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Start Over Author "Chiang, Wen-C." Journal inorganic chemistry
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1. Synthesis and thermal and hydrolytic conversion of heterometallic copper oxide-alkoxides

Author

Samuels, John A., Chiang, Wen-C., Huffman, John C., Trojan, Kathleen L., Hatfield, William E., Baxter, David V., and Caulton, Kenneth G.

Subjects
Copper compounds -- Research, Oxo compounds -- Analysis, Nuclear magnetic resonance spectroscopy -- Analysis, Chemistry
Abstract

Oxo complexes of copper-zirconium alkoxides are produced by hydrolysis or oxidation with molecular oxygen. These oxide-alkoxide species have different thermal decomposition products when compared to alkoxides species due to increased number of O(super 2-) ligands and less metal segregation. Magnetic, spectroscopic and thermal studies of heterometallic alkoxides show that these compounds undergo internal redox with isopropoxide ligands yielding acetone, alcohol and copper metal.

Published
1994

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