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[Display omitted] • Marine emission possesses both environmental and human health risks. • Alternative fuels including hydrogen can reduce harmful emissions from marine transport. • Alternative fuels have the potential to promote UN Sustainable Development Goals. • The potential challenges of alternative fuel in marine transport are highlighted. The International Maritime Organization (IMO) has placed stricter controls on several aspects of global maritime transport operations to protect the environment. In light of this, the goal of this study is to examine and assess the different prospective paths and technologies that will assist the shipping industry in decarbonizing its operations. We consider how the utilisation of various alternative energy sources reduces greenhouse gas (GHG) emissions from marine transportation and contributes to the promotion of the United Nations Sustainable Development Goals (SGDs). The complexities associated with maritime industry operations using alternative energy sources are also explored. Biofuel as an alternative energy source, including biomethanol and biodiesel, can reduce greenhouse gas emissions in the shipping industry by 25% to 100%. However, the current supply of biofuels can only meet about 15% of the total demand which is not sufficient to sustainably power the entire marine fleet. There are several issues associated with these biofuels, including oxidation, ecological consequences, feedstock availability, technical and operational constraints, and economic factors that must be addressed before their full potential may be achieved. [ABSTRACT FROM AUTHOR]

• Novel conceptual methods for tuning microalgae to aviation biofuel were presented. • Conversion methods that directly act on wet algae biomass are highly desired. • Chemical methods are able to obtain a maximum lipid yield of 98% • Microalgae bio-jet fuel parameters are compiled with ASTM standards. • Zeolite catalytic pyrolysis increased the bio-oil yield from Microalgae to 80 %. Concerns have been raised about the effects of fossil fuel combustion on global warming and climate change. Fuel consumer behavior is also heavily influenced by factors such as fluctuating fuel prices and the need for a consistent and reliable fuel supply. Microalgae fuel is gaining popularity in the aviation industry as a potential source of energy diversification. Microalgae can grow in saltwater or wastewater, capture CO 2 from the atmosphere and produce lipids without requiring a large amount of land. As a result, the production of oil from microalgae poses no threat to food availability. The low carbon footprint of microalgae-derived fuels has the potential to mitigate the impact of traditional aviation fuels derived from petroleum on climate change and global warming. Therefore, aviation fuels derived from microalgae have the potential to be a more environmentally friendly and sustainable alternative to conventional fuels. Gathering microalgal species with a high lipid content, drying them, and turning them into aviation fuel is an expensive process. The use of biofuels derived from microalgae in the aviation industry is still in its infancy, but there is room for growth. This study analyses the potential routes already researched, their drawbacks in implementation, and the many different conceptual approaches that can be used to produce sustainable aviation fuel from microalgal lipids. Microalgae species with fast-growing rates require less space and generate lipids that can be converted into biofuel without imperiling food security. The key challenges in algal-based aviation biofuel include decreased lipid content, harvesting expenses, and drying procedure that should be enhanced and optimized to increase process viability. [ABSTRACT FROM AUTHOR]

• Second-generation feedstocks have potential to be used as aviation fuel. • A multicriteria decision analysis tool is used to assess the suitability of the feedstocks. • The fatty acid-based properties of more than 50% feedstocks meet international biofuel standards. • The modification of some fuel properties is needed to meet the strict aviation fuel standards. This paper examines the potential of suitable second-generation feedstocks for sustainable aviation fuel production, theoretically based on fatty acid-based fuel properties. The fatty acid composition of 38 s-generation feedstocks was collected from the literature. The fuel properties of these feedstocks were then calculated using empirical formula and assessed according to international fuel standards including American and European standards. The selected feedstocks were assessed and ranked using a multi-criteria decision analysis (MCDA) tool, i.e., PROMETHEE GAIA, to identify the suitability of the sources based on kinematic viscosity (KV), density (D), higher heating value (HHV), cetane number (CN), iodine value (IV), oxidation stability (OS), and cold filter plugging point (CFPP). It was found that 20 of the 38 feedstocks meet international fuel standards. The utilisation of the MCDA tool indicates that Ricinus communis is the highest-ranked feedstock for sustainable aviation fuel production, followed by the Azadirachta indica feedstock, with Sterculia feotida L. the lowest-ranked feedstock. The assessment of the properties of ranked feedstock against aviation fuel standards, including Jet A and Jet A1, reveals that the kinematic viscosity of all the feedstocks meets both these standards. However, fatty acid-based fuel properties could not satisfy the international aviation fuel standards for D, HHV, and freezing points. Further experimental work is recommended, including improvements in the processing and modification of biofuel produced from second-generation feedstocks. It is recommended that a comprehensive action plan is required to facilitate the introduction of sustainable biofuel from non-edible sources for the aviation industry, such as the adjustment of the current jet fuel standards. [ABSTRACT FROM AUTHOR]

• Physical and chemical pretreatment show great effectiveness but need huge energy. • Biological pretreatment can address most challenges but with long incubation times. • Hybrid technologies gain popularity and improve the chemical yield. • Pretreatment of lignocellulosic biomass account for 40% of total production costs. • Optimization of process parameters need for techno-economically feasible. As the world attempts to transition from fossil fuels, lignocellulosic biomass (LCB) serves as a promising alternative due to its high abundance. Hydrolysing LCB can generate various bioproducts, such as biofuels and value-added chemicals. However, the presence of lignin inhibits the solubilization of LCBs, presenting a major techno-economic challenge in the biorefinery concept. Therefore, this paper addresses the gaps left by most of the recent review works that fail to comprehensively review different pretreatment methods and the full scope of applications of LCBs, and do not incorporate techno-economic considerations of the technologies, the latter being the greatest bottleneck in the commercialization of the processes. The literature review revealed that while many of the physical and chemical pretreatment methods exhibit great effectiveness, they have a huge dependence on energy, chemicals, water, and/or specialized equipment, and produce harmful waste and inhibitory compounds. The pretreatment of lignocellulosic biomass can account for 40% of total production costs. Biological pretreatment can address these challenges but is limited by long incubation times. For instance, the bacterial pretreatment can noticeably reduce sawdust cellulose, hemicelluloses, and lignin contents by 35.8%, 37.1%, and 46.2%, respectively. Recently, integrated/coupling (hybrid) methods, such as chemical-assisted liquid hot water/steam and microwave or ultrasound-assisted alkaline pretreatment, have been gaining popularity due to their potential to improve chemical yield, but at the expense of the high cost of operation. To make pretreatment processes more techno-economically feasible, there is a need for process integration and the standardization and optimization of process parameters. [ABSTRACT FROM AUTHOR]

[Display omitted] • Biorefinery concept for sustainable processing of microalgae biomass has been discussed. • Reactor technologies for cultivating microalgae has been reviewed. • Factors affecting the microalgae culture system has been reviewed. • Different technologies to convert microalgae into biofuel and value-added products have been presented. • The utilisation of a biorefinery concept can make the valorisation of microalgae economically viable. Microalgal biomass has been proved to be a sustainable source for biofuels including bio-oil, biodiesel, bioethanol, biomethane, etc. One of the collateral benefits of integrating the use of microalgal technologies in the industry is microalgae's ability to capture carbon dioxide during the application and biomass production process and consequently reducing carbon dioxide emissions. Although microalgae are a feasible source of biofuel, industrial microalgae applications face energy and cost challenges. To overcome these challenges, researchers have been interested in applying the bio-refinery approach to extract the important components encapsulated in microalgae. This review discusses the key steps of microalgae-based biorefinery including cultivation and harvesting, cell disruption, biofuel and value-added compound extraction along with the detailed technologies associated with each step of biorefinery. This review found that suitable microalgae species are selected based on their carbohydrate, lipid and protein contents and selecting the suitable species are crucial for high-quality biofuel and value-added products production. Microalgae species contain carbohydrates, proteins and lipids in the range of 8% to 69.7%, 5% to 74% and 7% to 65% respectively which proved their ability to be used as a source of value-added commodities in multiple industries including agriculture, animal husbandry, medicine, culinary, and cosmetics. This review suggests that lipid and value-added products from microalgae can be made more economically viable by integrating upstream and downstream processes. Therefore, a systematically integrated genome sequencing and process-scale engineering approach for improving the extraction of lipids and co-products is critical in the development of future microalgal biorefineries. [ABSTRACT FROM AUTHOR]

• Seaweed, a marine biomass, identified as an underutilized renewable resource with potential for biofuel. • Seaweed conversion demonstrated to aid carbon sequestration, nutrient recycling, and waste management. • Marine biomass utilization seen as promising yet intricate pathway to global sustainability. • Future research proposed to involve rigorous feasibility analysis and interdisciplinary collaboration. Amid the global energy crisis and environmental concerns, marine biomass, specifically seaweed, serves as a type of marine biomass with potential for conversion into sustainable energy in alignment with the United Nations Sustainable Development Goals (UN SDGs). There is a pressing need to shift towards sustainable energy resources, and seaweed emerges as an underexplored renewable energy source. A thorough analysis of past, current, and emerging trends in seaweed biomass conversion takes place. Thermochemical processes and other conversion methods are detailed, evaluating their efficiencies, limitations, and advancements. Due to its rapid growth and rich carbohydrate content, seaweed proves to be a prime candidate for bioenergy production. Converting seaweed aids in carbon capture, nutrient recycling, and waste management, which positively impacts several UN SDGs. Challenges, including technological barriers, economic feasibility, and environmental concerns related to large-scale seaweed farming and energy conversion, are present. The potential of marine biomass, especially seaweed, in sustainable energy production becomes evident, highlighting its intricate nature. Advancements in conversion technologies, thorough life-cycle assessments, and stringent sustainability protocols are recommended. Future efforts should concentrate on in-depth feasibility studies and foster inter-disciplinary collaborations to address the multifaceted challenges of this energy transition, aligning it with the UN's sustainability aspirations. [ABSTRACT FROM AUTHOR]

• Implications for efficient pyrolysis processes using municipal green waste. • Potential for increased process economics and sustainability. • Optimal parameters boost bio-oil yield (52.8%) and energy efficiency (72.9%). • Holding time enhances bio-oil and syngas yields, while decreases biochar yields. • Smaller feedstock particle size leads to higher energy and exergy efficiency. This study aims to determine how different operating conditions for a fast pyrolysis process employing municipal green waste (MGW) in an auger reactor affect product yields, overall energy efficiency, and total exergy efficiency. In this study, a range of pyrolysis conditions, including temperatures from 400 to 600 °C (in 50 °C increments), holding times from 1 to 5 min (in 1-minute increments), and feedstock particle sizes from 2 to 10 mm (in 2-mm increments) were used. MGW and pyrolysis products were characterised using separate pieces of equipment and in accordance with applicable ASTM standards. The results demonstrate that a yield of 52.8% for bio-oil and a yield of 23.7% for syngas can be achieved at temperatures of 500 and 600 °C, respectively. At 400 °C, the biochar production was highest as 21.5%. Bio-oil and syngas yields improved with holding times, whereas biochar yields declined. At a feedstock particle size of 2 mm, the overall energy efficiency was at its maximum (72.9%), while the total exergy efficiency was also at its highest (68.4%). As feedstock particle size increased, overall energy efficiency and total exergy efficiency dropped. In conclusion, this study provides valuable insights into the effects of different operating parameters on the pyrolysis process using MGW, which can be used to optimize the process and increase its efficiency. [ABSTRACT FROM AUTHOR]

[Display omitted] • Rice bran biodiesel is produced using ultrasound and infrared radiation. • ANN-GWO is a reliable tool to optimize the transesterification process. • The predicted rice bran yield is 98.16%. • The optimum yield obtained from the experiment is 97.74%. • The FAME content of the optimized biodiesel is 95%. A system combining ultrasound and infrared radiation was used to increase the chemical reactions between incompressible reactants by enhancing their mass transfers with the aim to reduce the energy usage and reaction time. In this study, biodiesel from RBO was produced via transesterification, and the process variables were optimized using the combination of ANN and GWO algorithm. Process parameters considered in this study are ratio of methanol to oil, catalyst concentration, and reaction time. Based on the ANN-GWO algoritm used, the optimum conditions for the process parameters were (1) methanol to oil ratio: 60%, (2) concentration of catalyst: 1 wt%, (3) time: 7.76 min, leading to the metyl ester yield of 98.16 wt%. The algoritm was verified by conducting a triplicate independent experiments using the suggested optimum values, resulting in an average methyl ester yield of 97.74 wt%. Subsequently, properties of rice bran biodiesel were compared to ASTM D6751 and EN 14214 standards, and the obtained values met both the standards. [ABSTRACT FROM AUTHOR]

[Display omitted] • Thermal degradation behavior, kinetic and thermodynamic analyses of surface fibers of date palm. • Kinetic analysis was performed on the devolatilization region using the Coats–Redfern model–fitting method. • Surface fibers pyrolysis governed by two diffusion models: one–way transport and Valensi equation. • E a and A were estimated to be 91.40 kJ/mol and 1.59 × 103 –29.39 × 103 min−1, respectively. The potential of the least-exploited date pam waste was presented as feedstock for bio-oil production. The surface fibers of the date palm are widely available as waste material in the Gulf region, the Middle East, and Africa. Chemical composition analysis and physiochemical characterization showed that surface fibers are valuable feedstock for energy production. Surface fibers were analyzed thermogravimetrically at different heating rates (10, 20, and 30 °C /min) in an inert atmosphere. Decomposition was carried out in three stages: dehydration, devolatilization, and solid combustion. Kinetic analysis was performed on the devolatilization region using the Coats–Redfern model–fitting method using twenty–one reaction mechanisms from four different solid-state reaction mechanisms. Two diffusion models: one–way transport (g(x) = α2) and Valensi equation (g(x) = α+(1-α) × ln(1-α)) showed the highest regression coefficient (R2) with the experimental data. The activation energy (E a) and the pre-exponential factor (A) was estimated to be 91.40 kJ/mol and 1.59 × 103 –29.39 × 103 min−1, respectively. The kinetic parameters were found to be dependent on the heating rate. The surface fibers' thermodynamic parameters ΔH, ΔG, and ΔS were 80–97, 151–164, and −0.17- −0.18 kJ/mol, respectively. This indicates that the pyrolysis of surface fibers is endothermal and not spontaneous. Since there is not much experimental work on the pyrolysis of surface fibers available in the literature, the reported results are crucial for designing the pyrolysis process. [ABSTRACT FROM AUTHOR]

[Display omitted] • Conversion of toxic and hazardous Zanthoxylum armatum seed into biodiesel. • Catalytic application of green nanoparticles of silver oxide has been discussed. • Use of Central Composite Design for optimization reactions of transesterification. • Characterization of nanoparticles using analytical techniques. The cleaner and sustainable production of biodiesel from toxic and hazardous non-edible seed oils offer a remarkable opportunity to deal with energy crises and provide a renewable substitute to depleting fossil fuels. In the current study, the potential of the novel, toxic and non-edible seed oil of Zanthoxylum armatum was investigated for eco-friendly production of biodiesel catalysed by green nanoparticles of silver oxide. Silver oxide nanoparticles were synthesised with aqueous leaf extract of Silybum marianum. Heterogeneous green nanocatalysts were preferred due to their recyclable nature and easy recovery. The maximum yield of 95% of methyl ester was obtained at optimum reaction conditions of oil to methanol molar ratio 1:7, catalyst loading 0.5 (wt.%), reaction temperature 90 °C and reaction time 2 h. Characterisation of synthesised nanoparticles of silver oxide was carried out with X-Ray diffraction (XRD), scanning electron microscopy (SEM), and energy diffraction X-ray (EDX). Fourier-transform infrared spectroscopy (FTIR) and nuclear magnetic resonance (NMR) confirmed the formation of methyl esters. 5, 8-octadecenoic acid was found to be the major fatty acid methyl ester in the biodiesel sample. Fuel properties of biodiesel were investigated and found comparable to international standards of ASTM D-6571 and EN-14214. It was concluded from the current investigation that Zanthoxylum armatum is a potential biomass feedstock for the sustainable production of biodiesel using green nanoparticles of silver oxide. [ABSTRACT FROM AUTHOR]

• Food waste is a potential source of sustainable gaseous biofuel. • Anaerobic digestion is an efficient technology to convert food waste into fuel. • Turning food waste into energy can assist the decarbonisation of the economy. • Converting food waste into sustainable fuel can significantly lower the GHG emission. Food waste is a type of organic waste generated by restaurants, food processing plants, households, and commercial and institutions. This study aims to assess the sustainable biofuel, electricity production and greenhouse gas emission reduction potential of food waste using anaerobic digestion technology. Food waste data was collected from the Australian government database to estimate the biomethane and biogas yield and to evaluate the opportunities to convert the biomethane into electricity and heat. This study found that food waste can yield 47% biomethane and hence for Australia, an estimated total of 0.07 million m3 to 1.54 million m3 of biogas can be produced and up to 414,898 tonnes of greenhouse gas emissions reduced annually. The study also estimated that the generated biogas can replace fossil fuel-based electricity generation of up to 52.36 GW and 554.4 TJ heat per year. The environmental assessment indicated that the complete conversion of food waste can lower greenhouse gas emissions (GHG) by up to 5,07,434 tonnes per year and Australia can earn about $52.38 M revenue from electricity production. Therefore, conversion of food waste into biofuel through the anaerobic digestion process can play a significant role in generating electricity from non-fossil-based sources, reducing GHG emissions and earning revenue. [ABSTRACT FROM AUTHOR]

• High dependency on fossil fuel as main energy source brings excessive CO 2 emission. • CO 2 and CH 4 utilization is one of the solutions to mitigate climate change. • Alternative energy technology has potential in meeting the increasing energy demand. • Four main technologies that used to mitigateclimate change is reviewed. • Their mechanism, limitations, and suggestions for up-scaling purpose are highlighted. The excessive global emission of greenhouse gases (mainly carbon dioxide, CO 2 and methane, CH 4), especially due to the burning of fossil fuel for energy and power generation, is the main cause to the air pollution and greenhouse effect. This has eventually brought many issues, such as climate change and global warming, that will affect the standard life of human beings. Many strategies have been proposed to further reduce the excessive emission of greenhouse gases, including CO 2 and CH 4 utilization. This method not only reduce the CO 2 concentration in the atmosphere, but also producing renewable energy (syngas) at the same time. Hence, CO 2 and CH 4 utilization is also a promising approach to assist in overcoming the energy crisis due to the increasing population in time. Basically, the utilization of CO 2 and CH 4 system can be categorized into four: (i) electrochemical reduction, (ii) advanced catalyst system, (iii) photocatalytic reduction, and (iv) plasma technology. In this review paper, the mechanism implemented on the four abovementioned categories and their respective limitations are presented. Besides, future recommendations to optimize the greenhouse gases utilization system for up-scaling purpose is also highlighted. [ABSTRACT FROM AUTHOR]

Today renewable energies such as biodiesel have considerable role in the bio-based economy. Long production time and low efficiency are a number of problems in biodiesel production that is essential to be considered when designing and operating the biodiesel production systems. In this study, using safflower oil in a hydrodynamic cavity reactor, biodiesel fuel was produced in the possible shortest time and maximum efficiency. The effect of reaction time (30, 60 and 90 s), concentration of potassium hydroxide catalyst (0.75%, 1% and 1.25%), alcohol to oil ratio (6, 8 and 10) and rotor-stator distance (1 cm, 2 cm and 3 cm) on the reaction yield were analyzed. The results were analyzed by response surface methodology. Among the independent variables, reaction time was the most important factor on the reaction yield, which had a positive impact on the quality of methyl ester. The optimum values obtained were: 63.88 s reaction time, 0.94% catalyst concentration, 1: 8.36 alcohol to oil molar ratio, 1.53 cm rotor-stator distance, and 89.11% yield. Several properties and compounds of biodiesel obtained were measured and compared with ASTM D6751 (American Society for Testing and Materials) and EN 14214 standard (European Standards). The results showed that most of the features conform to the afore-mentioned standard. Therefore, transesterification of safflower oil with a hydrodynamic cavitation reactor can function as a good alternative to the diesel. [ABSTRACT FROM AUTHOR]

• Impact of water – biodiesel – diesel nano-emulsion fuel on diesel engine parameters investigated. • Nano-emulsion fuel generated less power and torque than diesel. • NO emission of nano-emulsion fuel decreased 9.06% than diesel. • Diesel nano-emulsion fuel is a satisfactory alternative to fossil diesel fuel in diesel engines. The use of emulsion fuel in the engine has been reported as an effective solution to reduce the harmful emission. This experimental study examined the effects of nano-emulsion biodiesel fuel on engine efficiency, gas emission parameters and combustion parameters of a single-cylinder air-cooled diesel engine. Nano-emulsion fuel made of 5% waste cooking oil biodiesel and 5% distilled water were used to test the performance of the diesel engine. This fuel was produced using ultrasonic waves by stabilizing 5% by volume tween 80 and spans 80 surfactants in HLB8 (Hydrophilic-Lipophilic Balance). Performance parameters and pollutants emission of a diesel engine using nano-emulsion fuel were compared with emulsion fuel. This test was performed on four different engine loads (25%, 50%, 75%, and 100%) at different speeds of 1700, 2000, 2300, and 2600 rpm. Power, torque, cylinder pressure levels, and emissions including soot opacity, carbon monoxide (CO), unburned hydrocarbon (UHC), carbon dioxide (CO 2), and nitrogen oxides (NO X) were measured. The test results show that diesel engine power and torque using nano-emulsion fuel improved by about 4.84% and 4.65% compared to emulsion fuel, respectively. The use of nano-emulsion fuel significantly decreased CO (~11%), UHCs (~6%), NOx (~9%) and soot opacity (~10%) emission. However, a small rise in CO 2 (~7%) emission was observed. The combustion result shows that nano-emulsion fuel creates more cylinder pressure (CP) than emulsion fuel during combustion. The highest CP was recorded at 10° crank angle after the top dead centre with diesel fuel. Finally, nano-emulsion fuel can be a satisfactory alternative to diesel fuel in a diesel engine without having to change the engine. [ABSTRACT FROM AUTHOR]