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In the field of building energy conservation, the development of biodegradable biomass aerogels with excellent mechanical performance, flame retardancy and thermal insulation properties is of particular importance. Here, a directional freeze-drying method was used for fabricating composite sodium alginate (SA) aerogels containing functionalized ammonium polyphosphate (APP) flame retardant. In particular, APP was coated with melamine (MEL) and phytic acid (PA) by a supramolecular assembly process. Through optimizing the flame retardant addition, the SA-20 AMP sample exhibited excellent flame retardant and thermal insulation properties, with the limiting oxygen index of 38.2 % and the UL-94 rating of V-0. Such aerogels with anisotropic morphology demonstrated a low thermal conductivity of 0.0288 (W/m·K) in the radial direction (perpendicular to the lamellar structure). In addition, as-obtained aerogels displayed remarkable water stability and mechanical properties, indicating significant potential for practical applications. [Display omitted] • A high-efficiency flame retardant was synthesized. • AMP has a good interface compatibility with sodium alginate. • SA-20 AMP reached V-0 rating and the LOI value was 38.2 %. • Directional freezing endows SA-20 AMP with outstanding thermal insulation properties. [ABSTRACT FROM AUTHOR]

In this study, a multi-functional guar gum aerogel with the oriented lamellar structure, which introduced sodium silicate (Na 2 O·nSiO 2) and phytic acid (PA) as thermal insulation additives and flame-retardant agents, respectively, was fabricated via freeze drying. Our aerogel's chemical structure, morphology, and thermal and mechanical properties were analyzed. The oriented lamellar structure was attributed to the orientated growth of ice crystals, which was induced by the "silicate-guar, guar-phytate, and phytate-silicate" multiple hydrogen bonds formed between Na 2 O·nSiO 2 , PA, and guar gum. The density of the sample with 2 wt% PA could reach 0.0335 g·cm−3, and the porosity was 5 %, along with a specific pore volume of 0.8144 cm3·g−1. The mechanical properties and thermal insulation performed significant differences in the radial and axial direction of the oriented lamella (nearly 100 % resilience while 50 % deformation quantity and 0.0235 W/(m*K) of thermal conductivity in the radial direction, up to 0.079 MPa of compressive strength in the axial direction). The presence of PA attached a good flame-retardant ability to our aerogel (The Limiting Oxygen Index (LOI) was 30.77 %). This work provides a novel and promising method for developing anisotropic aerogel with excellent potential in building energy efficiency and flame-retardant. [ABSTRACT FROM AUTHOR]

Naturally-derived aerogels have attracted considerable attention owing to their good biocompatibility, biodegradability and sustainability, but their weak mechanical properties largely limit their applications in various fields. Herein, we proposed the use of a directional freeze-drying method to prepare an anisotropic honeycomb three-dimensional porous aerogel with water-soluble chitosan (CS) as a rigid skeleton and water-soluble biobased epoxy resin as cross-linked hard segments, which had low volume shrinkage and density of 13.9 % and 34.3 mg/cm3, respectively. The resultant aerogel had anisotropic mechanical properties, such as rigidity in the axial direction with a maximum axial modulus of 6.71 MPa, which was 51.6 times larger than that of the pure chitosan aerogel, demonstrating a good compressive elasticity in the radial direction. It also had anisotropic thermal management properties, with a lower thermal conductivity in the radial direction than in the axial direction, down to 0.029 W/mK. The introduction of biobased epoxy resin improved the overall thermal stability, flame retardancy, and increased the biomass content in the aerogel, reducing the carbon footprint of the material. This study paves the way for the construction of a special graded porous, structurally and functionally integrated thermal insulation aerogel, which is of great significance for the development of new thermal insulation materials. [Display omitted] • Anisotropic honeycomb bio-based aerogels have been prepared by directional freeze-drying. • The introducing of bio-based epoxy resin improves the comprehensive properties of aerogel. • The aerogel exhibits low thermal conductivity of 0.029 W/mK in the radical direction. • The aerogel shows low volume shrinkage (13.9 %) and density (34.3 mg/cm3). [ABSTRACT FROM AUTHOR]