Australian alpine peatlands are critically important ecosystems that deliver a range of valuable services. However, our understanding of these services in Australia, particularly peatland carbon cycling, is lacking. Here, we quantified peat soil carbon (C) and nitrogen (N) concentrations, C:N ratios, and C density in eight Sphagnum-dominated peatlands on the Bogong High Plains, southeastern Australia. Soil C and N concentrations averaged 16.5 ± 13.2% and 0.6 ± 0.4%, respectively. C:N ratios averaged 30.9 ± 20.4, and C density averaged 46.6 ± 20.7 mg C cm− 3. Our findings suggest that (1) peat biogeochemistry is highly variable between sites, even at small spatial scales; and (2) while not a direct focus of the study, peat depths in this area were relatively shallow, ranging from 30 to 60 cm, most likely due to previous disturbance causing peat removal and carbon loss. Additionally, we present preliminary data investigating CO2and CH4fluxes at these sites. We recommend that future research includes (1) age dating peat cores to better understand the role of disturbance in rates of peat accumulation and loss; and (2) long-term carbon flux studies at multiple peatland sites.