyst performed excellent degradation over ten cycles without any chemical recovery processes. Moreover, high degradation efficiencies were observed between 95 % and 98 % when tested with other dyes. [ABSTRACT FROM AUTHOR]

Chitosan-grafted-poly(acrylic acid) (CS-g-PAA) and chitosan-grafted- poly(2-acrylamido-2-methyl-1-propanesulfonic acid) (CS-g-P(AA- co -AMPS)) hydrogels were synthesized and then employed as adsorbents for the effective removal of Cu2+ and other heavy metal ions. The effect of hydrogel's composition on the Cu2+ adsorption was explored. The CS-g-PAA hydrogel demonstrated a superior adsorption capacity compared to pristine CS, PAA hydrogel, and CS-g-P(AA-co-AMPS) hydrogels. The adsorption followed the Langmuir isotherm model, and the pseudo-second order kinetic model. Additionally, the CS-g-PAA hydrogel exhibited relatively high adsorption performances toward Cr3+, Co2+, Ni2+, Pb2+, and Zn2+. Metal ions adsorbed within CS-g-PAA hydrogels underwent reduction to their corresponding metallic states and were reutilized as catalysts for the reduction of 4-nitrophenol. The comparative catalytic performances of the metal species in the hydrogel were in the order of Cu > Ni > Co > Zn. The reduction efficiency of Cu-CS-g-PAA increased with increased catalyst dosage, NaBH 4 concentration, and temperature. A very low activation energy of 3.7 kJ/mol was observed. The catalyst maintained high catalytic performance even when subjected to real water samples and proved its reusability for up to three cycles. Moreover, the catalyst could effectively reduce 2-nitrophenol and methyl orange. [ABSTRACT FROM AUTHOR]

Chitosan-grafted-poly(acrylic acid) (CS-g-PAA) and chitosan-grafted- poly(2-acrylamido-2-methyl-1-propanesulfonic acid) (CS-g-P(AA- co -AMPS)) hydrogels were synthesized and then employed as adsorbents for the effective removal of Cu2+ and other heavy metal ions. The effect of hydrogel's composition on the Cu2+ adsorption was explored. The CS-g-PAA hydrogel demonstrated a superior adsorption capacity compared to pristine CS, PAA hydrogel, and CS-g-P(AA-co-AMPS) hydrogels. The adsorption followed the Langmuir isotherm model, and the pseudo-second order kinetic model. Additionally, the CS-g-PAA hydrogel exhibited relatively high adsorption performances toward Cr3+, Co2+, Ni2+, Pb2+, and Zn2+. Metal ions adsorbed within CS-g-PAA hydrogels underwent reduction to their corresponding metallic states and were reutilized as catalysts for the reduction of 4-nitrophenol. The comparative catalytic performances of the metal species in the hydrogel were in the order of Cu > Ni > Co > Zn. The reduction efficiency of Cu-CS-g-PAA increased with increased catalyst dosage, NaBH 4 concentration, and temperature. A very low activation energy of 3.7 kJ/mol was observed. The catalyst maintained high catalytic performance even when subjected to real water samples and proved its reusability for up to three cycles. Moreover, the catalyst could effectively reduce 2-nitrophenol and methyl orange. [ABSTRACT FROM AUTHOR]