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Oxygen isotopes from bioapatite (conodonts) have been used for several decades to reconstruct the Palaeozoic climate history. During the Ordovician, conodont-based δ18Ophos studies have revealed a general cooling trend throughout the system. The δ18Ophos data from Estonia confirm this long-term shift but also demonstrate that against the background of a generally cooling climate in the pre-Hirnantian, the Late Ordovician was quite unstable, with several episodes of sea surface temperature (SST) decrease and increase of different magnitude and duration. In the sedimentary sequence, these cooling events are reflected by major sea-level lowstands. Several of these are also recognizable in the Tunguska Basin of Siberia. We have recently studied the δ18Ophos record from two Middle and Upper Ordovician sections in Siberia. Comparisons of the results with data from the Baltic region have revealed differences but also some similarities in the δ18Ophos trends, even though these two regions were located on different palaeocontinents, Siberia and Baltica. Both were geographically separated and display different Early Palaeozoic histories with respect to their environmental conditions. Siberia was located in low equatorial latitudes from the Cambrian onwards and remained there through the Ordovician and Silurian, whereas Baltica drifted from high southern latitudes to low latitudes from the late Cambrian and reached the southern subtropics in the Late Ordovician (late Sandbian–early Katian). Despite Siberia’s location at low northern subequatorial latitudes, the upper Middle (starting from the Darriwilian) and the Upper Ordovician in the Tunguska Basin are assumed to be represented by cool-water deposits (various calcareous siltstones with interbeds of micritic and/or bioclastic limestone). The onset of cool-water conditions is explained by plate-tectonic reorganization, resulting in the upwelling of cold oceanic waters along the southern margin of the palaeocontinent and their penetration into the epicontinental seas. Our δ18Ophos data generally fluctuate around 17.5‰ (VSMOW), indicating that SST was relatively stable. This general state is interrupted by six cooling episodes, but unlike in Baltica, no general trend of SST change in any direction (decrease or increase) is evident. In the Baltic region, a general cooling trend prevailed, and SST decreased continuously during the pre-Hirnantian Late Ordovician. In addition to this general trend, seven cooling events (CE) are observed, named (from the oldest upwards) the Late Kukruse, Haljala, Keila, Early Nabala, Vormsi, Early Pirgu, and Middle Pirgu CEs. Comparison of the δ18Ophos curves from the Tunguska and Baltoscandian basins shows that five of these CEs are reflected by brief intervals of higher δ18Ophos values also in the former one. The Keila CE is identified in the lower Mangazea Formation (Fm), the Early Nabala CE in the upper Mangazea Fm, and the Vormsi CE in the uppermost Mangazea Fm. In addition, the Haljala CE probably corresponds to an interval in the lowermost Mangazea Fm and the Early Pirgu CE to a small δ18Ophos peak in the lowermost Dolbor Fm. The most pronounced CE in Siberia is recorded in the upper Darriwilian, in the lower Ust’Stolbovaya Fm, and apparently reflects the Middle-Darriwilian Ice Age. The recognition of the same CEs in successions on two different palaeocontinents is clear evidence that they are not some regional phenomena but the result of global climatic perturbations. The recently acquired δ18Ophos data allow an improvement in the dating of the Siberian strata and their correlation with successions on other palaeocontinents. Previously, the MDICE, Upper Kukruse Low, GICE, and an interval probably including Rakvere (KOPE) and Saunja carbon isotopic events (CIE) were recognized in the Siberian δ13Ccarb record. Now, the position of the Keila CE just below an increase in δ13Ccarb in the Tunguska Basin confirms the identification of this CIE as GICE and allows the correlation of this level (lower Baksian Regional Stage) with the Keila Regional Stage in Estonia. In addition, the prolonged CIE between the Early Nabala and Vormsi CEs as identified in the Tunguska Basin apparently corresponds to the Saunja (Waynesville) CIE. This also means that the small peak in the δ13Ccarb curve below this CIE correlates with the Rakvere CIE. [ABSTRACT FROM AUTHOR]

Variation in the relative abundance of the stable carbon isotopes has been widely used to correlate Ordovician marine successions over the past two decades. To date, only a few of studies of Ordovician carbon chemostratigraphy have been conducted in South China. Most of the previous studies in this field have focused on specific time intervals and/or events in the Middle and Upper Ordovician. The Lower and Middle Ordovician of the Yangtze Platform is typically represented by a sedimentary succession dominated by carbonate rocks, which is ideal for studying the carbon chemostratigraphy. Three sections spanning the Nantsinkuan/Lunshan, Fenhsiang, Hunghuayuan, and Dawan/Zitai formations, corresponding to the Tremadocian–Dapingian in age, have been sampled for high-resolution δ13C chemostratigraphy. Our new δ13C data reveal five tie-points with the potential for global correlation: (1) a positive δ13C excursion in the lower Nantsinkuan Formation within the Tremadocian Rossodus manitouensis Zone; (2) an excursion with two peaks roughly within the late Tremadocian Paltodus ‘deltifer’ Zone; (3) a positive δ13C shift in the lower Hunghuayuan Formation, within the early Floian Serratognathus diversus Zone; (4) a gradual positive δ13C shift in the late Floian, ranging from the uppermost S. diversus Zone to the basal Oepikodus evae Zone; (5) a minor negative shift in the lower Dawan/Zitai Formation, within the early Dapingian Baltoniodus triangularis Zone. These excursions are herein used for correlation of the Yangtze Platform strata with successions from South China, North China, the Argentine Precordillera, North America and Baltica. From a palaeogeographical perspective, the Gudongkou, Xiangshuidong and Daling sections represent depositional environments along an inner to outer ramp profile. The δ13C data from these sections show successively heavier (higher) δ13C values with increasing depositional depth, which can be interpreted as due to remineralization of organic carbon within the carbonate rocks formed in the shallow-water environment. [ABSTRACT FROM AUTHOR]

The Late Ordovician mass extinction occurred during an icehouse interval, accompanied by the glaciation of the supercontinent Gondwana, which was located at the South Pole at that time. As suggested by sequence stratigraphy of near- and far-field sedimentary successions as well as stable oxygen isotope studies, ice sheets reached their maximum extent in the late Hirnantian M. persculptus graptolite zone. As a result, the global sea-level dropped significantly during the Hirnantian Glacial Maximum (HGM). This led to exposure and erosion of sediments on the tropical shelves of Laurentia and Baltica. Where shelves remained submerged, water depths were probably very shallow. Local redox proxies, such as I/Ca ratios or iron speciation, indicate that shelf environments were well oxygenated. At the same time, stable uranium isotopes, measured on shallow-water carbonate samples, indicate a global expansion of the seafloor overlain by anoxic water. This implies that the observed increase in anoxia was confined to the open ocean and that there was a redox gradient between coastal and oceanic environments. Unfortunately, the lack of Late Ordovician deep water sedimentary records makes it impossible to directly measure open-ocean redox conditions. In general, Late Ordovician deoxygenation is in stark contrast to other oceanic anoxic events of the Phanerozoic, which occurred during greenhouse conditions and are associated with rising water temperatures. Under present interglacial conditions, with a relatively high sea-level, it is estimated that about 70% of the nutrient phosphorus delivered from the continents is retained in shelf sediments. Hence, shelf environments act as a nutrient filter. However, during times of low sea-level, this filter is switched off due to the bypassing of incoming riverine dissolved load through river canyons. As a result, excess phosphorus is released into the open ocean leading to eutrophication. This has previously been proposed for the Last Glacial Maximum (LGM) and is supported by geochemical data. We suggest that this scenario may also be applicable to the HGM and serve as an explanation for increasing anoxia during cold climatic conditions. To test this, we measured phosphorus concentrations across the HGM on carbonate samples collected from two low-latitude successions (Ruisseau aux Algues on Anticosti Island and Valga-10 core section from Estonia, both interpreted as shelf environments). To eliminate the detrital, non-reactive phosphorus fraction, we used the SEDEX sequential extraction method, which allows to separately measure reactive (Preact) and organic phosphorus (Porg). In order to evaluate the burial efficiency of phosphorus, we determined total organic carbon (C) concentration and calculated C/Porg and C/Preact ratios. We observe a decreasing trend in Preact towards the HGM and a minimum during the subsequent initial transgression. Low C/Preact and C/Porg in the range of the Redfield ratio indicate efficient burial under oxygenated conditions. Therefore, we can rule out that phosphorus regeneration, which is stronger under anoxic conditions, caused the observed minimum. This means that Preact is a direct measure of primary productivity and phosphorus burial. Using the Preact data and an estimate for the shelf area, we modelled the global burial flux of phosphorus into shelf sediments. Due to the overall reduction in shelf area during the HGM and the low Preact contents, the modelling suggests that the shelf burial flux was approximately halved. If the phosphorus input had remained constant across the interval, which is reasonable given that the erosion of exposed shelf sediments compensated for a reduction in continental weathering during the cold and arid climate, the excess phosphorus would have entered the open ocean stimulating primary productivity. Ultimately, enhanced productivity would have resulted in a high organic matter sinking flux and oxygen depletion by aerobic respiration. In summary, our data and modelling support the proposed scenario of an inefficient nutrient filter. [ABSTRACT FROM AUTHOR]

Understanding ancient climate changes is hampered by the inability to disentangle trends in continental ice volume from records of relative sea-level change. As a unique coastal deposit in tropical and subtropical regions, beachrock has been proved to be reliable for constraining the glacial meltwater signal and thus the total volume of land-based ice in Quaternary. However, beachrock is rarely recognized in the fossil record due to (a) the two-dimensional distribution of beach deposits, as opposed, for example, to extended platform sediments, and (b) the fact that specific environmental conditions are required in order to lithify sediments directly on the beach. By combining the stratigraphic architecture with petrography of characteristic carbonate cements, we demonstrate the first known occurrence of Ordovician beachrock in the Tarim Block, northwestern China. According to biostratigraphic data, a middle Katian (Upper Ordovician) palaeokarst surface is capped by carbonate conglomerate beachrock and this is suggesting a significant relative sea-level rise in late Katian. The beachrock can be correlated with widespread subaerial exposure surfaces and a pronounced stratigraphic gap within the Katian in northwestern Tarim. We suggest that the beachrock ‘fingerprinted’ a strong melt-water pulse in high latitudes after a short-lived Katian glaciation, which has not received much attention in scientific papers so far. [ABSTRACT FROM AUTHOR]

The δ13C record from an early Sheinwoodian limestone unit in the Prague Basin suggests its deposition during the time of the early Sheinwoodian carbon isotope excursion (ESCIE). The geochemical data set represents the first evidence for the ESCIE in the Prague Basin which was located in high latitudes on the northwestern peri-Gondwana shelf during early Silurian times. [ABSTRACT FROM AUTHOR]

Based on δ13C data from two drillcores recovered from the Siljan district, we present a first continuous carbon isotope record of the upper Tremadocian-lower Katian limestone succession of central Sweden. New names for some isotopic carbon excursions from the Cambrian-Ordovician boundary through the basal Darriwilian are introduced. The Mora 001 core from the western part of the Siljan impact structure ranges through the Lower-Middle Ordovician, whereas the Solberga 1 core from its eastern part ranges through the Middle-lower Upper Ordovician. Upper Tremadocian and Floian units are extremely condensed and include extensive stratigraphic gaps. Multiple hardgrounds, sometimes with minor karstic overprint, imply recurrent periods of erosion and/or non-deposition. Like in other parts of Sweden, the Dapingian and Darriwilian succession is characterized by a relatively complete sedimentary record and low sedimentation rates. [ABSTRACT FROM AUTHOR]

Reefs developed simultaneously during the latest Sandbian/earliest Katian global Guttenberg Isotopic Carbon Excursion (GICE) in several places across Baltoscandia. Latest Sandbian/earliest Katian patch reefs are also described from the Vasalemma Formation of northern Estonia. The Saku Member of the Vasalemma Formation was previously considered as a proximal facies related to the reefs. However, the Saku Member clearly post-dates the GICE interval and ranges from the latest Keila to Rakvere in terms of regional stages. Some small reefs occur in direct proximity to the stratotype of the Saku Member. New δ13C data from the stratotype section and the adjacent reefs indicate that these reefs developed before the deposition of the Saku Member during the GICE interval. The chemostratigraphic data support the hypothesis of a short-time Baltoscandian reef growth event that terminated during the GICE interval. [ABSTRACT FROM AUTHOR]