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Certain fluctuations in particle number, \(n\), at fixed total energy, \(E\), lead exactly to a cut-power law distribution in the one-particle energy, \(\omega\), via the induced fluctuations in the phase-space volume ratio, \(\Omega_n(E-\omega)/\Omega_n(E)=(1-\omega/E)^n\). The only parameters are \(1/T=\langle \beta \rangle=\langle n \rangle/E\) and \(q=1-1/\langle n \rangle + \Delta n^2/\langle n \rangle^2\). For the binomial distribution of \(n\) one obtains \(q=1-1/k\), for the negative binomial \(q=1+1/(k+1)\). These results also represent an approximation for general particle number distributions in the reservoir up to second order in the canonical expansion \(\omega \ll E\). For general systems the average phase-space volume ratio \(\langle e^{S(E-\omega)}/e^{S(E)}\rangle\) to second order delivers \(q=1-1/C+\Delta \beta^2/\langle \beta \rangle^2\) with \(\beta=S^{\prime}(E)\) and \(C=dE/dT\) heat capacity. However, \(q \ne 1\) leads to non-additivity of the Boltzmann–Gibbs entropy, \(S\). We demonstrate that a deformed entropy, \(K(S)\), can be constructed and used for demanding additivity, i.e., \(q_K=1\). This requirement leads to a second order differential equation for \(K(S)\). Finally, the generalized \(q\)-entropy formula, \(K(S)=\sum p_i K(-\ln p_i)\), contains the Tsallis, Rényi and Boltzmann–Gibbs–Shannon expressions as particular cases. For diverging variance, \(\Delta\beta^2\) we obtain a novel entropy formula.

The analysis of high-energy particle collisions is an excellent testbed for the non-extensive statistical approach. In these reactions we are far from the thermodynamical limit. In small colliding systems, such as electron-positron or nuclear collisions, the number of particles is several orders of magnitude smaller than the Avogadro number; therefore, finite-size and fluctuation effects strongly influence the final-state one-particle energy distributions. Due to the simple characterization, the description of the identified hadron spectra with the Boltzmann–Gibbs thermodynamical approach is insufficient. These spectra can be described very well with Tsallis–Pareto distributions instead, derived from non-extensive thermodynamics. Using the q-entropy formula, we interpret the microscopic physics in terms of the Tsallis q and T parameters. In this paper we give a view on these parameters, analyzing identified hadron spectra from recent years in a wide center-of-mass energy range. We demonstrate that the fitted Tsallis-parameters show dependency on the center-of-mass energy and particle species (mass). Our findings are described well by a QCD (Quantum Chromodynamics) inspired parton evolution ansatz. Based on this comprehensive study, apart from the evolution, both mesonic and baryonic components found to be non-extensive ( q > 1 ), besides the mass ordered hierarchy observed in the parameter T. We also study and compare in details the theory-obtained parameters for the case of PYTHIA8 Monte Carlo Generator, perturbative QCD and quark coalescence models.