Search

Your search keyword '"Mair, Francis S."' showing total 4 results
Start Over Author "Mair, Francis S." Journal inorganic chemistry
4 results on '"Mair, Francis S."'

1. Crystal structure of the molecular addition compound diphenylchloroborane.tetrahydrofuran

Author

Cross, Wendy I., Lightfoot, Matthew P., Mair, Francis S., Pritchard, Robin G., and Walton, Richard A.

Subjects
Chemistry, Inorganic -- Research, Borane -- Research, Borane -- Chemical properties, Chemistry
Abstract

Crystalline Diphenylchloroborante.Tetrahydrofuran is unexpectedly stable complex containing an intact THF ligand in the presence of a boron halide bond. Using Gillespie's ligand close-packing arguments, the short B - O and long B - Cl bonds of this ether cleavage precursor complex are rationalized.

Published
2000

2. Structural characterization of [(2,6-Pr(super i)(sub 2)C6H3)-NC(Me)C(H)C(Me)N(2,6-Pr(super i)(sub 2)C6H3)K*PhCH3]sub infiniti: a heavy alkali metal diazapentadienyl complex

Author

Clegg, William, Cope, Elaine K., Edwards, Andrew J., and Mair, Francis S.

Subjects
Coordination compounds -- Analysis, Alkali metals -- Analysis, Ligands -- Analysis, Nuclear magnetic resonance spectroscopy -- Analysis, Chemistry
Abstract

An experiment was conducted to derive a structural characterization of ((2,6-Pr(super i)(sub 2)C6H3)-NC(Me)C(H)C(Me)N(2,6-Pr(super i)(sub 2)C6H3)K*PhCH3)sub infiniti which is considered a heavy alkali metal complex. The characterization was carried by using nuclear magnetic resonance spectroscopy. Results revealed that the molecular structure of the complex exhibited a monomeric and polymerized features.

Published
1998

Catalog

Books, media, physical & digital resources
See catalog results