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A potential CO2 storage site located offshore the west coast of Italy, has been modelled using PFLOTRAN assuming an injection rate of 1.5 Mtons/year for 20 years. The model predicts a CO2 footprint characterised by a diameter of about 3.5 km and a maximum pressure build up of 38 bars. The solubility trapping has been quantified, predicting a dissolution in brine of 69% and 79% of the total amount of CO2 injected after 1000 and 2000 years respectively. The residual trapping has also been found to play an important role, with 9% and 6% of the injected CO2 being locked into the hosting matrix pores after 1000 and 2000 years respectively. Considering a worst-case scenario for leakages, where zero critical capillarity pressure has been assumed, minor CO2 leakages through the caprock have been identified, caused by the combined effects of the long-term structural trapping and the large and lasting overpressure caused by the CO2 injection in an ideally closed system. Finally, some preliminary work undertaken as part of an ongoing effort to couple a geochemical model to the multi-phase flow simulations reveals i) small changes in mineral volume fraction and porosity during and after the injection (~5% after 1000 years), and ii) a not negligible self-sealing effect due to precipitation of calcite in the lower layer of the caprock. Further investigations and longer physical time runs are needed to confirm this assumption, but also to gain more confidence on the geochemical model built so far and to estimate the mineral trapping potential for this site. © 2013 The Authors. Published by Elsevier Ltd. Selection and peer-review under responsibility of SINTEF Energi AS.

Italy is one of the most promising prone areas to study the CO 2 behavior underground, the caprock integrity to the CO 2 leakage, mostly in presence of pervious/geochemically active faults, due to a wide availability of CO 2 rich reservoirs at a depth between 1 and 10 km, as highlighted by recent literature. These deep CO 2 reservoirs generate at least 200 leakage areas at surface throughout Italy which have been defined “Diffuse Degassing Structures” (DDS) by INGV. These are widely studied by INGV institutionally by a long term convention with the Civil Protection Department (DPC) with the aim to catalog, monitor and assess the Natural Gas Hazard (NGH, namely the probability of an area to become a site of poisonous peri-volcanic gas exhalation from soils). More than 150 researcher of INGV are involved in monitoring areas affected by the CO 2 presence underground and at surface, by continuous monitoring on-line networks (around 40 stations throughout Italy, including the Etna area, Aeolian Islands, Umbria region, Piemonte region, etc.) and discretely (9 groups of research were involved in the last years to localize, define and monitor almost all the DDSs in Italy), by sampling and analyzing chemical and isotopic compounds, useful to discriminate the origin, evolution and natural gas hazards of the examined DDS. In this paper, we will discuss some DDS catalogued and studied by a Rome INGV Research Unit (UR 11) which focused its work in Central Italy, throughout different DDS, also in relation to the diverse seismotectonic settings, to discover buried faults as possible gas leakage pathways, mostly if they are “geochemically” activated. In particular we discuss, among the discrete monitoring techniques exploited by INGV, soil gas surveying, which consists in a collection of gas samples from the soil zone not saturated (dry zone) to measure the geogas gaseous species both in fluxes (CO 2 , CH 4 , 222 Rn) and in concentration (He, H 2 , H 2 S, helium, hydrogen, CO 2 , CH 4 , 222 Rn), that permeate the soil pores. The total CO 2 flux budget was calculated as “baseline” degassing rate of these “ CO 2 analogues”. A good discrete areal monitoring is prerequisite to design sound continuous monitoring network to monitor CO 2 related parameters in liquid/gas phases, to review the protocol of the Annex II of the European Directivity on CCS.