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Determination of zircon ages as well as geochemical and Sm-Nd isotope systematics of granitoids in the Khetri Copper Belt of the Aravalli mountains, NW India, constrain the late Palaeoproterozoic crustal evolution of the Aravalli craton. The plutons are typical A-type within-plate granites, derived from melts generated in an extensional tectonic environment. They display REE and multi-element patterns characterized by steep LREE-enriched and almost flat HREE profiles and distinct negative anomalies for Sr, P and Ti. Initial εNd values range from -- 1.3 to -- 6.2 and correspond to crustal sources with mean crustal residence ages of 2.5 to 2.1 Ga. A lower mafic crustal anatectic origin is envisaged for these granitoids, and the heterogeneous εNd(t) values are inferred to have been acquired from the magma source region. Zircon Pb-Pb evaporation and U-Pb ages indicate widespread rift-related A-type magmatism at 1711-1660 Ma in the northern Delhi belt and also suggest a discrete older magmatic event at around 1800 Ma. The emplacement ages of the compositionally distinct A-type granitoid plutons, and virtually coeval granulite metamorphism and exhumation in another segment of the Aravalli mountains, further signify that part of the Aravalli crust evolved during a widespread extensional event in late Palaeoproterozoic time. [ABSTRACT FROM AUTHOR]

The Pelagonian Zone in Greece represents the westernmost belt of the Hellenide hinterland (Internal Hellenides). Previous geochronological studies of basement rocks from the Pelagonian Zone have systematically yielded Permo-Carboniferous ages. In this study we demonstrate, for the first time, the existence of a Precambrian crustal unit within the crystalline basement of the Pelagonian Zone. The U--Pb single-zircon and SHRIMP ages of these orthogneisses vary from 699 ± 7 Ma to 713 ± 18 Ma, which identify them as the oldest rocks in Greece. These Late Proterozoic rocks, which today occupy an area of c. 20 x 100 km, are significantly different from the neighbouring rocks of the Pelagonian Zone. They are therefore interpreted as delineating a terrane, named here the Florina Terrane. During the Permo-Carboniferous, Florina was incorporated into an active continental margin, where it formed part of the basement for the Pelagonian magmatic are. The activity of this arc was dated in this study by single-zircon Pb/Pb ages as having taken place at 292 ± 5 Ma and 298 ± 7 Ma. During the Alpine orogeny, Florina, together with the Pelagonian Zone, eventually became a constituent of the Hellenides. Geochemically, the Florina orthogneisses represent granites formed at an active continental margin. Because of the Late Proterozoic ages, this Late Proterozoic active continental margin can be correlated to a Pan-African or Cadomian arc. As the gneisses contain inherited zircons of Late to Middle Proterozoic age, the original location of Florina was probably at the northwestern margin of Gondwana. Similar to other Gondwana-derived terranes, such as East Avalonia, Florina approached the southern margin of Eurasia during Palaeozoic times, where it became part of an active continental margin above the subducting Palaeotethys. These interpretations further indicate that terrane accretion was already playing an important role in the early pre-alpine evolution of the Hellenides. [ABSTRACT FROM AUTHOR]

Whole-rock geochemical and Sm/Nd isotope data are presented for a representative suite of crustal rocks from the Pindos Ophiolite in order to resolve the origin of the geochemical signature of the boninites. Comparison is made with Triassic MORB from the Avdella mélange and with other ophiolitic rocks of northwestern Greece. Hydrothermal alteration results in large scatter in Sr and K and some variability in Ba, Th and U. The Pindos boninites contain high Zr and Hf with respect to REE, characteristic of many boninites. Pb, La/Sm and Nb decrease with decreasing TiO2 from MORB to IAT, but then increase in the boninites. Nd isotopic values expressed as end decrease systematically with decreasing TiO2, from 7-8 in IAT to 0.6-3.0 in boninites. As mantle wedge harzburgite became increasingly depleted, another magma source contributed significant amounts of Pb, REE and probably Nb. The Pb and other large-ion lithophile elements may have been transported in aqueous solutions from the subducting slab, but the REE and Nb imply an ocean-island basalt (OIB)-type source within the mantle wedge. This OIB source is a consequence of mantle plume activity during late Triassic rifting. [ABSTRACT FROM AUTHOR]

Because magmatism associated with subduction is thought to be the principal source for continental crust generation, assessing the relative contribution of pre-existing (subducted and assimilated) continental material to arc magmatism in accreted arcs is important to understanding the origin of continental crust. We present a detailed Nd isotopic stratigraphy for volcanic and volcaniclastic formations from the South Mayo Trough, an accreted oceanic arc exposed in the western Irish Caledonides. These units span an arc--continent collision event, the Grampian (Taconic) Orogeny, in which an intra-oceanic island arc was accreted onto the passive continental margin of Laurentia starting at ∼475 Ma (Arenig). The stratigraphy corresponding to pre-, syn- and post-collisional volcanism reveals a progression of εNd(t) from strongly positive values, consistent with melt derivation almost exclusively from oceanic mantle beneath the arc, to strongly negative values, indicating incorporation of continental material into the melt. Using εNd(t) values of meta-sediments that represent the Laurentian passive margin and accretionary prism, we are able to quantify the relative proportions of continent-derived melt at various stages of arc formation and accretion. Mass balance calculations show that mantle-derived magmatism contributes substantially to melt production during all stages of arc--continent collision, never accounting for less than 21% of the total. This implies that a significant addition of new, rather than recycled, continental crust can accompany arc--continent collision and continental arc magmatism. [ABSTRACT FROM AUTHOR]