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This letter summarizes a regional assessment of radiometric data products from the Ocean and Land Colour Instrument operated onboard Sentinel-3A. The assessment is supported by in situ reference measurements from the Ocean Colour component of the Aerosol Robotic Network and the Bio-optical mapping of Marine Properties Program. Results indicate a systematic underestimate of the water-leaving radiance at the blue and red spectral bands. Conversely, the aerosol optical depth at 865 nm exhibits overestimate, while the Angstrom exponent shows a narrow distribution of values confined below a maximum of approximately 1.7. These findings suggest difficulty in separating water and atmospheric radiance contributions, which results in a poor determination of aerosol load and type and, consequently, an overestimate of atmospheric effects.

Trends in the difference between primary satellite ocean-color products and in situ reference data at a coastal site are analyzed and presented. Investigated products are the normalized water-leaving radiance LWN and aerosol optical thickness τa from the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) and the Moderate-Resolution Imaging Spectroradiometer onboard the Aqua and Terra platforms (MODIS-A and MODIS-T, respectively). In situ reference data are from the Ocean-Color component of the Aerosol Robotic Network (AERONET-OC). Restricting the period of investigation to May 2002-April 2010 for SeaWiFS and MODIS-T and July 2002-June 2008 for MODIS-A, results do not indicate any statistically significant trend in the bias of LWN. Biases, determined at around the middle of the considered period, exhibit values from -0.4% to +7.7% for SeaWiFS and from -1.9% to +4.6% for MODIS-T in the 412-555-nm spectral interval. Higher and systematically negative biases from -15.4% to -6.2% are observed for MODIS-A in the same spectral interval. Statistically appreciable trends are observed for τa from SeaWiFS at 443 and 490 nm (approximately +1% per year) and from MODIS-A at 667 nm (+4.7% per year). The biases are very high for both MODIS-A and MODIS-T τa products in the 412-555-nm spectral interval (on average, +21% and +16%, respectively) when compared to SeaWiFS (exhibiting values between +1% and +4%).

A three-year time-series of radiometric data collected with an autonomous above-water system at the Acqua Alta Oceanographic Tower in the northern Adriatic Sea has shown its applicability for monitoring the trophic state of marine waters and its suitability for the validation of remote sensing products in coastal areas. Specifically, the radiometric data have been used to produce surface chlorophyll a concentration (Chla) by applying a regional algorithm proposed for the northern Adriatic Sea coastal waters. A comparison based on 41 match-ups between these Chla and reference values from high-performance liquid chromatography, has shown an average absolute difference of 32%. The comparison of Chla derived from remote sensing SeaWiFS and in situ above-water radiances has shown an average absolute difference of 21% for 183 match-ups, when the same regional algorithm is applied to both types of radiometric data.