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Your search keyword '"Castro, Ludovic"' showing total 5 results
Start Over Author "Castro, Ludovic" Journal inorganic chemistry
5 results on '"Castro, Ludovic"'

3. Formation of a Uranium Trithiocarbonate Complex via the Nucleophilic Addition of a Sulfide-Bridged Uranium Complex to CS2.

Author

Lam, Oanh P., Castro, Ludovic, Kosog, Boris, Heinemann, Frank W., Maron, Laurent, and Meyer, Karsten

Subjects
*URANIUM, *SULFIDES, *COMPLEX compounds, *NUCLEOPHILIC addition (Chemistry), *SCISSION (Chemistry), *REDUCTIVE elimination (Chemistry)
Abstract

The uranium(IV)/uranium(IV) μ-sulfide complex [{((AdArO)3N)U}2(μ-S)] reacts with CS2 to form the trithiocarbonate-bridged complex [{((AdArO)3N)U}2(μ-K2:K2-CS3)]. The trithiocarbonate complex can alternatively be formed in low yields from low-valent [((AdArO)3N)U(DME)] through the reductive cleavage of CS2. [ABSTRACT FROM AUTHOR]

Published
2012
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5. Formation of a uranium trithiocarbonate complex via the nucleophilic addition of a sulfide-bridged uranium complex to CS2.

Author

Lam OP, Castro L, Kosog B, Heinemann FW, Maron L, and Meyer K

Abstract

The uranium(IV)/uranium(IV) μ-sulfide complex [{(((Ad)ArO)(3)N)U}(2)(μ-S)] reacts with CS(2) to form the trithiocarbonate-bridged complex [{(((Ad)ArO)(3)N)U}(2)(μ-κ(2):κ(2)-CS(3))]. The trithiocarbonate complex can alternatively be formed in low yields from low-valent [(((Ad)ArO)(3)N)U(DME)] through the reductive cleavage of CS(2).

Published
2012
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