1. Structure–Property Relations in Multiferroic [(CH3)2NH2]M(HCOO)3 (M = Mn, Co, Ni)
- Author
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Xiaxin Ding, Hongjun Xiang, Amanda Clune, Naresh S. Dalal, Nandita Abhyankar, Dmitry Smirnov, John Singleton, Kendall D. Hughey, Michael Yokosuk, Janice L. Musfeldt, and Jing Li
- Subjects
Chemistry ,Hydrogen bond ,Infrared ,Infrared spectroscopy ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Ferroelectricity ,0104 chemical sciences ,Inorganic Chemistry ,Magnetization ,Crystallography ,chemistry.chemical_compound ,Multiferroics ,Formate ,Physical and Theoretical Chemistry ,0210 nano-technology ,Phase diagram - Abstract
We bring together magnetization, infrared spectroscopy, and lattice dynamics calculations to uncover the magnetic field-temperature (B-T) phase diagrams and vibrational properties of the [(CH3)2NH2]M(HCOO)3 (M = Mn2+, Co2+, Ni2+) family of multiferroics. While the magnetically driven transition to the fully saturated state in [(CH3)2NH2]Mn(HCOO)3 takes place at 15.3 T, substitution with Ni or Co drives the critical fields up toward 100 T, an unexpectedly high energy scale for these compounds. Analysis of the infrared spectrum of the Mn and Ni compounds across TC reveals doublet splitting of the formate bending mode which functions as an order parameter of the ferroelectric transition. By contrast, [(CH3)2NH2]Co(HCOO)3 reveals a surprising framework rigidity across the order−disorder transition due to modest distortions around the Co2+ centers. The transition to the ferroelectric state is thus driven by the dimethylammonium cation freezing and the resulting hydrogen bonding. Under applied field, the Mn (an...
- Published
- 2018
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