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Pulsed laser deposition operated by an ultra-short laser beam was used to grow in a vacuum and at room temperature natively nanostructured thin films of lead telluride (PbTe) for thermoelectric applications. Different percentages of silver (Ag), from 0.5 to 20% of nominal concentration, were added to PbTe deposited on polished technical alumina substrates using a multi-target system. The surface morphology and chemical composition were analyzed by Scanning Electron Microscope and X-ray Photoelectron Spectroscopy, whereas the structural characteristics were investigated by X-ray Diffraction. Electrical resistivity as a function of the sample temperature was measured by the four-point probe method by highlighting a typical semiconducting behavior, apart from the sample with the maximum Ag concentration acting as a degenerate semiconductor, whereas the Seebeck coefficient measurements indicate n-type doping for all the samples. The power factor values (up to 14.9 µW cm−1 K−2 at 540 K for the nominal 10% Ag concentration sample) are competitive for low-power applications on flexible substrates, also presuming the achievement of a large reduction in the thermal conductivity thanks to the native nanostructuring. [ABSTRACT FROM AUTHOR]

Small-size concentrated solar power (CSP) plants are presently not diffused due to a too-high levelized cost of electricity (LCoE), contrarily to CSP plants with capacity >100 MW, which provide LCoE < 20 cEUR/kWh. The integration of solid-state converters within CSP plants can enhance the scalability and economic competitiveness of the whole technology, especially at smaller scales, since the conversion efficiency of solid-state converters weakly depends on the size. Here a system with a high-temperature thermionic energy converter (TEC), together with an optical concentrator designed to be cheap even providing high concentration ratios, is proposed to improve the cost-effectiveness of CSP plants, thus achieving conditions for economic sustainability and market competitiveness. This is possible since TEC can act as a conversion topping cycle, directly producing electricity with a possible conversion efficiency of 24.8% estimated by applying realistic conditions and providing useful thermal flows to a secondary thermal stage. Under established technical specifications for the development of optical concentrator and TEC and according to reasonable economic assumptions, the overall plant conversion efficiency is estimated to be 35.5%, with LCoE of 6.9 cEUR/kW and considering the possibility of an 8 h storage tank for a 1 MW input solar energy system. The calculated projected value is an extremely competitive value compared with other available renewable energy technologies at small capacity scales and opens the path for accelerating the deployment of technological efforts to demonstrate the proposed solution. [ABSTRACT FROM AUTHOR]