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In this study, large-area dielectric breakdown performances of various bi-axially oriented polypropylene (BOPP)-silica nanocomposite films are studied by utilizing the self-healing multi-breakdown method presented in the Part I of this publication. In particular, the effects of silica filler content, pre-mixing method, co-stabilizer content and film processing on the large-area breakdown performance are analyzed. Nanostructural and film cross-sectional analyses are correlated to the breakdown responses. The optimum silica filler content is found to reside at the low fill fraction level (~1 wt-%) and automatic pre-mixing of the raw materials and the optimization of the orientation temperature are found to be preferable. The co-stabilizer Irgafos 168 is found to have a significant effect on the breakdown distribution homogeneity of the reference BOPP films. The breakdown response of the silica nanocomposites is found to be not only dependent on the active measurement area but also on the voltage ramp rate, indicating that the silica nanocomposites exhibit altered internal charge behavior under DC electric field. The area- and ramp-rate-dependence results exemplify the importance of careful breakdown strength evaluation of dielectric polymer nanocomposites. Above all, the results emphasize the fact that a thorough understanding and the optimization of the film processing parameters are crucial for achieving improved breakdown response in dielectric polymer nanocomposite films. [ABSTRACT FROM PUBLISHER]

New data of the electronic properties of liquid helium and liquid neon are discussed with respect to their relevance for the initiation of electric breakdown. It is concluded that under ideal conditions the cathode plays a decisive role in the initiation of the breakdown process. It is speculated that a Townsend type breakdown mechanism is absent in the liquid phase of these elements. [ABSTRACT FROM AUTHOR]

Pre-breakdown phenomena in pure n-tridecane in liquid and solid state have been investigated experimentally in a needle-plane geometry with impulse voltage. Light emission and charge injection from the high-field electrode were measured. Pre-inception currents in liquid and solid state were recorded and compared to finite element calculations to find plausible high-field conduction models for n-tridecane and cyclohexane. n-tridecane was chosen as a model system for polyethylene based on the known similarities in energy bands for polyethylene and alkanes. The results obtained in pure n-tridecane were compared to similar experiments on cyclohexane and polymer systems. High-field conduction in liquid n-tridecane was found to have a similar field dependence as previously reported for cross linked polyethylene (XLPE). Conduction currents and inception probabilities were found to be almost independent of polarity in frozen and liquid n-tridecane, which is also in line with results obtained for XLPE. Conduction currents were observed at lower voltages in n-tridecane than in cyclohexane, reflecting the lower space charge limited field (SCLF) in n-tridecane. Inception of streamers in liquid cyclohexane occurs at lower voltages than in liquid n-tridecane, and a stronger polarity dependence for all phenomena was observed in cyclohexane compared with n-tridecane. A possible explanation for the differences between n-tridecane and cyclohexane is given based on the field needed for electron avalanches and the SCLF in the two liquids. Inception voltages, light emission and charge injection were found to be similar in liquid and solid n-tridecane. This indicates that the same processes are responsible for inception and propagation of electrical trees in solids and streamers in liquids when the material is stressed by a fast transient. The similarity between the measured properties in solid and liquid phases leads to the conclusion that electrical treeing mainly takes place in the amorphous regions of the solid phase. [ABSTRACT FROM PUBLISHER]