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Start Over Author "Gayathri B" Journal inorganic chemistry
4 results on '"Gayathri B"'

3. Bimetallic Ru-Pd and Trimetallic Ru-Pd-Cu Assemblies on the Carborane Cluster Surface

Author

Corey R. Martin, Gayathri B. Gange, Dmitry V. Peryshkov, Kyoung Chul Park, Mark D. Smith, H. D. A. Chathumal Jayaweera, Bennett J. Eleazer, and Alexey A. Popov

Subjects
Inorganic Chemistry, Metal, Crystallography, Chemical bond, Chemistry, visual_art, Electrophile, Cluster (physics), visual_art.visual_art_medium, Carborane, Physical and Theoretical Chemistry, Bimetallic strip
Abstract

The synthesis of well-defined heterometallic complexes remains a frontier challenge in inorganic chemistry. We report an approach that relies on the sequential insertion of electrophilic metal fragments into electron-rich Ru-B bonds of the η2-BB-carboryne complex (POBBOP)Ru(CO)2 [POBBOP = 1,7-OP(iPr)2-m-2,6-dehydrocarborane]. Utilizing this synthetic strategy, bimetallic (POBBOP)(Ru)(CO)2[Pd(PtBu3)] and trimetallic (POBBOP)(Ru)(CO)2[Pd(PtBu3)](CuBr) complexes were selectively prepared. Structural and theoretical analysis of the features of chemical bonding within Ru-B-B-Cu and Ru-B-B-Pd fragments is presented.

Published
2021

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