Search

This investigation aimed to scrutinize the level of phthalate esters (PEs) in the landfill leachate of a coastal city in the north of the Persian Gulf and the sensitive ecosystem (soil and water) around it. Soil (two depths) and water samples were prepared from 5 stations in wet and dry seasons. The studied landfill leachate contained 114-303 μg/L of phthalates. The highest concentration of phthalates was related to bis (2-ethylhexyl) phthalate (3257 ng/g) in the wet season at surface soil (0-5 cm) in the landfill site, while the lowest one (6 ng/g) belonged to dimethyl phthalate at sub-surface soil at 700 m from the landfill in the dry season. A significant change in the level of Σ6PEs in the dry (303 μg/L) and wet (114 μg/L) seasons (P ≤ 0.05) was observed for water samples. The PE concentrations in wet times were higher in all soil depths than in dry times. With increasing depth, the content of phthalates decreased in all studied environments. A direct relationship was observed between the phthalates concentration and the pH value of leachate/water and soil. The PEs concentration was linked to electrical conductivity (leachate: R 2  = 0.65, P < 0.01 and surface soil: R 2  = 0.77, P < 0.05) and the soil organic content. The ecological risk of di-n-butyl phthalate, benzyl butyl phthalate, bis (2-ethylhexyl) phthalate, and di-n-octyl phthalate in the wet season was greater than one. The results showed that significant levels of phthalate esters are released from landfills to the surrounding environment, which requires adequate measures to maintain the health of the ecosystem and nearby residents., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Inc. All rights reserved.)

Previous researches have reported significant levels of heavy metals in indoor air of smoking cafés. The current research aimed to evaluate the potential exposure of smoking cafés workers to heavy metals through quantifying amounts of these pollutants in urine samples. To this end, 35 waterpipe/cigarette cafés workers were selected as the exposed population, 35 employees from non-smoking cafe' as the control group 1 (CG1) and 25 cases of the normal citizens as the control group 2 (CG2); and their urine samples were taken. Samples were then prepared by acid digestion approach and measured by the ICP in order to determine amount of heavy metals in them. The findings of the current work show the significant difference among urinary levels of metals in the exposed and both CG1 and CG2 (P value < 0.05). Furthermore, urinary metal levels in samples collected from smoking café workers after the exposure were considerably higher than those were collected before the exposure (P-value <0.05). According to the findings, "tobacco type" could be considered as a leading factor for heavy metal exposure in studied smokers. Additionally, a positive and significant association was found between urinary metals and urinary levels of 8-OHdG (a markers of DNA degradation through oxidative stress). Therefore, workers in waterpipe/cigarette café can be classified as high risk people in terms of DNA oxidative damage., (Copyright © 2021 Elsevier Inc. All rights reserved.)

Polycyclic aromatic hydrocarbons (PAHs) bounded in indoor dust have significant effects in residents' health. Although various researches has evaluated exposure to PAHs in some indoor areas around the world, no work has been conducted on bioaccessibility of indoor PAHs in the buildings of Bushehr city. Therefore, dust samples were collected from various indoor microenvironments including residential buildings (RB), office buildings (OB), commercial buildings (CB), industrial buildings (IB), school classroom (SC), laboratory (LR), drugstores (DS), beauty salons (BS), smoking cafés (SC) and restaurants (Res) - 10 from each microenvironment. In order to determine the levels of polycyclic aromatic hydrocarbons (PAHs), bioaccessible PAHs, and sink sorption PAHS were analyzed in them. The results showed that the highest level of these contaminants was detected in SC and the lowest in Lab. The median concentration of dust-bound ΣPAHs, bioaccessible ΣPAHs, and sink sorption ΣPAHs in the SC samples were 10,890.00, 1157.92, and 297.28 ng/g, and they were 1160.00, 19.69, and 0.75 ng/g in Lab samples. The results also indicated that the ΣPAHs concentration had a negative and significant association with the ventilation rate (pvalue <0.05 in most cases), as well as a positive and significant relationship with smoking inside buildings (pvalue <0.05). The estimated daily intake (EDI) values calculated for residential buildings (RB) were higher compared to most of the other studied microenvironments. These observations can be due to the fact that people spend much more time in residential buildings (50% of the entire day) compared to occupational settings (22%). Thus, they intake more dust within a longer time, and are hence exposed to larger amounts of pollutants bound with these particles., (Copyright © 2021 Elsevier Inc. All rights reserved.)

Parabens are a group of chemical additive extensively utilized in various health care products and ubiquitously observed in the different environmental matrixes. Nevertheless, the exposure of women working in beauty salons to these pollutants is not well-documented. For this purpose, 50.00 women working in beauty salons were chosen as the exposed group (EG) and 35.00 housewives were chosen as the control group (GC). The concentration of methyl paraben (MeP), ethyl paraben (EtP), butyl paraben (BuP), propyl paraben (PrP), benzyl paraben (BzP), heptyl paraben (HepP), and para-hydroxybenzoic acid (4-HB) metabolite were quantified in the collected urine samples. It was seen that paraben sexist with a high detection frequency (DF) in the urine of women working in beauty salons. The results also revealed that the significant difference between the urinary parabens level in the EG and CG (P value < 0.05). The median concentration of Σparaben and HB-4 metabolite in the before exposure (BE) samples was 124.00 and 219.00 μg/L, while in the after exposure (AE) samples, it was 156.00 and 249.00 μg/L, respectively. Moreover, the parabens levels in the AE samples were considerably higher than in BE samples in women working in beauty salons (P value < 0.05). This research also documented that "personal care products (PCPs) usage" can be known as a leading factor for the urinary paraben level in the studied individuals. The median total estimated daily intakes (TEsDI) for MeP, EtP, and PrP for the studied women were obtained as 8.02, 4.57, and 7.88 μg/L respectively. Also, a significant and positive association was observed between EtP, PrP as well as BuP and 8-OhdG (as a DNA oxidative stress biomarker) (P value < 0.01). Further, a significant and positive association was found between EtP as well as BuP and some biomarkers of kidney damage (like uTIMP-1 and uKim-1). Accordingly, it can be stated that women working in beauty salons are at a high risk in terms of DNA oxidative stress and kidney damage., (Copyright © 2021 Elsevier Inc. All rights reserved.)