1. Impact of Zr-Doped TiO2 Photocatalyst on Formaldehyde Degradation by Na Addition
- Author
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Yukang Zhou, Chen Yingwen, Shubao Shen, Haitao Xu, Baoqing Duan, Qiong Huang, and Chao Huang
- Subjects
Anatase ,Materials science ,General Chemical Engineering ,Doping ,Formaldehyde ,chemistry.chemical_element ,02 engineering and technology ,General Chemistry ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Oxygen ,Industrial and Manufacturing Engineering ,0104 chemical sciences ,chemistry.chemical_compound ,X-ray photoelectron spectroscopy ,chemistry ,Photocatalysis ,Particle size ,0210 nano-technology ,Nuclear chemistry ,Visible spectrum - Abstract
In this study, a series of Na–Zr/TiO2 photocatalysts with different Na contents were synthesized via the sol–gel process. The characterization of the materials showed that Na addition facilitates the maintenance of anatase and excess Na led to particle size increases because of the formation of Na2Ti3O7. The XPS results suggested that Na loading can increase the number of oxygen vacancies, leading to more abundant surface hydroxyl groups. The enhanced photocatalytic activities under visible light irradiation can be attributed to a decreasing band gap and increasing oxygen vacancies. The efficiency of the Na–Zr/TiO2 samples was investigated by the degradation of formaldehyde under visible light. A high degradation rate of formaldehyde of approximately 96.6% was obtained with 2.5 mol % Na added to the Zr/TiO2 samples.
- Published
- 2018