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Start Over Author "Ken‐ichiro Awasaguchi" Journal heterocycles
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1. A New Synthetic Strategy for 2-Deoxy-D-ribose via Palladium(II)-Catalyzed Cyclization of Aldehyde

Author

Ikuyo Uoya, Hajime Yokoyama, Yoshiro Hirai, Ken‐ichiro Awasaguchi, and Masahiro Miyazawa

Subjects
Pharmacology, chemistry.chemical_classification, Anomeric effect, Stereochemistry, Organic Chemistry, Total synthesis, Tetrahydropyran, Carbohydrate, Aldehyde, Analytical Chemistry, chemistry.chemical_compound, chemistry, Intramolecular force, Hemiacetal, Stereoselectivity
Abstract

We achieved a total synthesis of 2-deoxy-D-ribose through intramolecular Pd(II)-catalyzed cyclization of aldehyde via an unstable hemiacetal intermediate as a key step.

Published
2010
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