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This study examined the natural dyeing properties of hemp fabrics using a mixed mordant consisting of aluminum potassium sulfate (10 and 20 g/L) and tannic acid (5 and 10 g/L). The natural dye was derived from jackfruit wood (Artocarpus heterophyllus) and then processed into a powder via spray drying. The fabrics were dyed using 10% owf dye, at a pH of 5, temperature of 80 °C, for 50 min, with a liquor ratio (L:R) of 1:30. Prior to dyeing, mordanting was applied to improve dye uptake. The mordanting process compared three distinct heating techniques: infrared heating (IRH), ultrasonic heating (USH), and microwave heating (MWH). The X-ray diffraction results showed that MWH was the only heating technique that maintained the crystallinity index ( CI ) of the fibers. However, it produced slightly lower color strength ( K / S of 1.01 ± 0.01) compared to IRH ( K / S of 1.36 ± 0.04) and USH ( K / S of 1.32 ± 0.04). IRH exhibited the most significant reduction in the CI , followed by USH. The sample treated with IRH had the highest aluminum content (0.88 ± 0.02%), whereas the MWH-treated sample had the lowest (0.75 ± 0.02%), which is consistent with the results concerning CI and K / S . The ratings for color fastness to washing, light, and rubbing were generally favorable. Mordanting enhanced both the color fastness and the color strength of the fabric, but it did not affect the tensile properties of the fabrics. Mordanting and dyeing slightly enhanced the ultraviolet protection efficiency of the fabrics. However, all samples, including the pristine hemp fabric, provided excellent protection against ultraviolet radiation. [ABSTRACT FROM AUTHOR]

In this research, natural dyeing studies were conducted using indigo, and dyeability was compared using sodium hydroxide, calcium hydroxide, and calcium carbonate as bases. As a reducing agent, sodium hydrosulfite and glucose were compared. For a more environmentally friendly method, 3D-printed thermoplastic polyurethane (TPU) materials were dyed with natural indigo using glucose as the reducing agent and calcium hydroxide as the alkali. The dyeability of TPU materials was investigated under various conditions. The color fastness to light, rubbing, and washing of dyed 3D-printed TPU materials were investigated. At a 15 g/l glucose concentration and a 10 g/l calcium hydroxide concentration, the K/S value increased significantly, showing the color of the PB series. The K/S value tended to increase as dyeing temperature, dyeing time, and indigo dye concentration increased. However, the effect of indigo dye concentration was not significant, and there was no significant increase after the dyeing temperature was 90 °C and the dyeing time was 60 min. The color fastness to light was poor, but for washing and rubbing the fastness was good. Therefore, it was confirmed that more environmentally friendly 3D-printed TPU material dyeing is possible by indigo dyeing using glucose by replacing sodium hydrosulfite. [ABSTRACT FROM AUTHOR]

In this study, to evaluate color emotions and color preferences of cotton fabric having two different colored portions with contrast tones by dyeing with persimmon and indigo, respectively, six different stimuli were prepared with variations of contrasting tone types and color area ratios and they were subjectively assessed by inviting female college students in fashion and textiles. The factor analysis results showed four different factors including 'Light', 'Gentle', 'Traditional', and 'Dynamic' and they were revealed as effected by contrasting tone types such as 'pale-dull' and 'light-dull' and by color area ratios such as 1:1, 2:1, and 1:2 as well as objective colorimetric combination variables. Precisely the type of 'pale-dull' contributed to stronger feeling of factor 'Light' and 'Gentle' and the ratio of 2:1 evoked more perception of 'Light'. Color preference was more highly rated for 'pale-dull' and as Δ a p ∗ as a colorimetric combination variable was higher. Finally color emotion factor such as 'Light' and 'Traditional' and color preference were quantitatively described by modeling each of them with some of objective colorimetric combination variables. [ABSTRACT FROM AUTHOR]

The goal of this study is to present an environmentally benign route for cotton fabric and investigate the effect of different pretreatments in natural dyeing. In this context, conventional alkaline scouring, conventional hydrogen peroxide bleaching, low-temperature one-step biopreparation processes, namely enzymatic scouring (alkaline pectinase and alkaline pectinase-neutral cellulase combination) at 55 °C and enzyme-bleaching agent (hydrogen peroxide/sodium percarbonate/sodium perborate)-activator agent (TAED) combinations at 65 °C were applied to 100% cotton knitted fabric. The use of agricultural waste and eco-friendly mordants was preferred in natural dyeing. For this purpose, pretreated fabrics were dyed with the outer green shell of almond fruit extracts and a low amount of 0.4 g/L metal mordants (alum and iron(II) sulfate) in accordance with the simultaneous mordanting method. The dyeing properties of bio- and conventionally prepared cotton fabrics were examined in terms of colorimetric data (K/S, CIELa*b*C*h°) and wash fastness compared with water absorbency, whiteness, weight loss, pectin removal, and type of mordant. Excellent wash fastness values were achieved regardless of the type of pretreatment. Low-temperature one-step biopreparation can be a good substitute for conventional scouring and bleaching processes. Since different results can be achieved, it is essential to determine and evaluate all bioprocess conditions depending on the end-use characteristics of the textile (e.g. whether it will be white or dyed/printed, its color and lightness/darkness) at the laboratory and industrial scale applications. [ABSTRACT FROM AUTHOR]

The research reported in this paper concerns the examination of the ability to dye cotton textiles with plant-derived colorants in the presence of various natural additives. For this purpose, cotton textile samples were dyed with commercially available plant-derived dyes, which are usually used for food application, using a cold dyeing process in acidic conditions. The natural origin additives which were applied during the dyeing process were cosmetic grade and low molecular weight chitosan, nettle extract and shellac in an ethanol solution. The dyed fabrics were analyzed using FTIR spectroscopy, and the mechanical properties were tested to study the influence of colorants and additives on cotton textile properties or the dyeing process. Furthermore, the color stability under the influence of UVC irradiation was studied, using a colorimeter. The obtained results indicated that applied plant-derived colorants may effectively dye natural fabrics, such as cotton. The application of natural additives had a beneficial influence on cotton textile properties and the dyeing process. The pretreatment of cotton with chitosan, nettle extract or shellac improves the color stability following UVC irradiation of the material. Moreover, those additives can influence the mechanical properties of cotton textiles. Further research, however, is required to develop the most favorable dyeing conditions in each case. [ABSTRACT FROM AUTHOR]

The research aimed to dye silk satin textiles with a plant-derived colorant in the presence of additives of natural origins, such as chitosan and shellac, to investigate whether they can dye silk textiles with satisfactory results. In this study, a series of mechanical properties (Young modulus, elongation at break, and tensile strength), and colorfastness following exposure to UVC irradiation and 6 months of storage of dyed silk textiles samples were tested. Colorimetric measurements and scanning electron microscopy (SEM) images were performed and FTIR spectra were registered. Results indicated that the plant-derived colorant used in this research had the potential to dye silk satin textiles with satisfactory results. Colorant with the addition of chitosan and shellac dyed silk textiles more intensely, shellac covering ensured their color stability following UVC irradiation and during storage while the addition of chitosan did not particularly affect the color stability under the influence of UVC irradiation. However, pre-treatment with low molecular weight chitosan improves colorfastness during storage. Both additives influenced the mechanical properties of dyed silk textiles. [ABSTRACT FROM AUTHOR]

This study was conducted to develop an effective mordanting method for black color expression of silk and cotton fabrics using the neutral extract (NE) of Pinus radiata bark and various iron mordants. Also, mordanting characteristics of iron salts in equimolar concentrations were evaluated. The mordanting was carried out in methods of pre-, post-, and pre- and then post-mordanting in one process with ferrous sulfate (FeSO4), ferrous chloride (FeCl2), ferrous acetate (Fe(CO2CH3)2), ferrous lactate (Fe-lac, Fe(CH3CH(OH)CO2)2, ferric sulfate (Fe2(SO4)3), and ferric chloride (FeCl3). The mordant concentration was 1 mM o.w.f. (on the weight of fabric); 0.5 mM for Fe2(SO4)3. The colors of mordanted silk fabrics ranged from dark brown to black and that of mordanted cotton fabric were in the range of light grayish-brown to gray. Using ferrous ion (Fe2+) and post-mordanting methods led to the expression of darker colors and the divalent and trivalent cations (Fe ions) were found to influence dark color expression. The color of silk fabric in the presence of the combination of Fe2(SO4)3 pre- and Fe-lac post-mordanting (PSPL) was closest to the silk fabric dyed with synthetic black dye. Based on the colorfastness assessment, an increase in the light fastness of PSPL silk fabric was observed along with a decrease in the rubbing fastness compared to the non-mordanted silk. [ABSTRACT FROM AUTHOR]

This research paper is focused on the dyeing of silk fabrics with a natural dye extracted from Celosia flower and banana pseudostem sap as a biomordant. The dyeing process was carried out by three different techniques i.e. pre-, post-, and simultaneous mordanting method. The effect of dyeing process parameters namely mordant concentration, pH, and temperature on the dye absorption and fastness properties of dyed silk fabric have been investigated for each dyeing method. Optimal values of dyeing process parameters have been categorized based on the highest value of dye absorption in terms of K/S value. Optimum mordant concentration was found to be 18 % for all sets of dyeing methods. The optimum pH was examined to be 4.5, 4.0, and 4.0 and dyeing temperature was 70 °C, 70 °C, and 65 °C for the pre-, post-, and simultaneous mordanting dyeing methods, respectively. The color fastness to light, washing, and rubbing of dyed silk fabrics was investigated. Fastness values of light and rubbing showed fair-to-good fastness level, whereas the color fastness to washing was found to be good to very good. The antibacterial activity of the banana sap mordanted and simultaneously dyed silk fabrics was evaluated. The dyed silk fabric exhibited moderate antibacterial activity against gram-positive and gram-negative bacteria. [ABSTRACT FROM AUTHOR]

Today's men are experiencing an unprecedented technological advance allowing the use of increasingly large chemical dyes. However, a recent fashion trend continues to grow and results in a return to nature: The idea is to combine well-being and ecology for man and his environment. In this context, several natural resources have been exploited as dyes for textile fibers. In this paper, a singular interest is brought to the fruits extract of Phytolacca americanna L. which was valued in the dye of wool yarns. Hence, the dye extracts and the primary color components of the fruits extract of Phytolacca americanna were analyzed. The color features of the extract under different pH conditions, the influence of temperature on dyes stability, the FTIR spectral analysis, and their application in wool yarns dyeing were studied. In addition, the dyeing performances of wool yarns with the fruits extract of Phytolacca americanna under different conditions (dyeing temperature, dyeing pH, and dyeing duration) are presented. The best dyeing results were obtained at pH 2, 45 min, and 90 oC. Besides, bio-mordanting processes were applied to enhance the dye depth and improve the fastness properties of the dyed wool yarn. Various shades and better fastness were obtained. [ABSTRACT FROM AUTHOR]

In this study, Berberis vulgaris L. wood as an agricultural waste was used for dyeing and functional finishing of cotton. To facilitate the attachment of natural dye, citric acid was used to create carboxylic acid functional groups on cotton fibers. The process of crosslinking of cotton fabric with citric acid was optimized in order to obtain the maximum dyeability with the cationic natural dye. The effects of three important factors including citric acid concentration, sodium hypophosphite concentration and curing temperature on the color strength of the dyed samples with woods of barberry tree were analyzed by response surface methodology and the optimum conditions for obtaining the highest color strength was obtained. The crosslinking of citric acid on cotton fibers was confirmed by FTIR spectroscopy. The dyed sample prepared under the optimum conditions of crosslinking showed good wash and light fastness properties besides very good antibacterial activity against gram-negative and gram-positive bacteria. [ABSTRACT FROM AUTHOR]

In this work, the natural dyeing behavior of woollen yarn with madder (Rubia tinctorum L.) root extract was studied. The effects of different tannin-rich plants (Rhus coriaria, Eucalyptus, Terminalia chebula, Quercus castaneifolia, Pomegranate) extract as biomordants and alum (as a chemical mordant) with two mordanting procedures (pre- and metamordanting) on color characteristics of the dyed samples were also investigated. The CIEDE2000 values, color strength (K/S), washing fastness and tensile property of the mordanted and dyed samples were assessed. Visually, a range of hues from orange to brownish-red were obtained. In general, pre-biomordanted samples with Rhus coriaria (10 %owf), Eucalyptus (10 %owf), Terminalia chebula (5 %owf), Quercus castaneifolia (5 %owf) and Pomegranate (5 %owf) showed almost the same color difference (ΔE00) and wash fastness values compared to those treated with 3 %owf alum. Finally, it was concluded from the comparative studies that the biomordants have good potential to be considered as alternatives to the common chemical mordants. [ABSTRACT FROM AUTHOR]

The use of natural dyes and natural finishes on textiles has become a matter of significant importance because of the increased environmental awareness to avoid some hazardous synthetic dyes and synthetic chemicals. The Delonix regia stem shells were extracted in distilled water methanol and ethanol solvents. Phytochemical analysis was carried out for the presence of bioactive chemical constituents such as saponin, terpenoid, flavonoid, glycoside, phenol and tannin using the standard procedure. All the tests showed positive for the presence of components except saponin in methanol and ethanol extract. The qualitative antibacterial analysis was done by AATCC 147 method with excerpts from three different solvents both against S. aureus (gram-positive) and E. coli (gram-negative) bacteria. Delonix regia stem shell extract (DSE) in distil water was used for natural dyeing of mulberry silk fabric. Pre-mordanting and post-mordanting of silk fabric were carried out using alum and myrobalan mordants. Treated fabrics showed a substantial increase in colour depth ( K/ S) and adequate wash, light and rubbing fastness properties without and with mordanted and dyed silk fabrics. Quantitative antibacterial analysis by AATCC 100 method was done on dyed silk fabric which showed very good resistance both against bacteria S. aureus and E. coli bacteria. Dyed silk fabric also showed good to very good ultraviolet (UV) protection property. The physicochemical composition of the untreated and without mordant treated silk fabrics were analysed by attenuated total reflection (ATR) Fourier transforms infrared (FTIR) spectroscopy, scanning electron microscope (SEM), energy dispersive spectrometry (EDS) and atomic absorption spectrophotometer (AAS). In addition to that wash, durability was also measured of dyed silk fabric for antibacterial and ultraviolet protection (UPF) properties according to AATCC 61 2A washing method. [ABSTRACT FROM AUTHOR]

The current study is the first report of using biomordants with prina extract as a possible substitute for environmentally unfavourable metallic mordants. As a part of sustainable and cleaner production approach, eco-friendly natural dyeing conditions were presented in terms of cost and consumption efficiencies. A novel and renewable natural dye source prina is an essential by-product of olive oil production. This biomass was valorized in wool dyeing in conjunction with biomordants namely powder of iris germanica (I. Versicolor), valex (acorn of Quercus ithaburensis ssp.macrolepis), pomegranate (Punica granatum L.) rind, rosemary (Rosmarinus officinalis), and thuja (thuja orientalis). Their color coordinates and fastness properties were compared and assessed versus metallic mordants. Prina extract itself without mordant has a fair light fastness of 3 and an excellent washing fastness of 4-5 both for color change and bleeding. Valex, pomegranate rind, iris, rosemary, and thuja leaves were proposed as promising alternatives to alum, iron II sulfate, copper II sulfate, stannous chloride, and potassium dichromate. Biomordants generated significant color yield increment and exhibited equivalent fastness properties to metallic mordants. Water, energy, dye, chemical cost, and consumption of natural and synthetic dyeings on the basis of mill conditions were also calculated and compared mutually. Total recipe cost and chemicals/auxiliary consumption of natural dyeing are on average significantly less than with synthetic dyeing. Considerable savings are possible with natural dyeing, especially one-bath, in terms of cost, time, and consumption. [ABSTRACT FROM AUTHOR]

In this research we investigated the dyeing of cotton fabrics with extracts of Xylocarpus granatum, a mangrove plant with a long history of use in leather tanning and textile dyeing. X. granatum bark was extracted and spray-dried, yielding a tannin-rich, reddish-brown powder. This powder proved a suitable colorant for the natural dyeing of cotton with promising color fastness properties to wet treatments (washing, water, sea water, and perspiration), hot pressing, crocking, and light exposure. However, the dye alone produced only weak levels of coloration and therefore metallic salt mordants were employed to improve the color strength, through the formation of insoluble tannate complexes. The resulting fabric K/ S values were dependent on the mordant used and exhibited the following trend: ferric sulfate > sodium dichromate > copper sulfate > potassium aluminum sulfate > no mordant, for fabrics exposed to mordants before and after dyeing. Mordanting resulted in slight variations in shade and color fastness. In most cases, the color fastness properties were preserved, except for color fastness to light and hot pressing, for which lowered ratings were found for some mordants. Stiffness and mechanical performance were not greatly affected by dyeing or mordanting, except for sodium dichromate mordanting which significantly stiffened and weakened the fabric. The ultraviolet protection factor ( UPF) of all the dyed samples achieved the maximum (50+) level, highlighting the excellent UV shielding properties of the fabric. Overall, X. granatum bark extract is a promising, effective colorant for the natural dyeing of cotton in terms of appearance, fastness, and physical characteristics. [ABSTRACT FROM AUTHOR]

A new approach for dyeing and functional finishing for cotton fabric using Henna extract and TiO nano-sol was investigated. In this study, 3-chloro-2-hydroxy propyl trimethylammonium chloride was used to substitute metallic mordants (heavy-metal salts) in pre-treating cotton fabric. This eventually will prevent heavy metal pollution as well as obtain dyeing without addition of salt. TiO nano-sol was prepared by sol-gel method using different amounts of tetraisopropyl orthotitanate (TTIP) and applied on cationized cotton fabrics using the same finishing formulation and treatment sequence. Treated fabrics were then dyed with Henna extract at different dyeing temperatures (60 ℃, 80 ℃, and 90 ℃). TiO nanoparticles were characterized by transmission electron microscopy (TEM). The chemical and morphological structures of the dyed fabrics were characterized by attenuated total reflection-Fourier transform infrared (ATR-FTIR), scanning electron microscopy (SEM), and X-ray diffractometry (XRD). Color strength, fastness properties (washing, rubbing, and light), UV-blocking, antibacterial activity, and tensile strength were investigated. Samples treated with TiO and dyed with Henna extract exhibited outstanding enhancement in both the UV protection and antibacterial efficacy with minimal impact on color depth and tensile strength. Enhancement or decrement in the UV protection, antibacterial activity and dyeing properties are governed by the amount of TTIP and the dyeing temperature. [ABSTRACT FROM AUTHOR]

Although madder ( Rubia tinctorum) has been used as a well-known natural textile dye source for dyeing of natural fibers such as wool, silk and cotton, 100 % polyester dyeing with madder is not common. In this study, polyester samples were dyed with madder at different dyeing temperatures, from 60 °C to 130 °C, in company with 7 chemical and 5 natural mordants. Color properties and rub, light and wash fastness performances were investigated. Different shades of orange, brown, pink and reddish green colors were obtained. Dyeing at 130 °C exhibited the highest color yield, the highest chroma and the lowest lightness values. Overall, chemical mordants exhibited higher color yields than natural mordants. High wash fatness, moderate light and rub fastness levels were observed. The potassium bitartrate and gallnut, a natural mordant, exhibited the best results. The madder dyeing of polyester should be carried out at hot temperature conditions, 130 °C, in order to obtain the highest achievable color yield and chroma with the highest light and wash fastness properties. [ABSTRACT FROM AUTHOR]

In this study, a natural dye extraction was carried out to isolate dyestuff extract powder from the waste barks of Turkish red pine ( Pinus brutia Ten.) timber which is not a common natural dyestuff source. The natural dyestuff powder obtained was applied to cotton, flax, wool, silk, tencel, polyamide and acrylic fibers accompanied by simultaneous application of alum and natural oak ash mordants. Color properties were investigated including rub-, light- and wash-fastness performance. Differently dyed fiber samples exhibited slightly different shades of beige, brown and brownish-yellow depending on the mordant used and fiber type. Alum mordanted samples exhibited better color properties. The highest (63.4) and the second highest (45.3) f( k) color yield values were observed for alum mordanted silk and wool samples, respectively. Dyed fabrics showed excellent wash fastness, very low staining performance, and moderate light- and rub-fastness. [ABSTRACT FROM AUTHOR]

This study was carried out to optimize dyeing conditions of unripe Citrus Unshiu extract on silk fabric and to evaluate antimicrobial activity of the dyed fabric for its potential use as a functional natural dye. Unripe fruits of Citrus Unshiu in Jeju Island, Korea, extracted in 80 % Ethanol solution to final solid dye powder were dyed on silk fabric under a variety of conditions such as dye bath concentrations, temperature, and dyeing duration together with mordanting. Dyeing fastness properties to washing, rubbing, perspiration, and light were tested and the antimicrobial activities of the dyed fabric against Staphylococcus aureus and Klebsiella pneumoniae were investigated quantitatively. As results, the fabric showed the maximum dye uptake ( K/S) under the conditions of 80 °C for temperature, 30 min for duration, and 600 % (o.w.f.) for dye concentration. Both pre- and post-mordanting seemed not to be effective on increasing K/S values of the dyed silk fabrics under the optimum dyeing conditions. Fastness ratings to washing, rubbing, and perspiration were all very good (4-5 grades) for both 300 and 600 % dyed silk fabrics. Excellent antimicrobial activities over 99 % reduction rate against two both bacteria were exhibited for all of dyed fabrics undergone more than 300 % of dye concentration. From these results, it was concluded that the dye concentration of 300 % of unripe Citrus Unshiu could be employed to produce antimicrobial silk fabric. Furthermore, to get more saturated shades on the fabric by the citrus, higher dye concentration such as 600 % was available as well. [ABSTRACT FROM AUTHOR]

Symplocos spicata (local name: Dom sheng) belonging to Family Symplococeae produces yellowish brown natural dye which has been used for dyeing textiles since ancient times by the Monpas tribe of Arunachal Pradesh. Symplocos spicata (Dom Sheng) was found in the Lumla area of Tawang district. Leaves of the plant are used by the Monpas and Tibetans for extraction of dye. Innovative sonicator dyeing with S. spicata showed that pretreatment with 2–4% metal mordant of the weight of the fabric is optimum showing very good fastness properties for dyed natural polymers such as cotton, wool, and silk. CIE Lab and K/S of the dyed fabrics were also evaluated. The superiority of sonicator dyeing over conventional dyeing has been established through this study. [ABSTRACT FROM AUTHOR]