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We present a 3-year time series of lead (Pb) and mercury (Hg) concentrations and isotope signatures in total suspended particulate (TSP) matter and as total gaseous Hg (TGM) in Xi'an, Northwestern China. Mean concentrations of TSP (299 ± 120 µg m-3), PbTSP (0.33 ± 0.15 µg m-3) and HgTSP (0.64 ± 0.54 ng m-3), and TGM (5.7 ± 2.7 ng m-3) were elevated. We find that atmospheric Pb levels in winter in Xi'an have decreased by 4.6% per year since 2003, yet remain elevated relative to air quality guidelines and therefore a major health concern. δ202HgTSP and Δ199HgTSP averaged -0.80 ± 0.30‰ (1σ) and -0.02 ± 0.10‰ (1σ) and δ202HgTGM and Δ199HgTGM averaged -0.08 ± 0.41‰ (1σ) and 0.00 ± 0.04‰ (1σ). Relative to raw coal from Shaanxi and surrounding provinces, δ202HgTSP is enriched in the light Hg isotopes, whereas δ202HgTGM is enriched in the heavy isotopes. TSP and TGM Δ199Hg signatures are indistinguishable from raw coal, indicating little photochemical mass independent fractionation of atmospheric Hg in the near-field urban-industrial environment. δ202HgTGM correlates significantly with TGM levels (r2 = 0.3, p < 0.01) and likely reflects binary mixing of local industrial TGM emissions with global background TGM. [ABSTRACT FROM AUTHOR]