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Your search keyword '"Otte, Matthias"' showing total 4 results
Start Over Author "Otte, Matthias" Journal european journal of inorganic chemistry
4 results on '"Otte, Matthias"'

1. Mimicry of the 2-His-1-Carboxylate Facial Triad Using Bulky N,N,O-Ligands: Non-Heme Iron Complexes Featuring a Single Facial Ligand and Easily Exchangeable Co-Ligands

Author

Folkertsma, Emma, primary, de Waard, Esther F., additional, Korpershoek, Gerda, additional, van Schaik, Arnoldus J., additional, Solozabal Mirón, Naiara, additional, Borrmann, Mandy, additional, Nijsse, Sjoerd, additional, Moelands, Marcel A. H., additional, Lutz, Martin, additional, Otte, Matthias, additional, Moret, Marc-Etienne, additional, and Klein Gebbink, Robertus J. M., additional

Published
2016
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3. Regioselective Cleavage of Electron-Rich Double Bonds in Dienes to Carbonyl Compounds with [Fe(OTf)2(mix-BPBP)] and a Combination of H2O2 and NaIO4.

Author

Spannring, Peter, Yazerski, Vital A., Chen, Jianming, Otte, Matthias, Weckhuysen, Bert M., Bruijnincx, Pieter C. A., and Klein Gebbink, Robertus J. M.

Subjects
REGIOSELECTIVITY (Chemistry), DOUBLE bonds, DIOLEFINS, CARBONYL compounds, ELECTRONS, ALDEHYDES, KETONES, OXIDIZING agents
Abstract

A method for the regioselective transformation of dienes to carbonyl compounds has been developed. Electron-rich olefins react selectively to yield valuable aldehydes and ketones. The method is based on the catalyst [Fe(OTf)2(mix-BPBP)] with an oxidant combination of H2O2 (1.0 equiv.) and NaIO4 (1.5 equiv.); it uses mild conditions and short reaction times, and it outperforms other olefin cleavage methodologies. [ABSTRACT FROM AUTHOR]

Published
2015
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4. Regioselective Cleavage of Electron-Rich Double Bonds in Dienes to Carbonyl Compounds with [Fe(OTf)2(mix-BPBP)] and a Combination of H2O2 and NaIO4.

Author

Spannring, Peter, Yazerski, Vital A., Chen, Jianming, Otte, Matthias, Weckhuysen, Bert M., Bruijnincx, Pieter C. A., and Klein Gebbink, Robertus J. M.

Subjects
*REGIOSELECTIVITY (Chemistry), *DOUBLE bonds, *DIOLEFINS, *CARBONYL compounds, *ELECTRONS, *ALDEHYDES, *KETONES, *OXIDIZING agents
Abstract

A method for the regioselective transformation of dienes to carbonyl compounds has been developed. Electron-rich olefins react selectively to yield valuable aldehydes and ketones. The method is based on the catalyst [Fe(OTf)2(mix-BPBP)] with an oxidant combination of H2O2 (1.0 equiv.) and NaIO4 (1.5 equiv.); it uses mild conditions and short reaction times, and it outperforms other olefin cleavage methodologies. [ABSTRACT FROM AUTHOR]

Published
2015
Full Text
View/download PDF

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