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Sediment is an important carrier of evidence about environmental evolution which receives huge volumes of organic material originated from both anthropogenic and natural sources. In this study, based on sedimentary chronology, the vertical trends of particle size distribution, total organic carbon (TOC), total nitrogen (TN), and their stable isotopes (δ13C, δ15N) in the sediment core of the nuclear power sea in southwest Daya Bay were analyzed, and the distribution characteristics and contribution ratios of different sources of organic matter in the sedimentary environment over the past 70 years were resolved using a Bayesian mixing model (MixSIAR). TOC, TN, δ13C, and δ15N ranged from 0.89 to 1.56%, 0.09 to 0.2%, − 22.3 to − 20.6‰, and 4.38 to 6.51‰, respectively. The organic matter in the sediment is controlled by a mixture of terrestrial input and marine autochthonous, the proportion of organic matter from terrestrial sources increases, while that from marine sources decreases in the sediment core, which persists from 1960 to 2000, yet organic matter from marine sources still dominates. The first signs of increased primary productivity occurred in 1960, and it was primarily due to agricultural activity. After the 1980s, the rapid increase in population around Daya Bay, the construction of nuclear power plants, the rise of aquaculture, and the quick expansion of industrial bases were all major factors that changed the ecological environment of Daya Bay. [ABSTRACT FROM AUTHOR]

Sediment is an important carrier of evidence about environmental evolution which receives huge volumes of organic material originated from both anthropogenic and natural sources. In this study, based on sedimentary chronology, the vertical trends of particle size distribution, total organic carbon (TOC), total nitrogen (TN), and their stable isotopes (δ13C, δ15N) in the sediment core of the nuclear power sea in southwest Daya Bay were analyzed, and the distribution characteristics and contribution ratios of different sources of organic matter in the sedimentary environment over the past 70 years were resolved using a Bayesian mixing model (MixSIAR). TOC, TN, δ13C, and δ15N ranged from 0.89 to 1.56%, 0.09 to 0.2%, − 22.3 to − 20.6‰, and 4.38 to 6.51‰, respectively. The organic matter in the sediment is controlled by a mixture of terrestrial input and marine autochthonous, the proportion of organic matter from terrestrial sources increases, while that from marine sources decreases in the sediment core, which persists from 1960 to 2000, yet organic matter from marine sources still dominates. The first signs of increased primary productivity occurred in 1960, and it was primarily due to agricultural activity. After the 1980s, the rapid increase in population around Daya Bay, the construction of nuclear power plants, the rise of aquaculture, and the quick expansion of industrial bases were all major factors that changed the ecological environment of Daya Bay. [ABSTRACT FROM AUTHOR]

A sedimentary record of the 19 organochlorine pesticides (OCPs) pollutants from Dongping Lake, north China, is presented in this study. According to the dating of core sediment and OCP content analysis in samples, from 1904 to 2016, the total concentration of OCPs varied from undetectable levels (n.d.) to 33.1 ng/g. The OCP concentration was first detected in the samples of 1938, and then gradually increased to a peak level in 2000 thereafter decreased until 2016. Among the detected OCPs, hexachlorocyclohexanes (HCHs) and dichlorodiphenyltrichloroethanes (DDTs) were the predominant and the most frequently detected contaminants in the core sediment, with concentrations ranging from n.d. to 16.9 ng/g and from n.d. to 8.8 ng/g, respectively. The distribution of OCPs in the sediments was affected by organic carbon concentration, showing a significant positive correlation (r = 0.93, p < 0.001), especially for HCHs (r = 0.98, p < 0.001). The source analysis showed that HCH contamination mainly derived from historical use of technical HCHs, while in recent years, it derived from lindane usage. DDT pollution was attributed to historical use of technical DDTs, as well as the microbial degradation of historic DDT residues. Finally, risk analysis was performed for OCPs in sediment cores based on sediment quality guidelines from the Canadian Council of Ministers of the Environment, showing that DDTs presented a high ecological toxicity risk during the period of 1959–2010. [ABSTRACT FROM AUTHOR]

High-altitude Pyrenean lakes are ecosystems far from local pollution sources, and thus they are particularly sensitive to the atmospheric deposition of metals and metalloids. This study aims to quantify the effect of human activity in 18 lakes located in both side of the France–Spain frontier. Sediment cores were collected in summer 2013, sampled at a 1cm resolution and the concentration of 24 elements was measured by ICP-MS. Statistic and chemometric analysis of the results highlights the influence of the geographical position and lithogenic features of each lake basin on trapping pollutants. More than the 80% of the lakes showed values of enrichment factor (EF) above 2 for at least one of the elements investigated in at least one core interval, which corroborates the existence of historical anthropogenic inputs of elements in the studied area. The results demonstrate the natural origin of As and Ti in Pyrenees, together with the significant anthropogenic inputs of Cd, Pb, Sb and Sn from ancient times. The data set points mining activities as the main historical source of pollution and illustrate the large impact of the industrial revolution. The regional variability could reflect also differential long-range transport, followed by dry or wet deposition. [ABSTRACT FROM AUTHOR]

The suitability of lake sediment cores to reconstruct past inputs, regional pollution, and usage patterns of pesticides has been shown previously. Until now, no such data exist for lakes in eastern Germany. Therefore, 10 sediment cores (length 1 m) of 10 lakes in eastern Germany, the territory of the former German Democratic Republic (GDR), were collected and cut into 5–10-mm layers. In each layer, concentrations of trace elements (TEs) As, Cd, Cr, Cu, Ni, Pb, S, and Zn, as well as of organochlorine pesticides (OCPs), i.e., dichlorodiphenyltrichloroethane (DDT) and hexachlorocyclohexane (HCH), were analyzed. A miniaturized solid–liquid extraction technique in conjunction with headspace solid-phase microextraction (HS-SPME) and gas chromatography–mass spectrometry (GC–MS) was used for the latter. The progression of TE concentrations over time is uniform. It follows a trans-regional pattern and is indicative of activity and policy making in West Germany before 1990 instead of those in the GDR. Of OCPs, only transformation products of DDT were found. Congener ratios indicate a mainly aerial input. In the lakes' profiles, several regional features and responses to national policies and measures are visible. Dichlorodiphenyldichloroethane (DDD) concentrations reflect the history of DDT use in the GDR. Lake sediments proved to be suitable to archive short- and long-range impacts of anthropogenic activity. Our data can be used to complement and validate other forms of environmental pollution long-term monitoring and to check for the efficiency of pollution countermeasures in the past. [ABSTRACT FROM AUTHOR]

With the development of urbanization and economic growth, the urban lake ecosystem faces many challenges derived from external factors. As pollutants in the aquatic environment, heavy metals and microplastics negatively influence the urban lake ecosystem due to their intrinsic properties. To understand the distribution patterns and multidecadal deposition characteristics of heavy metals and microplastics, six sediment cores were collected in March 2021 from a Chinese urban lake, Xinghu Lake, and the isotopic composition of cesium-137 and lead-210 was analyzed for the chronology of the sediment core. Here, the classifications of comprehensive ecological risk evaluation methods for heavy metals and microplastics were adjusted further. Meanwhile, the correlations among heavy metals, microplastics, sediment grains, and natural and social factors were further analyzed. The results showed that the sediments of Xinghu Lake were mainly fine silt (39%), and the average surface area of sediment was 1.82 ± 0.60 m2/g. The average concentrations of cadmium, chromium, copper, nickel, lead, vanadium, and zinc were 0.268 ± 0.077, 59.91 ± 16.98, 23.29 ± 6.48, 52.16 ± 13.11, 36.83 ± 11.78, 119.57 ± 26.91, and 88.44 ± 29.68 mg/kg, respectively. The average comprehensive potential ecological risk indexes of heavy metals and microplastics in sediment cores were 46.59 ± 9.98 and 105.78 ± 23.32 in Xinghu Lake, and their risks were projected to reach high and very high levels by 2030 and 2050. The annual average temperature was the key natural factor for the abundances of heavy metals and microplastics, and the small sediment grain had a significant correlation with these. Agricultural activities were major pollution sources of heavy metals and microplastics, while the chemical fibers and plastic products were closely related to the abundance of microplastics. [ABSTRACT FROM AUTHOR]

To clarify the impact of human activities on the natural environment, as well as the current ecological risks to the environment surrounding Zhushan Bay in Taihu Lake, the characteristics of deposited organic materials, including elements and 16 polycyclic aromatic hydrocarbons (∑16PAHs), in a sediment core from Taihu Lake were determined. The nitrogen (N), carbon (C), hydrogen (H), and sulfur (S) contents ranged from 0.08 to 0.3%, 0.83 to 3.6%, 0.63 to 1.12%, and 0.02 to 0.24%, respectively. The most abundant element in the core was C followed by H, S, and N, while elemental C and the C/H ratio displayed a decreasing trend with depth. The ∑16PAH concentration was in the range of 1807.48–4674.83 ng g−1, showing a downward trend with depth, with some fluctuations. Three-ring PAHs dominated in surface sediment, while 5-ring PAHs dominated at a depth of 55–93 cm. Six-ring PAHs appeared in the 1830s and gradually increased over time before slowly decreasing from 2005 onward due to the establishment of environmental protection measures. The ratio of PAH monomers indicated that PAHs in samples from a depth of 0 to 55 cm were mainly derived from the combustion of liquid fossil fuels, while the PAHs in the deeper samples mainly originated from petroleum. The results of a principal component analysis (PCA) showed that the PAHs in the sediment core of Taihu Lake were mainly derived from the combustion of fossil fuels, such as diesel, petroleum, gasoline, and coal. The contributions of biomass combustion, liquid fossil fuel combustion, coal combustion, and unknown source were 8.99%, 52.68%, 1.65%, and 36.68%, respectively. The results of a toxicity analysis indicated that most of the PAH monomers had little impact on the ecology, and the annual increase of a small number of monomers might have toxic effects on the biological community, resulting in a serious ecological risks, that requires the imposition of control measures. [ABSTRACT FROM AUTHOR]

Reservoir sediment contamination with heavy metals produced by mining activities has aroused widespread global concern owing to its potential threat to human health. In this study, the total concentrations and speciation of heavy metals (Cd, Pb, Zn) in the Lexi (LX) and Maoshui (MS) reservoirs around the historical artisanal zinc smelting area in Southwest China were determined, and pollution indices were applied to assess the pollution levels and potential ecological risks of the two reservoirs. The results showed that all the detected samples in the two reservoirs presented significant metal accumulation, especially for Cd, as compared with the soil background values in Guizhou Province. Between the two reservoirs, the vertical distribution characteristics of each metal in sediment columns were similar. The heavy metal concentrations of the three columns in the LX reservoir reached their maxima at 35, 15, and 10 cm and showed a trend of first increasing and then decreasing overall. However, the heavy metal contents of the three columns in the MS reservoir all exhibited wave-like characteristics in the vertical direction, and all of them reached a relatively obvious high point at approximately 5 and 30 cm. The geoaccumulation index (Igeo) and potential ecological risk index (RI) indicated that Cd was strongly enriched and represented the main risk factor, and the pollution level of the MS reservoir was significantly higher than that of the LX reservoir. Furthermore, the effect coefficients (ERMQ) confirmed that the two reservoirs are likely to have toxic impacts on aquatic organisms and need to be controlled and mitigated. The speciation analysis of heavy metals revealed that Cd was primarily in the acid-extractable fraction (69.57%, 68.28%), Pb was chiefly in the reducible fraction (55.24%, 42.18%) and oxidizable fraction (22.60%, 38.02%), and Zn was mainly in the oxidizable fraction (32.54%, 37.65%) in the LX and MS reservoirs, respectively. The ratios of the secondary phase and primary phase (RSP) and risk assessment code (RAC) evaluation demonstrated that Cd in the sediments of the two reservoirs presents a very high potential ecological risk, and Pb and Zn were at medium to high ecological risk levels. This study highlighted that the artisanal zinc smelting activities had caused serious heavy metal pollution in reservoir sediments, posing a threat to the local ecological environment. [ABSTRACT FROM AUTHOR]

Polycyclic aromatic hydrocarbons (PAHs) are typical toxic organic pollutants that can accumulate in sediments and may be toxic to aquatic organisms. In the present study, the contamination level, composition pattern, and sources of sixteen PAHs listed by the United States Environmental Protection Agency were investigated in surface sediments and a sediment core from Daihai Lake, which is located in a typical semiarid area of Inner Mongolia, China, and the ecological risk of these PAHs was assessed. The results show that the total concentration of PAHs in the surface sediments ranged from 204.6 to 344.5 ng/g with an average value of 287.2 ng/g and that compared with other aquatic systems, the level of PAHs in the sediments from Daihai Lake was low. However, a general upward trend was observed for the concentrations of PAHs in the sediment core, which might be related to the increase in human activities in the area. Moreover, the PAH concentrations were significantly positively correlated with the total organic carbon (TOC) content in the sediments, and it is thus inferred that TOC regulates the distribution of PAHs in Daihai Lake. Three-ring and four-ring PAHs were found to be predominant in all the sediment samples, and phenanthrene (Phe) was the most abundant compound. According to the composition of PAHs and the anthracene (Ant)/(Ant+Phe) or fluoranthene (Flt)/(Flt+pyrene (Pyr)) ratios, the PAHs in Daihai Lake mainly originated from the combustion of domestic coal, grass, and wood, and petroleum cannot be ignored as a source considering the growth of industry. Risk assessment based on a comparison of PAH concentrations and the effect range low (ERL) and effect range median (ERM) values demonstrated that acenaphthene (Ace) at 11 sites and fluorene (Flu) at 7 sites had occasional adverse biological effects. [ABSTRACT FROM AUTHOR]

Water level fluctuation zone (WLFZ) with changeable environmental conditions would affect the transport and release of nutrients in the sediment. To investigate the influence of long-term water level fluctuations on sediment phosphorus (P), a reservoir sediment partitioning method based on historical water level was developed and applied in the Biliuhe Reservoir. The reservoir sediment was divided into frequent fluctuation zone (FFZ), fluctuation zone of continuous droughts (DFZ), and continuously submerged zone (CSZ). Sediment cores in different zones were collected and P was analyzed. TP content in the surface sediment progressively increased from FFZ, DFZ, to CSZ except the 0–10-cm samples of D1, and TP content of sediment cores increased gradually with decreasing depth except D1 core. Ferric iron-bound P (Fe-P) and organic P (OP) exhibited uniform spatial variation with TP, while no clear patterns were found with regard to the other forms. Fe-P composed most of TP (54.67 ± 10.15%) and had a significant positive correlation with stable OP (5.55 ± 2.07%). The contributions of Fe-P, detrital apatite P (Det-P), and OP are stable among the four cores, indicating that the relationship between the various P forms is relatively stable despite variations in environmental conditions of WLFZ. The alternation of deposition and erosion under long-term water level fluctuation can promote P transport down-flow, which can be prevented by the continuous growth of plants in WLFZ. Thus, the reasonable use of the plant growth in WLFZ can control the P load of the reservoir. [ABSTRACT FROM AUTHOR]

The impacts of anthropic activities have had profound effects on the nitrogen (N) and phosphorus (P) cycles in many aquatic ecosystems. We investigated the spatial and temporal distributions of carbon (C), N, and P in the sediments of a tropical Paiva Castro Reservoir (São Paulo, Brazil), as well as their release and retention in the system. In 2010, surface sediments were collected at nine sites in the reservoir, and a core was obtained in the limnetic zone, in 2010. The core was dated using the 210Pb technique. The organic C content was estimated from organic matter concentration, which was measured by the loss-on-ignition method, and the concentrations of P and N were determined by spectrophotometry. Marked spatial heterogeneity in the Paiva Castro sediments associated with both natural variations in the water body and variations induced by human impacts was observed. Heterogeneity was evidenced by a decrease in the allochthonous contribution of organic matter (C/N) in the upstream-downstream direction and increases of N and P, mainly associated with water flows in the different compartments of the reservoir. In the core, C and N concentrations display significant positive correlations with increases in population and agricultural activities in the drainage basin through time. The C/P molar ratios in surface sediments are indicative of human impacts in the region, as C:P ratios in the sediment are low (7.8:1) compared to the Redfield ratio (C:P = 108:1). Predominance of oxic conditions at the sediment surface and particles sizes < 63 μm provided favorable conditions for P retention in the sediments, which helps prevent eutrophication. Approaches used in this research should be extended to other locations, especially in mesotrophic and oligotrophic reservoirs, to provide information on historical impacts in such aquatic ecosystems. [ABSTRACT FROM AUTHOR]

A novel approach was proposed to evaluate the potential risk of organic enrichment in marine aquaculture farms without obvious environmental degradation. The approach was based on historical environmental records preserved in sediment cores, and potential risk of organic enrichment can be effectively evaluated by comparing burial fluxes of marine organic carbon (OCM) during times before and after large-scale aquaculture. A case study was conducted in Sanggou Bay. The change trends on burial fluxes of organic carbon in sediment over the past 150 years were rebuilt. OCM burial fluxes have greatly increased since the beginning of large-scale aquaculture in 1980s, reaching 16.0~16.5 times higher than that before large-scale aquaculture. The results indicate that aquaculture activities have resulted in obvious accumulation of aquacultural organic matters, although sedimental environment has not degraded seriously. Besides, if the OCM burial fluxes further increase to 3.5~7.0 times higher than that in present, sedimental environment may degrade obviously. Therefore, potential risks of organic enrichment still exist with aquaculture development in Sanggou Bay. [ABSTRACT FROM AUTHOR]

The spatial distribution of polycyclic aromatic hydrocarbons (PAHs) and their source contributions employing receptor models has been widely reported. However, the temporal distribution of PAH source contributions is less studied. Thus, in this paper, three receptor models including principle component analysis-multiple linear regression (PCA-MLR), positive matrix factorization (PMF), and Unmix were used to PAH source apportionment study in a sediment core from Honghu Lake, China. Sixteen USEPA priority PAHs in 37 sliced sediment layers (1-cm interval) were measured, with the concentrations of ∑PAH (sum of 16 PAHs) ranging from 93.0 to 431 ng g. The source apportionment results derived from three receptor models were similar, with three common sources: mixed sources of biomass burning and coal combustion (31.0-41.4% on average), petroleum combustion (31.8-45.5%), and oil leakage (13.1-21.3%). The PMF model segregated an additional source: domestic coal combustion (contributed 20.9% to the ∑PAHs). Four aspects including intra-comparison, inter-comparison, source numbers and compositions, and source contributions were considered in comparison study. The results indicated that the PMF model was most reasonable in PAH source apportionment research in this study. [ABSTRACT FROM AUTHOR]

Vertical distribution of metals (Cu, Zn, Cr, Fe, Mn, Pb, Ni, Cd, and Li) in four sediment core samples (C, C, C, and C) from Anzali international wetland located southwest of the Caspian Sea was examined. Background concentration of each metal was calculated according to different statistical approaches. The results of multivariate statistical analysis showed that Fe and Mn might have significant role in the fate of Ni and Zn in sediment core samples. Different sediment quality indexes were utilized to assess metal pollution in sediment cores. Moreover, a new sediment quality index named aggregative toxicity index (ATI) based on sediment quality guidelines (SQGs) was developed to assess the degree of metal toxicity in an aggregative manner. The increasing pattern of metal pollution and their toxicity degree in upper layers of core samples indicated increasing effects of anthropogenic sources in the study area. [ABSTRACT FROM AUTHOR]

An approximately 59-year (1955-2014) sedimentary record of metal elements (Cu, Pb, Zn, Ni, Co, Mn, and Fe) in a sediment core, collected from the Huaihe River, Huainan City, Anhui Province, China, was reconstructed by using Pb geochronology. Copper, Zn, Ni, Co, and Mn evaluated by enrichment factor (EF) indicated minor contamination due to water pollution accidents of the Huaihe River that occurred in 1990s and 2004. Lead presented the most severe pollution among the metals studied, especially during 1957-1974. The use of leaded petrol and atmospheric deposition of coal combustion flue gases could have contributed to Pb contamination. In spite of the general good quality (mean sediment pollution index (SPI) 35.69) of the sediment core evaluated by SPI based on the principal component analysis, worse sediment qualities in the upper section (<6 cm, 2004) were still observed, suggesting intensive human activities causing the increasing concentrations of metals in recent decades. [ABSTRACT FROM AUTHOR]

The study of benthic foraminifera in sediment cores provides the opportunity to recognize environmental changes, including those due to the anthropogenic impact. The integration of these data with chemical-physical parameters provides a comprehensive quality assessment. This research was applied to a sediment core collected in the Augusta bay, where a very large commercial and military harbor and one of the largest petrochemical poles in Europe are present. Inside the petrochemical area also operated, from 1958 to 2003, a chlor-alkali plant with mercury cell technology which caused anthropic contamination of surrounding land and marine areas. The sediment core was collected in front of this plant and characterized for grain size and pollutants directly associated to chlor-alkali activity, such as mercury (Hg), barium (Ba), polychlorobiphenyls (PCBs), and polycyclic aromatic hydrocarbons (PAHs). Composition of foraminiferal assemblages and faunal parameters such as specific diversity, faunal density, abundance of abnormal specimens, and foraminiferal size were investigated as potential indicators of environmental status. Statistical analysis indicated a main common origin for Hg, Ba, and PCBs and the influence of pollutants on species distribution and faunal diversity and density. Exceptionally high Hg concentrations (63-680 mg/kg d.w.) were recorded in the whole core, where the geochronological study attributed the most contaminated levels to the period of maximum activity of the chlor-alkali plant, while a decrease of contamination was recorded after the stop of the activity. Distinct foraminiferal assemblages identified different ecozones along the core, which suggested decreasing anthropogenic impact from the bottom to the top. [ABSTRACT FROM AUTHOR]

In estuarine ecosystems, metallic and organic contaminants are mainly associated with fine grain sediments which settle on mudflats. Over time, the layers of sediment accumulate and are then transformed by diagenetic processes mainly controlled by microbial activity, recording the history of the estuary's chemical contamination. In an environment of this specific type, we investigated the evolution of the chemical contamination and the structure of both total and active microbial communities, based on PhyloChip analysis of a 4.6-m core corresponding to a 40-year sedimentary record. While the archaeal abundance remained constant along the core, a decrease by one order of magnitude in the bacterial abundance was observed with depth. Both total and active microbial communities were dominated by Proteobacteria, Actinobacteria, and Firmicutes in all sediment samples. Among Proteobacteria, alpha- Proteobacteria dominated both total (from 37 to 60 %) and metabolically active (from 19.7 to 34.6 %) communities, including the Rhizobiales, Rhodobacter, Caulobacterales, and Sphingomonadales orders. Co-inertia analysis revealed a relationship between polycyclic aromatic hydrocarbons, zinc and some polychlorobiphenyls concentrations, and the structure of total and active microbial communities in the oldest and most contaminated sediments (from 1970 to 1975), suggesting that long-term exposure to chemicals shaped the structure of the microbial community. [ABSTRACT FROM AUTHOR]

To better understand the past and present impact of contaminants of emerging concern (CECs) in coastal and marine ecosystems, archived samples were analyzed for a broad suite of analytes, including pharmaceuticals and personal care products (PPCPs), flame retardants (including PBDEs), perfluorinated compounds (PFCs), and current-use pesticides. Surface sediment, mussels ( Mytilus spp.) and sediment core samples collected from the California (USA) coast were obtained from environmental specimen banks. Selected CECs were detected in recent surface sediments, with nonylphenol (4-NP), its mono- and di-ethoxylates (NP1EO and NP2EO), triclocarban, and pyrethroid insecticides in the greatest abundance. Alkylphenols, triclocarban, and triclosan were present in sediment core segments from the 1970s, as well as in Mytilus tissue collected during the 1990s. Increasing concentrations of some CECs (e.g., miconazole, triclosan) were observed in the surface layers (ca. 2007) of a sediment core, in contrast to peak concentrations of 4-NP and triclocarban corresponding to input during the 1970s, and an apparent peak input for PBDEs during the 1990s. These results suggest that chemicals sometimes referred to as 'emerging' (e.g., alkylphenols, triclocarban) have been present in the aquatic environment for several decades and are decreasing in concentration, whereas others (e.g., miconazole, triclosan) are increasing. [ABSTRACT FROM AUTHOR]

In the present study, 28 polycyclic aromatic hydrocarbons (PAHs) were investigated in four sediment cores collected from the main river estuaries of Chaohu Lake, one of the severely polluted lakes in China. The results indicate that elevated concentrations of total PAHs (ΣPAH) were found in the samples from the estuary of Nanfei River (ENF), considering BaP-based total toxicity equivalent (TEQ-BaP) and toxic unit (TU) results; there are potential adverse environmental implications. The total organic carbon (TOC) played an important role on the accumulation of PAHs at ENF and the estuary of Tongyang River (ETY). The predominant PAHs are high molecular weight (HMW) homologous for all samples; as a result, industrial wastewater from a steel company is expectedly the key source of PAHs in ENF, while coke consumption would be the important source of PAHs at other three sampling sites. Vertical distribution of PAHs in the sediment cores could be explained by the local social and economic activities. Furthermore, a minor variation of PAH composition in the sediment core could be justified by the stable structure of energy consumption in the Anhui Province. These results justify the need for further enhancement of industrial wastewater treatment and development of renewable energies which are the key factors on the control of PAH pollution in China. [ABSTRACT FROM AUTHOR]

In estuarine ecosystems, trace metals are mainly associated with fine grain sediments which settle on mudflats. Over time, the layers of sediments accumulate and are then transformed by diagenetic processes, recording the history of the estuary's chemical contamination. In such a specific environment, we investigated to what extent a chronic exposure to contaminants could affect metal-resistant sedimentary bacteria in subsurface sediments. The occurrence and diversity of cadmium resistance genes ( cadA, czcA) was investigated in 5- and 33-year-old sediments from a highly contaminated estuary (Seine France). Primers were designed to detect a 252-bp fragment of the czcA gene, specifically targeting a transmembrane helice domain (TMH IV) involved in the proton substrate antiport of this efflux pump. Although the cadA gene was not detected, the highest diversity of the sequence of the czcA gene was observed in the 5-year-old sediment. According to the percentage of identity at the amino acid level, the closest CzcA relatives were identified among Proteobacteria (α, β, γ, and δ), Verrucomicrobia, Nitrospirae, and Bacteroidetes. The most abundant sequences were affiliated with Stenotrophomonas. In contrast, in the 33-year-old sediment, CzcA sequences were mainly related to Rhodanobacter thiooxydans and Stenotrophomonas, suggesting a shaping of the metal-resistant microbial communities over time by both diagenetic processes and trace metal contamination. [ABSTRACT FROM AUTHOR]

Concentrations of inorganic tin (Sn), tributyltin (TBT) and its degradation products dibutyltin (DBT) and monobutyltin (MBT) were measured in surface sediments and in two cores from the Toulon Bay, hosting the major French military harbour. Anticipating planned dredging, the aim of the present work is to map and evaluate for the first time the recent and historic contamination of these sediments by inorganic and organic Sn species derived from antifouling paints used for various naval domains including military, trade, tourism and leisure. Tin and butyl-Sn concentrations in the bay varied strongly (4 orders of magnitude), depending on the site, showing maximum values near the shipyards. The concentrations of total Sn (1.3-112 μg g), TBT (<0.5-2,700 ng g), DBT (<0.5-1,800 ng g) and MBT (0.5-1,000 ng g) generally decreased towards the open sea, i.e. as a function of both distance from the presumed main source and bottom currents. Progressive degradation state of the butyl-Sn species according to the same spatial scheme and the enrichment factors support the scenario of a strongly polluted bay with exportation of polluted sediment to the open Mediterranean. Low degradation and the historical records of butyl-Sn species in two Pb-dated sediment cores, representative of the Northern Bay, are consistent with the relatively recent use of TBT by military shipyards and confirm maximum pollution during the 1970s, which will persist in the anoxic sediments for several centuries. The results show that (a) degradation kinetics of butyl-Sn species depend on environmental conditions, (b) the final degradation product Sn is by far the dominant species after 10-12 half-life periods and (c) using recent data to reliably assess former TBT contamination requires the use of a modified butyl-Sn degradation index BDI. Resuspension of extremely contaminated subsurface sediments by the scheduled dredging will probably result in mobilization of important amounts of butyl-Sn species. [ABSTRACT FROM AUTHOR]

Unique time trends of polycyclic aromatic hydrocarbons (PAHs) and dichlorodiphenyltrichloroethanes (DDTs) were found in a dated sediment core from Dianchi Lake (DC), an urban lake in Southwest China. The temporal trend of PAHs in DC was not only different from those in China's coastline and remote lakes of China, but also different from those in more developed countries. Identification of sources suggested that PAHs in DC originated primarily from domestic combustion of coal and biomass. However, a change of source from low- and moderate-temperature combustion to high-temperature combustion processes was observed. Different from those in China's coastline and some developed countries, the temporal trend of DDTs in DC mirrored the historical usage of DDTs in China, with erosion of soils and surface runoff from its drainage area the most likely routes of DDT introduction to the lake. Rapid urbanization and industrialization in its catchment, effective interception of point-source pollution, and changes in sources of energy during the last few decades have significantly influenced the vertical profiles of PAHs in DC. [ABSTRACT FROM AUTHOR]

In order to screen dioxin pollution in sediment of Three Gorges Dam (TGD) area, three sediment cores were obtained from two sites in 2010~2011; each core was divided into different samples with every 10 cm depth. Sediment dating determined by radiometry (Cs, Pb) and concentrations of dioxins were analyzed by high-resolution gas chromatography/mass spectrometry. The results indicated: Sediment dating showed no significant difference among all the samples from the same core and the two locations (ANOVA, p > 0.05). The total amount of polychlorinated dibenzo- p-dioxins (PCDD)/Fs in all sample ranged from 30.7 to 371 pg/g dry weight (d.w.), with the mean value of 66.2 pg/g d.w. PCDDs occupied 60.33~85.22 % of dioxins in each sample, and PCDFs contributed to a very small extend. There was no significant difference in the dioxin concentration between 2010 and 2011 and in the two locations ( t test, p > 0.05), but the vertical distribution of dioxins showed significant different in different depths. Toxic equivalent (TEQ) (WHO 2005, Humans) of samples ranged from 0.15 to 1.60 pg/g d.w.; the mean was 0.41 pg/g d.w. No significant difference was found in TEQ between 2010 and 2011( t test, p > 0.05). It could be concluded that the distribution of dioxins showed the spatial heterogeneous which resulted from the strong mixing and sediment deposition characteristics. Dioxin concentration in sediment cores was low with very low environmental risk potential. Dioxins at the two sites had the same origin, and exogenous input was the main source. It is the first report on the dioxins concentrations in sediment cores in the TGD area. [ABSTRACT FROM AUTHOR]