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Using salt caverns for an underground strategic petroleum reserve (SPR) is considered as an ideal approach due to the excellent characteristics of low porosity, low permeability, self-healing of damage, and strong plastic deformation ability of rock salt. Salt deposits in China are mostly layered rock salt structures, with the characteristics of many interlayers, bringing great challenges for the construction of SPR facilities. Studying the microscopic pore characteristics of the rock surrounding SPR salt caverns in different environments (with brine and crude oil erosion) is necessary because the essence of mechanical and permeability characteristics is the macroscopic embodiment of the microscopic pore structure. In this paper, XRD tests and SEM tests are carried out to determine the physical properties of storage media and surrounding rock. Gas adsorption tests and mercury intrusion tests are carried out to analyze the microscopic pore structure, specific surface area variation and total aperture distribution characteristics of SPR salt cavern host rock. Results show that: (1) Large numbers of cores in interlayer and caprock may provide favorable channels for the leakage of high-pressure crude oil and brine. (2) The blockage of pores by macromolecular organic matter (colloid and asphaltene) in crude oil will not significantly change the structural characteristics of the rock skeleton, which is beneficial to the long-term operation of the SPR salt cavern. (3) The water–rock interaction will bring obvious changes in the micro-pore structure of rock and increase the leakage risk of the storage medium. The results can provide theoretical bases and methods for the tightness analysis of China's first underground SPR salt cavern. [ABSTRACT FROM AUTHOR]

In order to explore the influences of effective stress change on gas adsorption–desorption behaviors, primary undeformed coal (PUC) and tectonically deformed coal (TDC) from the same coal seam were used for adsorption–desorption experiments under different effective stress conditions. Experimental results showed that gas adsorption and desorption behaviors were controlled by the coal core structure and the pore-fissure connectivity under effective stress. The coal matrixes and fissures were compressed together under effective stress to reduce connectivity, and it was difficult for gas to absorb and desorb as the stress increased in primary undeformed coal. The loose structure of tectonically deformed coal cores can help gas to fully contact with the coal matrix, resulting in higher adsorption gas volumes. The support of coal particles in tectonically deformed coal cores weakens the compression of intergranular pores when effective stress increases, which in this study manifested in the fact that while the volumetric strain of the coal matrix change rapidly under low effective stress, but the adsorbed gas volume did not decrease significantly. The reduction in effective stress induced the rapid elastic recovery of the coal matrix and the expansion of cracks, and increased desorption gas volumes. The stress reduction significantly increased the initial gas volume of the tectonically deformed coal, while promoting slow and continuous gas desorption in primary undeformed coal. Therefore, the promotion effect of the reservoir pressure reduction on gas desorption and coal connectivity enhancement can help to improve coalbed methane recovery in primary undeformed coal and tectonically deformed coal reservoirs. [ABSTRACT FROM AUTHOR]

Fine dissection of microscopic pore structure variations between the Niutitang Formation and the Wufeng-Longmaxi Formation will help to improve the understanding of the underlying geological theory of shale gas in northern Guizhou Province. The stratigraphic, geochemical, physical, and tectonic properties of the two formations vary greatly, resulting in differential development of the microscopic pore structure among reservoirs and, as a result, major variances in gas concentration. To explore the mechanism of differential pore evolution, experimental techniques and instruments such as gas adsorption, liquid intrusion, SEM, XRD, and organic geochemical tests were utilized. The results indicate that the Wufeng-Longmaxi Formation is in a high-maturity stage, while the Niutitang Formation is in an over-mature stage. The latter has a higher TOC content. Both petrographic phases are siliceous shale petrographic phases, and the former has more developed dissolution pores with better pore volume, throat radius, and macropore pore diameters than the latter, as well as organic matter pores, intergranular pores, and microfracture structural parameters, whereas the specific surface area is the opposite. The differences in reservoir pore formation between the two formations were analyzed, and the results showed that the petrographic type, thermal evolution, and tectonic preservation conditions were the primary controlling elements of differential shale gas reservoir formation. A differential reservoir-forming model of the Wufeng-Longmaxi Formation and the Niutitang Formation was constructed, providing a geological and theoretical basis for shale gas geological exploration in northern Guizhou Province. [ABSTRACT FROM AUTHOR]

Lower Cambrian shale and lower Silurian shale are both typical of oil-prone kerogen and siliceous composition, but different in thermal maturities. Porosity differences were determined in marine shales between the two shales. Measurements were utilized including organic geochemistry, XRD, scanning electron microscopy (SEM) and N2 gas adsorption. Pore volume (PV) of lower Silurian shale was approximately 1.5 times higher than that of lower Cambrian shale, and pore surface area (PSA) of lower Silurian shale was almost 2.5 times higher than that of lower Cambrian shale. Lower Cambrian shale and lower Silurian shale possess similar materials, but distinctive thermal degrees. Evolution mechanisms of different types of pores, especially organic matter (OM)-hosted pores, may trigger this different pore features. Pores of rigid framework are the residue of primary interparticle pores during the burial history. Pores associated with clay flakes can be preserved well adjacent to rigid grains or secondary minerals acting as rigid frameworks or grain supporters. Dissolved pores in both lower Cambrian shale and lower Silurian shale barely contribute to the total porosity and mean little to the permeability. Both excessive OM content and over thermal maturity are detrimental to development of OM-hosted pores. Rigid particles, clay flakes, and OM commonly co-exist within shale matrix. Rigid grains act as supporters, clay flakes confine ample space, and OM first migrates into and provides secondary OM-hosted pores. In this condition, pores can be preserved owing to associating matrix with good mechanic and chemical stability. The significant differences of structural settings result into various hydrocarbon explosion efficiency and different pressure circumstance, which consequently leads to the different pore features between the two shales. For lower Cambrian shale, overpressure circumstance diminish if hydrocarbon expels outside of the shale system, and OM-hosted pores destroy through compaction. Sustaining overpressure and abundant residue hydrocarbon (migrated OM) make positive contributions to the pore properties, in terms of numbers, diameters and connectivity of the lower Silurian shale samples. [ABSTRACT FROM AUTHOR]

The effect of clay minerals on the methane adsorption capacity of shales is a basic issue that needs to be clarified and is of great significance for understanding the adsorption characteristics and mechanisms of shale gas. In this study, a variety of experimental methods, including XRD, LTNA, HPMA experiments, were conducted on 82 marine shale samples from the Wufeng–Longmaxi Formation of 10 evaluation wells in the southern Sichuan Basin of China. The controlling factors of adsorption capacities were determined through a correlation analysis with pore characteristics and mineral composition. In terms of mineral composition, organic matter (OM) is the most key methane adsorbent in marine shale, and clay minerals have little effect on methane adsorption. The ultra-low adsorption capacity of illite and chlorite and the hydrophilicity and water absorption ability of clay minerals are the main reasons for their limited effect on gas adsorption in marine shales. From the perspective of the pore structure, the micropore and mesopore specific surface areas (SSAs) control the methane adsorption capacity of marine shales, which are mainly provided by OM. Clay minerals have no relationship with SSAs, regardless of mesopores or micropores. In the competitive adsorption process of OM and clay minerals, OM has an absolute advantage. Clay minerals become carriers for water absorption, due to their interlayer polarity and water wettability. Based on the analysis of a large number of experimental datasets, this study clarified the key problem of whether clay minerals in marine shales control methane adsorption. [ABSTRACT FROM AUTHOR]