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Your search keyword '"Radonovich, Lewis J"' showing total 7 results
Start Over Author "Radonovich, Lewis J" Journal inorganic chemistry
7 results on '"Radonovich, Lewis J"'

1. Metal hydride vs side-on-sigma-bonded trichlorosilane complexes of arene-chromium derivatives: (eta 6-arene)Cr(CO)(H2)(SiCl3)2

Author

Jagirdar, Balaji R., Palmer, Roger, Klabunde, Kenneth J., and Radonovich, Lewis J.

Subjects
Coordination compounds -- Research, Chromium compounds -- Analysis, Silane -- Research, Chemical bonds -- Analysis, Chemistry
Abstract

Photolysis of (eta 6-arene)Cr(CO)3 in the presence of HSiCl3 produces a Cr(IV) dihydride complex, (eta 6-arene)Cr(CO)(H)2(SiCl3)2, an intermediate in the formation of (eta 6-arene)Cr(CO)2(SiCl3)2. At room temperatures the hydride ligands exhibit fluxional behavior. X-ray studies along with NMR and IR data of fluorobenzene and mesitylene complexes support the formation of Cr(IV) dihydride derivatives rather than sigma-bonded side-on H-SiCl3 groups.

Published
1995

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