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Abstract: We have examined the new phase formation and compositional variations in the coatings produced by detonation spraying of Ti3Al powders in atmospheres of different chemistry. The composition of the spraying atmosphere was varied by changing the O2/C2H2 ratio used for the detonation. In the coatings sprayed at an O2/C2H2 ratio of 0.87 and 1.05, certain deviations of the Al/Ti ratio have been observed relative to the sprayed powder. In these coatings, the Ti3Al phase was found along with TiN and Ti2N formed due to the reaction of the heated particles with nitrogen used for powder injection. The amount of TiN increased with increasing explosive charge and a concomitant rise in the particles temperature. Under O2/C2H2 ratios equal to 1.50 and 2.00, significant losses of Al were detected, the coatings being composed mainly of titanium oxides. This study shows that detonation spraying conditions excluding severe oxidation of Ti3Al can be found as well those facilitating oxidation with an associated loss of Al in the deposits. [Copyright &y& Elsevier]