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Marangoni condensation is formed due to the surface tension gradient caused by the local temperature or concentration gradient on the condensate surface; thus, the investigation of the surface temperature distribution characteristics is crucial to reveal the condensation mechanism and heat transfer characteristics. Few studies have been conducted on the temperature distribution of the condensate surface. In this study, thermal infrared images were used to measure the temperature distributions of the condensate surface during Marangoni condensation for ethanol–water mixture vapor. The results showed that the surface temperature distribution of the single droplet was uneven, and a large temperature gradient, approximately 15.6 °C/mm, existed at the edge of the condensate droplets. The maximum temperature difference on the droplet surface reached up to 8 °C. During the condensation process, the average surface temperature of a single droplet firstly increased rapidly and then slowly until it approached a certain temperature, whereas that of the condensate surface increased rapidly at the beginning and then changed periodically in a cosine-like curve. The present results will be used to obtain local heat flux and heat transfer coefficients on the condensing surface, and to further establish the relationship between heat transfer and temperature distribution characteristics. [ABSTRACT FROM AUTHOR]