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Start Over Author "Dixon, Casey" Journal inorganic chemistry
5 results on '"Dixon, Casey"'

2. Mechanochemical Synthesis of a Sodium Anion Complex [Na+(2,2,2-cryptand)Na–] and Studies of Its Reactivity: Two-Electron and One-Electron Reductions

Author

Davison, Nathan, Hemingway, Jack M., Wills, Corinne, Stolar, Tomislav, Waddell, Paul G., Dixon, Casey M., Barron, Luke, Dawson, James A., and Lu, Erli

Abstract

Group 1 metal molecular chemistry is dominated by a +1 oxidation state, while a 0 oxidation state is widespread in the metals. A more exotic, yet still available, oxidation state of group 1 metal is −1, i.e., alkalide. Reported as early as the 1970s, the alkalides appear in every modern inorganic chemistry textbook as an iconic chemical curiosity, yet their reactivity remains unexplored. This is due to their synthetic hurdles. In this work, we report the first facile synthesis of the archetypical alkalide complex, [Na+(2,2,2-cryptand)Na–], which allows us to unveil a versatile reactivity profile of this once exotic species.

Published
2024
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5. Mechanochemical Synthesis of a Sodium Anion Complex [Na + (2,2,2-cryptand)Na - ] and Studies of Its Reactivity: Two-Electron and One-Electron Reductions.

Author

Davison N, Hemingway JM, Wills C, Stolar T, Waddell PG, Dixon CM, Barron L, Dawson JA, and Lu E

Abstract

Group 1 metal molecular chemistry is dominated by a +1 oxidation state, while a 0 oxidation state is widespread in the metals. A more exotic, yet still available, oxidation state of group 1 metal is -1, i.e., alkalide. Reported as early as the 1970s, the alkalides appear in every modern inorganic chemistry textbook as an iconic chemical curiosity, yet their reactivity remains unexplored. This is due to their synthetic hurdles. In this work, we report the first facile synthesis of the archetypical alkalide complex, [Na + (2,2,2-cryptand)Na - ], which allows us to unveil a versatile reactivity profile of this once exotic species.

Published
2024
Full Text
View/download PDF

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