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In this paper, cement mortar IN200 integrated with solid–solid PlusIce X25 commercial PCM was fully characterized for the first time via experimental tests and numerical simulations. An experimental setup was designed and built to evaluate the thermal performance of the composite. Experimental results confirmed the expected advantages of the PCM-loaded plaster in terms of inner surface temperature, inbound heat flux reduction, and the enhanced damping effect on the average temperature. The experimental results were used to validate and calibrate a finite element model implemented in COMSOL Multiphysics® 5.6. The model was adopted to carry out a parametric analysis assessing the influence of PCM mass fraction, phase transition temperature, and PCM mortar thickness. The composite thickness was the most influential parameter, resulting in an energy saving increase from 3.29% to 72.72% as it was increased from 10 mm to 30 mm. Moreover, the model was used in a set of dynamic simulations, reproducing real Mediterranean climatic conditions to capture the transition process for a long period in buildings. The PCM mortar located on the interior side exhibited the highest reduction in both heat flux and inner surface temperature, representing a simple approach to achieving the best thermal comfort conditions. [ABSTRACT FROM AUTHOR]

This study focuses on the development and testing under lab-controlled conditions of a hybrid sensible–latent thermal energy storage (TES) system for domestic hot water (DHW) provision in residential buildings. The TES system's design is based, for the first time in the literature, on a commercial tank-in-tank architecture integrating a macro-encapsulated commercial phase change material (PCM) inside the external tank to guarantee the safe provision of DHW and increase overall energy storage density at a reasonable cost. The PCM is a salt hydrate with a nominal melting temperature of 58 °C. The overall tank-in-tank TES volume is about 540 dm3. Almost one tenth of this volume is occupied by the PCM macro-capsules. The developed TES system was comparatively tested against the same configuration operated as a sensible TES. The obtained results showed the ability of the PCM to increase the thermal inertia inside the external tank, thus guaranteeing the quite stable provision of heat to the integral DHW tank during the stand-by periods. This effect was confirmed by the PCM's ability to achieve an energy storage capacity up to 16% higher than the reference sensible TES system. [ABSTRACT FROM AUTHOR]

Phase change slurries (PCSs) have great potential as both a heat transfer fluid and an energy storage medium for cooling processes, cold energy storage, and cold energy transportation due to desirable thermophysical properties. One of the major benefits of PCSs compared to pure phase change materials is their fluidity, thus making them cooled or heated by a heat exchanger, pumped through pipes, discharged, and stored directly in a thermal energy storage tank. The use of encapsulated phase change slurries and gas hydrate slurry has thus attracted considerable interest as reflected in the literature with a rising number of publications and institutions involved in the area. The use of bibliometric techniques has found a recent interest in the literature to define the progress of different scientific topics and inspire researchers to identify novelties. In this paper, bibliometric analysis and a detailed systematic review are carried out to show the state-of-the-art development of PCSs for cooling applications. Research gaps and hotspots are identified to help define future perspectives on this topic. [ABSTRACT FROM AUTHOR]

Solar thermal energy coupled to a seasonal sorption storage system stands as an alternative to fossil fuels to supply residential thermal energy demand in climates where solar energy availability is high in summer and low in winter, matching with a high space heating demand. Sorption storage systems usually have a high dependency on weather conditions (ambient temperature and solar irradiation). Therefore, in this study, the technical performance of a solar-driven seasonal sorption storage system, using an innovative composite sorbent and water as working fluid, was studied under three European climates, represented by: Paris, Munich, and Stockholm. All scenarios analyses were simulation-based under optimal system control, which allowed to maximize the system competitiveness by minimizing the system operational costs. The optimal scenarios profit from just 91, 82 and 76% of the total sorption system capacity, for Paris, Munich, and Stockholm, respectively. That means that an optimal control can identify the optimal sorption storage size for each location and avoid oversizing in future systems, which furthermore involves higher investment costs. The best coefficient of performance was obtained for Stockholm (0.31), despite having the coldest climate. The sorption system was able to work at minimum temperatures of −15 °C, showing independence from ambient temperature during its discharge. In conclusion, a seasonal sorption system based on selective water materials is suitable to be integrated into a single-family house in climates of central and northern Europe as long as an optimal control based on weather conditions, thermal demand, and system state is considered. [ABSTRACT FROM AUTHOR]

In this study, the development and testing of a hybrid thermal energy storage (TES) including phase change material (PCM) macro-capsules inside a vertical sensible tank is presented. The storage was specifically developed for delivering hot water on board of ships. Accordingly, a commercial PCM was selected and tested. Subsequently, the hybrid TES was designed and tested under mimicked boundary conditions at lab scale, showing the possibility of increasing the volumetric energy storage density up to 30% compared to the sensible configuration. On this basis, two numerical models were developed: a detailed one, implemented in a Fluent environment, aiming at investigating the main parameters affecting the heat transfer efficiency inside the TES and a second one, implemented in an ESP-r environment to simulate the TES as a component to be implemented inside a more complex system, thus helping its accurate design and operation through a reliable modelling phase. Both models were satisfactorily validated against the experimental results, thus being made available for future investigations and design optimization. [ABSTRACT FROM AUTHOR]

In order to reduce greenhouse gas emissions, current and future energy systems need to be made more efficient and sustainable. This change can be accomplished by increasing the penetration of renewable energy sources and using efficient technologies in energy generation systems. One way to improve the operation of the whole energy system is through the generation and end-use sector coupling. Power-to-heat energy conversion and storage technologies, in this view, are enabling technologies that can help in balancing and improving the efficiency of both thermal and electric grids. In the present paper, a comprehensive analysis of the role of heat pumps and thermal energy storage for sector coupling is presented. The main features of the analyzed technologies are presented in the context of smart electric grid, district heating and cooling and multi-carrier energy systems, and recent findings and developments are highlighted. Finally, the technical, social, and economic challenges in the adoption of investigated technologies are discussed. [ABSTRACT FROM AUTHOR]

A clear gap was identified in the literature regarding the in-depth evaluation of scaling up thermal energy storage components. To cover such a gap, a new methodological approach was developed and applied to a novel latent thermal energy storage module. The purpose of this paper is to identify some key aspects to be considered when scaling up the module from lab-scale to full-scale using different performance indicators calculated in both charge and discharge. Different normalization methods were applied to allow an appropriate comparison of the results at both scales. As a result of the scaling up, the theoretical energy storage capacity increases by 52% and 145%, the average charging power increases by 21% and 94%, while the average discharging power decreases by 16% but increases by 36% when mass and volume normalization methods are used, respectively. When normalization by the surface area of heat transfer is used, all of the above performance indicators decrease, especially the average discharging power, which decreases by 49%. Moreover, energy performance in charge and discharge decreases by 17% and 15%, respectively. However, efficiencies related to charging, discharging, and round-trip processes are practically not affected by the scaling up. [ABSTRACT FROM AUTHOR]

The need for innovative heating and cooling systems to decarbonize the building sector is widely recognized. It is especially important to increase the share of renewables at building level by maximizing self-consumption and reducing the primary energy demand. Accordingly, in the present paper, the results on a wide experimental campaign on a hybrid system are discussed. The system included a sorption module working as the topping cycle in a cascade configuration with a DC-driven vapor compression heat pump. A three-fluids heat exchanger with a phase change material (PCM), i.e., RT4 with nominal melting temperature of 4 °C, was installed on the evaporator side of the heat pump, for simultaneous operation as thermal storage and heat pumping purposes. The heat pump was connected to a DC-bus that included PV connection and electricity storage (batteries). Results showed that the energy efficiency of the heat pump in cascade operation was double compared to compression-only configuration and that, when simultaneously charging and discharging the latent storage in cascade configuration, no penalization in terms of efficiency compared to the compression-only configuration was measured. The self-sufficiency of the system was evaluated for three reference weeks in summer conditions of Athens climate and it was found that up to 100% of the electricity needed to drive the system could be self-produced for a modest cooling demand and up to 67% for the warmer conditions with high cooling demand. [ABSTRACT FROM AUTHOR]

Reticulate porous ceramic reactors use foam-type absorbers in their operation which must fulfill two essential functions: favoring the volumetric effect and increasing the mass and heat transfer by acting as a support for the reactive materials. Heating these absorbers with highly inhomogeneous concentrate irradiation induces high thermal gradients that affect their thermal performance. Owing to the critical function of these component in the reactor, it is necessary to define a selection criterion for the foam-type absorbers. In this work, we performed an experimental and numerical thermal analysis of three partially stabilized zirconia (PSZ) foam-type absorbers with pore density of 10, 20, and 30 PPI (pores per inch) used as a volumetric absorber. A numerical model and an analytical approximation were developed to reproduce experimental results, and calculate the thermal conductivity, as well as volumetric heat transfer coefficient. The results show that an increase in pore density leads to an increase in the temperature difference between the irradiated face and the rear face of the absorber, this occurs because when pore density increases the concentrated energy no longer penetrates in the deepest space of the absorber and energy is absorbed in areas close to the surface; therefore, temperature gradients are created within the porous medium. The opposite effect occurs when the airflow rate increases; the temperature gradient between the irradiated face and the rear face is reduced. This behavior is more noticeable at low pore densities, but at high pore densities, the effect is less relevant because the internal structure of porous absorbers with high pore density is more complex, which offers obstructions or physical barriers to airflow and thermal barriers to heat transfer. When the steady state is reached, the temperature difference between the two faces of the absorber remains constant if the concentrate irradiation changes slightly, even changing the airflow rate. The results obtained in this work allow us to establish a selection criterion for porous absorbers that operate within solar reactors; this criterion is based on knowledge of the physical properties of the porous absorber, the environment, the working conditions, and the results expected. [ABSTRACT FROM AUTHOR]

Industrial circulating cooling water contains a large amount of low-quality energy, which is lost to the environment through cooling towers. It is of great significance and potential to recover the waste heat to improve energy-saving effects and economic efficiency. However, the effect of common water harvesting and energy saving devices is not significant. Heat pumps have been shown to be effective in improving low-quality heat energy in energy conversion systems, although there are not many applications of heat pump scenarios in engineering practice. Based on this, a recovery solution of circulating cooling water waste heat and water resource using lithium bromide absorption heat pump has been put forward. The energy-saving performance of the recovery system was simulated and analyzed using Aspen Plus V10.0 (Bedford, MA, USA) to explore the effects of the parameters of the working medium in evaporators, condensers, absorbers, generators, heat exchangers, etc., and the modelling results indicated that the evaporation pressure and temperature have a great influence on the system COP (coefficient of performance) and can raise the thermal economy of the system. The heat from driving steam and heating capacity both increased with the increase in generating temperature, while the increase in temperature difference between evaporation and condensation inhibits the COP of heat pump systems. Furthermore, economic analyses and comparisons of the recovery solutions were conducted and the recovery solution of circulating cooling water waste heat with heat pump had the best economic performance due to the annual income from the recovery of waste heat and water resource. The static payback period results indicate that the recovery solution from circulating cooling water waste heat with a heat pump has better economic performance than the scenario with a cooling tower. The waste heat recovery solution with a heat pump can improve the thermal economy of the system and has a great guiding significance for engineering practice. [ABSTRACT FROM AUTHOR]

The study of flows with a high degree of turbulence in boundary layers, near-wall jets, gas curtains, separated flows behind various obstacles, as well as during combustion is of great importance for increasing energy efficiency of the flow around various elements in the ducts of gas-dynamic installations. This paper gives some general characteristics of experimental work on the study of friction and heat transfer on a smooth surface, in near-wall jets, and gas curtains under conditions of increased free-stream turbulence. Taking into account the significant effect of high external turbulence on dynamics and heat transfer of separated flows, a similar effect on the flow behind various obstacles is analyzed. First of all, the classical cases of flow separation behind a single backward-facing step and a rib are considered. Then, more complex cases of the flow around a rib oriented at different angles to the flow are analyzed, as well as a system of ribs and a transverse trench with straight and inclined walls in a turbulent flow around them. The features of separated flow in a turbulized stream around a cylinder, leading to an increase in the width of the vortex wake, frequency of vortex separation, and increase in the average heat transfer coefficient are analyzed. The experimental results of the author are compared with data of other researchers. The structure of separated flow at high turbulence—characteristic dimensions of the separation region, parameters of the mixing layer, and pressure distribution—are compared with the conditions of low-turbulent flow. Much attention is paid to thermal characteristics: temperature profiles across the shear layer, temperature distributions over the surface, and local and average heat transfer coefficients. It is shown that external turbulence has a much stronger effect on the separated flow than on the boundary layer on a flat surface. For separated flows, its intensifying effect on heat transfer is more pronounced behind a rib than behind a step. The factor of heat transfer intensification by external turbulence is most pronounced in the transverse cavity and in the system of ribs. [ABSTRACT FROM AUTHOR]

Hexagonal boron nitride and silicone rubber (h-BN/SR) composites were prepared by the mechanical stirring method, and their crystal morphology, chemical structure, thermal properties, and compression stress–strain performance were investigated. The experimental results suggest that silicone rubber combined with h-BN exhibits better thermal conductivity and mechanical properties. When the proportion of h-BN is 30 wt%, the thermal conductivity of the h-BN/SR composite material is 0.58 W/m∙K, which is 3.4 times that of pure silicone rubber. At the same time, the compressive strength of h-BN/SR is 4.27 MPa, which is 6.7 times that of pure silicone rubber. Furthermore, the finite element model was employed to numerically analyze the thermal behavior of a battery with a h-BN/SR composite as the thermal interface material. The analytical results show that the highest temperature of the battery decreased when using h-BN/SR as the thermal interface material in the battery thermal management system. The h-BN/SR composite can thus effectively improve the safety properties of batteries. [ABSTRACT FROM AUTHOR]

Increasing the energy efficiency of residential and non-residential buildings is a crucial point towards the development of the sustainable cities of the future. To reach such a goal, the commonly employed intervention measures (for instance, on facades and glass) are not sufficient and efforts in reaching a fully renewable energy generation are mandatory. In this context, this paper discusses the applicability of a system with solar and biomass as the main energy sources in different climates for heating, cooling, domestic hot water and electricity generation in office buildings. The energy system includes solar thermal collectors with thermoelectric generators, a biomass boiler, a reversible heat pump/organic Rankine cycle and an adsorption chiller. The results showed that the system can operate with a share of renewables higher than 70% for all energy needs, with up to 80% of the overall energy demand supplied only by solar and biomass sources even in the northern locations. [ABSTRACT FROM AUTHOR]

This manuscript presents a simplified method of modeling fixed-bed reactors based on the porous medium. The proposed method primarily allows the necessity of precisely mapping the internal structure of the bed—which usually is done using real object imaging techniques (like X-ray tomography) or numerical methods (like discrete element method (DEM))—to be avoided. As a result, problems with generating a good quality numerical mesh at the particles' contact points using special techniques, such as by flattening spheres or the caps method, are also eliminated. The simplified method presented in the manuscript is based on the porous medium method. Preliminary research has shown that the porous medium method needs modifications. This is because of channeling, wall effects, and local backflows, which are substantial factors in reactors with small values of tube-to-particle-diameter ratio. The anisotropic thermal conductivity coefficient was introduced to properly reproduce heat transfer in the direction perpendicular to the general fluid flow. Since the commonly used fixed-bed reactor models validation method based on comparing the velocity and temperature profiles in the selected bed cross-section is not justified in the case of the porous medium method, an alternative method was proposed. The validation method used in this work is based on the mass-weighted average temperature increase and area-weighted average pressure drop between two control cross-section of the reactor. Thanks to the use of the described method, it is possible to obtain satisfactorily accurate results of the fixed-bed reactor model with no cumbersome mesh preparation and long-term calculations. [ABSTRACT FROM AUTHOR]

Molten salt LiNO3-NaNO3-KNO3 has been investigated as heat transfer and thermal storage media for its low melting point and good thermal performance. In this paper, nanofluids were synthesized by dispersing MgO nanoparticles into LiNO3-NaNO3-KNO3, and the effects of nanoparticles on thermal properties were studied with different sizes (20–100 nm) and mass percent concentrations (0.5–2.0 wt.%). The addition of nanoparticles had little effect on melting temperature, and led to a slight increase in enthalpy of fusion by 2.0–5.5%. Compared with base salt, the density of nanofluid increased a little by 0.22–1.15%. The scanning electron microscope (SEM) test implied that nubby and punctate microstructures were responsible for larger surface area and interfacial energy, which could lead to the improvement of specific heat capacity reaching 2.6–10.6%. The heat transfer characteristics remarkably increased with the addition of nanoparticles, and the enhancement of average thermal diffusivity and conductivity of salt with 1 wt.% nano-MgO could be 5.3–11.7% and 11.3–21.2%, respectively. Besides, the viscosities of nanofluids slightly increased for 3.3–8.1%. As a conclusion, nano-MgO was positively influential on the thermal properties of LiNO3-NaNO3-KNO3 base salt. [ABSTRACT FROM AUTHOR]

The thermal masses of components influence the performance of many adsorption heat pump systems. However, typically when experimental adsorption systems are reported, data on thermal mass are missing or incomplete. This work provides original measurements of the thermal masses for experimental sorption heat exchanger hardware. Much of this hardware was previously reported in the literature, but without detailed thermal mass data. The data reported in this work are the first values reported in the literature to thoroughly account for all thermal masses, including heat transfer fluid. The impact of thermal mass on system performance is also discussed, with detailed calculation left for future work. The degree to which heat transfer fluid contributes to overall effective thermal mass is also discussed, with detailed calculation left for future work. This work provides a framework for future reporting of experimental thermal masses. The utilization of this framework will enrich the data available for model validation and provide a more thorough accounting of adsorption heat pumps. [ABSTRACT FROM AUTHOR]

In this study, the definition of a new methodology for a preliminary evaluation of the working boundary conditions under which a seasonal thermal energy storage (STES) system operates is described. The approach starts by considering the building features as well as the reference heating system in terms of solar thermal collectors' technology, ambient heat sinks/source, and space heating distribution systems employed. Furthermore, it is based on a deep climatic analysis of the place where the STES needs to be installed, to identify both winter and summer operating conditions. In particular, the STES energy density is evaluated considering different space heating demands covered by the STES (ranging from 10% up to 60%). The obtained results demonstrate that this approach allows for the careful estimation of the achievable STES density, which is varies significantly both with the space heating coverage guaranteed by the STES as well as with the ambient heat source/sink that is employed in the system. This confirms the need for careful preliminary analysis to avoid the overestimation of the STES material volume. The proposed approach was then applied for different climatic conditions (e.g., Germany and Sweden) and the volume of one of the most attractive composite sorbent materials reported in the literature, i.e., multi-wall carbon nanotubes (MWCNT)-LiCl, using water as the working fluid, needed for covering the variable space heating demand in a Nearly Zero Energy Building (NZEB) was calculated. In the case of Swedish buildings, it ranges from about 3.5 m3 when 10% of the space heating demand is provided by the STES, up to 11.1 m3 when 30% of the space heating demand is provided by the STES. [ABSTRACT FROM AUTHOR]

Hybrid sorption-compression systems are gaining interest for heating/cooling/ refrigeration purposes in different applications, since they allow exploiting the benefits of both technologies and a better utilization of renewable sources. However, design of such components is still difficult, due to the intrinsic complexity of the systems and the lack of reliable models. In particular, the combination of adsorption-compression cascade unit has not been widely explored yet and there are no simulations or sizing tools reported in the literature. In this context, the present paper describes a model of a hybrid adsorption-compression system, realised in Modelica language using the commercial software Dymola. The models of the main components of the sorption and vapour compression unit are described in details and their validation presented. In addition, the integrated model is used for proving the feasibility of the system under dynamic realistic conditions and an example of the technical sizing that the model is able to accomplish is given. [ABSTRACT FROM AUTHOR]