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The southern Rheinisches Schiefergebirge, which is part of the Rhenohercynian zone of the Central European Variscides, exhibits several allochthonous units: the Giesen-, and the Horre nappe, and parts of the Frankenbach imbrication zone. These units were thrust over autochthonous and par-autochthonous volcano-sedimentary complexes of the Lahn and Dill–Eder synclines. This paper reports a representative data set of U–Pb LA–SF–ICP–MS ages of 1067 detrital zircon grains from Devonian and Lower Carboniferous siliciclastic sediments of the autochthonous and the allochthonous areas, respectively. The cluster of U–Pb ages from the allochthonous units points to a provenance in the Saxothuringian zone. Zircon populations from the Saxothuringian zone are representative of a Gondwanan hinterland and are characterized by age clusters of ~ 530–700 Ma, ~ 1.8–2.2 Ga, ~ 2.5–2.7 Ga, and ~ 3.0–3.4 Ga. Further samples were taken from the autochthonous and par-autochthonous units of the Lahn–Dill and Kellerwald areas. A Lower Devonian sandstone sample from the Siegen anticline provides a reference for siliciclastic sediments derived from the Old Red Continent. These samples show a provenance representative of Laurussia with debris primarily derived from Baltica and Avalonia. U–Pb zircon age clusters occur at ~ 400–450 Ma, 540–650 Ma, 1.0–1.2 Ga, ~ 1.4–1.5 Ga, ~ 1.7–2.2 Ga, and 2.3–2.9 Ga. Provenance analysis and geochemical data of the Rhenohercynian zone provide new information on the evolution of magmatic arcs in the Mid-Paleozoic. The data set constrains top-SE and top-NW directed subduction of the oceanic crust of the Rheic Ocean. Subduction-related volcanism lasted from the Early Devonian to the Early Carboniferous and thus confirms the existence of the Rheic Ocean until the Early Carboniferous. The tectonic model outlined for the Rhenohercynian zone suggests a wide Rheic Ocean.

Conodonts collected from sections near the small towns of Thong Pha Phum and Mae Sariang in the westernmost part of Thailand are used to reconstruct the neodymium (Nd) isotopic composition of seawater during the Late Devonian. The study provides the first Devonian seawater signatures recognized within the Australian shelf of northeastern Gondwana and the adjacent Paleotethys Ocean. At Thong Pha Phum site, the seawater was characterized by very low e Nd values (from − 13.1 to − 18.2) and very high Sm/Nd ratios (between 0.36 and 0.66). In contrast, the seawater at the Mae Sariang site was characterized by much more radiogenic signatures (e Nd values from − 8.7 to − 11.1) and uniform, low Sm/Nd ratios (between 0.20 and 0.23). Extremely low e Nd values recognized at Thong Pha Phum attest to a passive margin continental setting and a paleogeographic position very close to a continental area where Paleoproterozoic and Neoarchean rocks were eroded. Thus, the isotopic data provide strong evidence that during Late Devonian time the Sibumasu terrane was situated in the proximity to the Archean cratons of Western Australia, presumably adjacent to the Carnarvon intracratonic basin. Moreover, Sibumasu may not have been situated in an outboard position on the shelf, as previously suggested, but could have been directly attached to the Australian continental crust. By contrast, low and uniform Sm/Nd ratios of seawater at Mae Sariang resemble those of the Variscan and the present-day oceanic seawaters. Therefore, a pelagic setting within the Paleotethys Ocean is postulated for the Mae Sariang succession. This conclusion is also constrained by minor temporal changes in e Nd values and suggests that the Paleozoic of Mae Sariang is not part of the Sibumasu terrane but belongs to the Inthanon Zone.