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Reducing the phenomenon of food waste and effective management of already wasted food in the form of post-consumer waste, included in the source-separated organic fraction of municipal solid waste (SS-OFMSW) from households and catering facilities, are some of the key challenges of the circular economy (CE), in particular in highly urbanized areas. The basis for the effective use of this waste is the knowledge of its physical and chemical properties. The main objective of the paper is to identify the key technological and organizational parameters for selective collection determining the characteristics of the SS-OFMSW and, consequently, the optimal path for its management. This paper presents the results of qualitative research of SS-OFMSW generated in the capital of Poland—Warsaw—coming from three sources: multi- and single-family housing and catering facilities. The collection efficiency of this waste was determined in the form of quality in container rate (QCR = 92–97%) and variability in terms of impurities and admixtures present in it (CV = 56–87%). High variability indicates that the system of selective waste collection in Warsaw is immature, which may hinder undertaking activities in the field of waste management planning. The study confirmed the suitability of the tested SS-OFMSW for organic recycling, especially using anaerobic digestion (AD), to which it is predisposed by water content, C/N, and biomethane potential (BMP). All tested food waste is characterized by a high yield of biogas in the range of 384–426 m3/Mg VS and an average share of methane in biogas at the level of 52–61%. Fertilizer properties, moisture, and its gas potential show little variability (CV ≤ 16%), which means that these data can be treated as stable data. The obtained results indicate the optimal direction for the collection and processing of SS-OFMSW based on post-consumer food waste in urbanized areas. [ABSTRACT FROM AUTHOR]

Hydrogen is widely considered as the fuel of the future. Due to the challenges present during hydrogen production using conventional processes and technologies, additional methods must be considered, like the use of microorganisms. One of the most promising technologies is dark fermentation, a process where microorganisms are utilized to produce hydrogen from biomass. The paper provides a comprehensive overview of the biological processes of hydrogen production, specifically emphasizing the dark fermentation process. This kind of fermentation involves bacteria, such as Clostridium and Enterobacterium, to produce hydrogen from organic waste. Synthetic microbial consortia are also discussed for hydrogen production from different types of biomasses, including lignocellulosic biomass, which includes all biomass composed of lignin and (hemi)cellulose, sugar-rich waste waters, and others. The use of genetic engineering to improve the fermentation properties of selected microorganisms is also considered. Finally, the paper covers the important aspect of hydrogen management, including storage, transport, and economics. [ABSTRACT FROM AUTHOR]

As the global demand for renewable energy continues to rise, biogas production has emerged as a promising solution for sustainable energy generation. This review article presents the advantages of biogas technologies (mainly agricultural, based on waste of animal and plant origin) and extensively discusses the main principles of biogas production in the anaerobic digestion (AD). In this respect, the main parameters of the process, which require monitoring and decisive for its efficiency are described, therefore: temperature, pH value, retention time and organic loading rate (OLR). The principles of substrate selection are also discussed and the necessity and advantages of the use of organic waste according to the model of a circular economy and the concept of sustainable development, are indicated. It is emphasized that according to the new European regulations, the crops classified as food cannot be considered energy crops. The part on biogas production is summarised with an explanation of the necessity to treat and purify biogas. Biogas purification is important from the point of view of the efficiency of its conversion into electricity. A special place in this paper is devoted to the design, construction, functioning and operation of biogas plants, based on both scientific and practical aspects. In conclusion of this chapter, the economic aspects and profitability of operating biogas plants are discussed. Cost and benefit analyses are the major tool used for the systematic evaluation of the financial costs and potential benefits associated with the operation of biogas plants. The important fact is that the return on investment can be achieved within a few years, provided the activities are well-planned and executed. In addition to the fundamental issues of the operation of biogas plants, this article presents the global situation regarding the development of biogas plants, discussing in detail the specific needs and limitations on different continents. It is a interesting and extensive part of this article. The global agricultural biogas market is at very different levels of development. Most such installations are located in Asia and Europe. China has the highest number of biogas plants, with more than 100,000 biogas plants, followed by Germany with over 10,000 plants. In addition to the 100,000 biogas plants, China also has a large number of household biogas units, which gives a total of approx. 40 million operating units. The article concludes with a discussion of opportunities and barriers to the development of biogas plants, pointing to: financial issues, access to feedstock, political regulations, public awareness and the geopolitical situation. The most frequently cited reasons for investment failure include economic problems, lack of professional knowledge. [ABSTRACT FROM AUTHOR]

Biowaste represents a significant fraction of municipal solid waste (MSW). Its separate collection is considered as a useful measure to enhance waste management systems in both the developed and developing world. This paper aims to compare the environmental performance of three market-ready technologies currently used to treat biowaste—biowaste composting, fermentation, and biowaste incineration in waste-to-energy (WtE) plants as a component of residual municipal solid waste (RES). Global warming potential (GWP) was applied as an indicator and burdens related to the operation of facilities and credits obtained through the products were identified. The environmental performance of a WtE plant was investigated in detail using a model, implementing an approach similar to marginal-cost and revenues, which is a concept widely applied in economics. The results show that all of the treatment options offer an environmentally friendly treatment (their net GWP is negative). The environmental performance of a WtE plant is profoundly affected by its mode of its operation, i.e., type of energy exported. The concept producing environmental credits at the highest rate is co-incineration of biowaste in a strictly heat-oriented WtE plant. Anaerobic digestion plants treating biowaste by fermentation produce fewer credits, but approximately twice as more credits as WtE plants with power delivery only. [ABSTRACT FROM AUTHOR]

The Adrar region (Algeria) has a total of 397,800 date palm trees (Phoenix dactylifera L.). Due to annual palm cleaning, large quantities of lignocellulosic biomass are produced. Depending on the variety, an average of 65 kg of biowaste is obtained per palm tree. Since the value of this biowaste is underrated, most of the palms are burned outdoors, causing air and visual pollution. This work explores the gasification potential of lignocellulosic waste from date palms (Phoenix dactylifera L. Takarbouche variety) into useful energy. The technology investigated is air updraft fixed-bed gasification, thanks to an originally designed and built reactor, with the capability to process 1 kg of feedstock. Four types of palm waste—namely, palms, petioles, bunch, and bunch peduncles—are first characterized (bulk density, proximate analysis, fixed carbon, elemental composition, and calorific value) and then used as feedstock for two gasification tests each. The syngas produced for the four date palm wastes is combustible, with an outlet temperature between 200 and 400 °C. The operating temperature inside the gasifier varies according to the feature of the biomass cuts (from 174 °C for the peduncles to 557 °C for palms). The experimental setup is also equipped with a cyclone, allowing for the recovery of some of the tar produced during the tests. Finally, the results show that the residence time has a positive effect on the conversion rate of date palm waste, which can significantly increase it to values of around 95%. [ABSTRACT FROM AUTHOR]

Energy and environmental issues are of great importance in the present era. The transition to renewable energy sources necessitates technological, political, and behavioral transformations. Hydrogen is a promising solution, and many countries are investing in the hydrogen economy. Global demand for hydrogen is expected to reach 120 million tonnes by 2024. The incorporation of hydrogen for efficient energy transport and storage and its integration into the transport sector are crucial measures. However, to fully develop a hydrogen-based economy, the sustainability and safety of hydrogen in all its applications must be ensured. This work describes and compares different technologies for hydrogen production, storage, and utilization (especially in fuel cell applications), with focus on the research activities under study at SaRAH group of the University of Naples Federico II. More precisely, the focus is on the production of hydrogen from bio-alcohols and its storage in formate solutions produced from renewable sources such as biomass or carbon dioxide. In addition, the use of materials inspired by nature, including biowaste, as feedstock to produce porous electrodes for fuel cell applications is presented. We hope that this review can be useful to stimulate more focused and fruitful research in this area and that it can open new avenues for the development of sustainable hydrogen technologies. [ABSTRACT FROM AUTHOR]

Industrial human activity has led to the release of substantial amounts of heavy metals into the environment. Contamination of water with heavy metals such as lead, cadmium, copper, zinc, chromium, or nickel represents a serious problem. As part of the circular economy, it is appropriate to use biowaste from agriculture, fisheries, and the timber industry as biosorbents. In this literature review, the potential of using these biowaste groups as biosorbents for metal removal is presented. This biowaste is characterized by the presence of carboxyl, hydroxyl, carbonyl, amide, amine, sulfydryl, and other groups on their surface, which form complexes and chelates with metals present in water. Biosorption seems to be a potential alternative to conventional technologies for removing or recovering heavy metals from water or wastewater, which are uneconomical and generate additional waste. The paper demonstrates that harnessing the potential of biowaste to remove metals is beneficial to the environment as they can solve the problem of incineration and realise recycling that meets the circular economy. Although the choice of a suitable biosorbent for the removal of a particular metal involves a lot of research, the high biosorption efficiency, low cost, and renewability justify their use. [ABSTRACT FROM AUTHOR]

Biowaste management is at the center of attention in recent years due to the increased focus on Circular Economy practices. Lesvos has numerous food processing facilities and olive mills, and therefore Olive Mill Wastewater (OMWW) is a wastewater stream that requires attention. In this study, a holistic experimental set-up that combines aerobic and anaerobic treatment strategies was developed taking into consideration the hydrothermal carbonization of AD digestate along with locally available OMWW. The study focuses on the hydrothermal carbonization (HTC) of anaerobic residues from biogas production, and food waste was co-utilized with spent coffee grounds (SCG). The reduced volatile solids of SCG have some effects on the final products. AD produced methane yields of 54.7% for the food waste and 52.4%. for the feedstock with added SCG. At the same time, the feedstock that contained SCG produced more hydrochar that reached up to 50% of the yield. Hydrothermal carbonization in a water medium produced liquids with basic pH values around 8 and conductivities of 4–5 mS/cm, while the samples that were treated in OMWW medium had pH values close to 5.5 and conductivities of around 12 mS/cm. The produced hydrochars have significant calorific values that exceeded 20 MJ/kg for almost all the samples. Overall, HTC with OMWW as a medium was able significantly reduce the COD of OMWW while resulting in hydrochars with increased heating values. [ABSTRACT FROM AUTHOR]

The production of biogas from biodegradable waste generated in all sectors of the economy in Poland is a key issue for the diversification of energy sources and climate neutrality. The biogas balances presented in the literature based on bio-waste often contain overly optimistic data, which in reality only represent the theoretical potential of biogas in Poland. The pragmatic approach presented in this study fills a gap in research by presenting a technical balance of biogas (real potential) that can be realistically achieved. The objective of the work was to perform a biogas balance in the context of electricity and heat generation in cogeneration units. The tests made it possible to estimate the technical potential of biogas, depending on the source of its generation, the possibility of its conversion to biomethane and biohydrogen and the methods of its use. The research results showed a 30% increase in biogas potential on an annual basis compared to the current state, resulting in a 29% increase in electricity production and a 28% increase in heat production. The technical potential of biogas was estimated at 2186.62 million m3, which would allow for the production of 4627.06 GWh of electricity and 1869.64 TG of heat. The technical balance of biogas and the potential energy production can serve as input material for developing plans and strategies for the development of renewable energy sources in Poland. The work is consistent with the issues of balancing the renewable energy resources from biogas and the methods of conversion into other energy carriers using sustainable energy transformations in order to optimise energy production processes. [ABSTRACT FROM AUTHOR]

Densely populated areas with large incoming populations have difficulty achieving high separate collection rates of municipal solid waste. The manuscript analyzes the link between biowaste collection and circular economy requirements as a fulfilment of the recycling rates and using biogas as a sustainable energy source. Three biowaste collection scenarios and three technical scenarios for its treatment are considered. The first scenario assumes only composting for biowaste treatment, the next includes also anaerobic digestion. In the years 2020–2050, the separate biowaste collection level will increase, depending on the scenario, from 26.9 kg/inh. up to 148.1kg/inh. By 2030, the quantity of biogas generated from biowaste can grow to almost 9 million m3/year, enabling the production of renewable energy at annual levels of almost 17 GWh and 69 TJ. Using the third scenario, the quantity of biogas generated grows more than twice (in 2035). If the capture rate of biowaste increases from 15% to 20% and then to 25%, the quantity of biogas generated grows by, respectively, 65% and more than 100%. Unfortunately, none of the scenarios enables the required municipal solid waste recycling rates in 2030 (60%) and 2035 (65%), which demonstrates the significant need to develop more effective separate collection systems, including biowaste. Methodology applied in the paper can be used for other cities and regions trying to meet circular economy demands. [ABSTRACT FROM AUTHOR]

To produce a valuable final product from anaerobic digestion (AD), one of the preferred methods of organic recycling, high quality feedstock must be ensured. In this study, separately collected real biowaste (B) was used, consisting of 90% food waste and 10% green waste. The priority issues of AD are both high methane production (MP) and high organics removal efficiency (as organic matter, OM and dissolved organics, and DCOD), which may be improved after pre-treatment. In this study, the effect of hydrothermal pre-treatment (BHT) and enzymatic additives (BE) on MP and organics removal from biowaste in mesophilic (37 °C) conditions was analyzed. To assess the adequacy of pre-treatment application, biowaste without treatment (BWT) was used. Pre-treatment of biowaste prior to AD affected the maximal MP, the removal effectiveness of both OM and DCOD, and the kinetic parameters of these processes. For BWT, the maximal cumulative MP reached 239.40 ± 1.27 NL/kg OM; the kinetic coefficient of MP (kCH4) and the initial MP rate (rCH4) were 0.32 ± 0.02 d−1 and 76.80 ± 1.10 NL/(kg OM·d), respectively. After hydrothermal pre-treatment, the MP of BHT (253.60 ± 1.83 NL/kg OM) was 6.3% higher than BWT. However, the highest MP was found for BE, 268.20 ± 1.37 NL/kg OM; to compare, it increased by 12.1% and 5.5% with BWT and BHT, respectively. However, the kinetic parameters of MP were highest with BHT:kCH4 0.56 ± 0.02 d−1 vs. 0.32 ± 0.02 d−1 (BWT) and 0.34 ± 0.02 d−1 (BE); rCH4 141.80 ± 0.02 NL/(kg OM·d) (BHT) vs. 76.80 ± 1.10 NL/(kg OM·d) (BWT) and 89.80 ± 0.50 NL/(kg OM·d) (BE). The effectiveness of OM removal was highest with BE, similarly to the MP with the use of an enzymatic additive. The kinetics of OM removal (rOM, kOM) were highest with BHT, similarly to the kinetics of MP (rCH4, kCH4). The highest effectiveness of OM and, consequently, its lowest final content obtained with BE means that the organics were used most efficiently, which, in turn, may result in obtaining a more stable digestive system. [ABSTRACT FROM AUTHOR]

The paper presents, for the first time, the results of fuel characteristics of biochars from torrefaction (a.k.a., roasting or low-temperature pyrolysis) of elephant dung (manure). Elephant dung could be processed and valorized by torrefaction to produce fuel with improved qualities for cooking. The work aimed to examine the possibility of using torrefaction to (1) valorize elephant waste and to (2) determine the impact of technological parameters (temperature and duration of the torrefaction process) on the waste conversion rate and fuel properties of resulting biochar (biocoal). In addition, the influence of temperature on the kinetics of the torrefaction and its energy consumption was examined. The lab-scale experiment was based on the production of biocoals at six temperatures (200–300 °C; 20 °C interval) and three process durations of the torrefaction (20, 40, 60 min). The generated biocoals were characterized in terms of moisture content, organic matter, ash, and higher heating values. In addition, thermogravimetric and differential scanning calorimetry analyses were also used for process kinetics assessment. The results show that torrefaction is a feasible method for elephant dung valorization and it could be used as fuel. The process temperature ranging from 200 to 260 °C did not affect the key fuel properties (high heating value, HHV, HHVdaf, regardless of the process duration), i.e., important practical information for proposed low-tech applications. However, the higher heating values of the biocoal decreased above 260 °C. Further research is needed regarding the torrefaction of elephant dung focused on scaling up, techno-economic analyses, and the possibility of improving access to reliable energy sources in rural areas. [ABSTRACT FROM AUTHOR]

Waste solid residue from the hydrothermal extraction of pectin derived from sugar beet pulp was used as feedstock in the production of 5-hydroxymethylfurfural (5-HMF). The depolymerization of pectin-free sugar beet pulp (PF-SBP) to monosaccharides and their dehydration to 5-HMF were conducted in subcritical water using a batch reactor. The experimental design methodology was used in order to model the hydrothermal process and to optimize the operational parameters of the reaction, namely temperature and holding time. These parameters are required to achieve the highest yield of 5-HMF. The model predicts, in good agreement with experimental results (R2 = 0.935), an optimal yield of 5-HMF (of approximately 38% in relation to the cellulosic fraction content in the PF-SBP) at a temperature of 192.5 °C and a holding time of about 51.2 min. 5-HMF was successfully isolated from the reaction mixture using the liquid–liquid extraction method. The results are suitable for industrial upscaling and may become an incentive to introduce a new, environmentally friendly, uncomplicated, and efficient waste treatment method. The method would be used to treat products from the sugar refining industry, the treatment of which has proven to be problematic until now. [ABSTRACT FROM AUTHOR]

The increase in the amount of municipal solid waste (MSW) generated, among other places, in households is a result of the growing population, economic development, as well as the urbanisation of areas with accompanying insufficiently effective measures to minimise waste generation. There are many methods for treating municipal waste, with the common goal of minimising environmental degradation and maximising resource recovery. Biodegradable waste, including selectively collected biowaste (BW), also plays an essential role in the concept of the circular economy (CE), which maximises the proportion of waste that can be returned to the system through organic recycling and energy recovery. Methane fermentation is a waste treatment process that is an excellent fit for the CE, both technically, economically, and environmentally. This study aims to analyse and evaluate the problem of odour nuisance in municipal waste biogas plants (MWBPs) and the impact of the feedstock (organic fraction of MSW-OFMSW and BW) on this nuisance in the context of CE assumptions. A literature review on the subject was carried out, including the results of our own studies, showing the odour nuisance and emissions from MWBPs processing both mixed MSW and selectively collected BW. The odour nuisance of MWBPs varies greatly. Odour problems should be considered regarding particular stages of the technological line. They are especially seen at the stages of waste storage, fermentation preparation, and digestate dewatering. At examined Polish MWBPs cod ranged from 4 to 78 ou/m3 for fermentation preparation and from 8 to 448 ou/m3 for digestate dewatering. The conclusions drawn from the literature review indicate both the difficulties and benefits that can be expected with the change in the operation of MWBPs because of the implementation of CE principles. [ABSTRACT FROM AUTHOR]

High anthropogenic activities are constantly causing increased soil degradation and thus soil health and safety are becoming an important issue. The soil quality is deteriorating at an alarming rate in the neighborhood of smelters as a result of heavy metal deposition. Organic biowastes, also produced through anthropogenic activities, provide some solutions for remediation and management of degraded soils through their use as a substrate. Biowastes, due to their high content of organic compounds, have the potential to improve soil quality, plant productivity, and microbial activity contributing to higher humus production. Biowaste use also leads to the immobilization and stabilization of heavy metals, carbon sequestration, and release of macro and micronutrients. Increased carbon sequestration through biowaste use helps us in mitigating climate change and global warming. Soil amendment by biowaste increases soil activity and plant productivity caused by stimulation in shoot and root length, biomass production, grain yield, chlorophyll content, and decrease in oxidative stress. However, biowaste application to soils is a debatable issue due to their possible negative effect of high heavy metal concentration and risks of their accumulation in soils. Therefore, regulations for the use of biowastes as fertilizer or soil amendment must be improved and strictly employed to avoid environmental risks and the entry of potentially toxic elements into the food chain. In this review, we summarize the current knowledge on the effects of biowastes on soil remediation, plant productivity, and soil organic carbon sequestration. [ABSTRACT FROM AUTHOR]

Knowledge of kinetic parameters of CO production during biowaste composting is significantly important for the prediction of its course and estimation of total gas quantity. This allows increasing the control of the process, to minimize its negative impact on the environment and to protect the occupational safety of employees exposed to CO in the biowaste composting plant. For the first time, a full study of the influence of temperature and biowaste sterilization on the kinetics of CO production is presented. The lab-scale experiments used a mixture of green waste, dairy cattle manure, and sawdust in two variants: sterilized and non-sterilized samples. The process was carried out in controlled temperature reactors with measuring the concentrations of CO, O2, and CO2 every 12 h.CO production and k value increased with temperature. However, higher CO production was observed in biotic conditions between 10~50 °C, suggesting the biotic CO formation and 1st-order kinetics. The abiotic (thermochemical) process was more efficiently generating CO above 50 °C, described with a 0-order kinetic model. Additionally, the rate constant (k) value of CO production under biotic conditions was increasing up to a temperature of 60 °C, above which a slight decrease in CO production rate was observed at 70 °C. The presented results are the basis for further studies focused on the feasibility of (1) the mitigation and (2) valorization of CO production during the biowaste biostabilization are warranted. [ABSTRACT FROM AUTHOR]

The effluents of the sugar and bio-ethanol industry, mainly vinasse as well as lignocellulosic waste, are produced in high volumes. Therefore, their treatment and valorization would reduce the environmental impact and make this industry more productive and competitive. The purpose of this study was to determine the potential use of press mud (lignocellulosic waste), vinasse powder, and vinasse sludge from an extraction process with ethanol, as raw materials for conventional pyrolysis evaluating the physicochemical characteristics that affect this thermochemical process, such as calorific power, density, ash content, volatile material, moisture and nitrogen, sulfur, carbon and hydrogen content, thermogravimetric profile, and quantification of lignin cellulose and hemicellulose. The batch pyrolysis experiments showed that all three wastes could be converted successfully into more valuable products. The powder vinasse led to the formation of the lowest content of bio-char (42.7%), the highest production of volatiles (61.6 wt.%), and the lowest ash content (20.5 wt.%). Besides, it showed the high heating value of 15.63 MJ/kg. Meanwhile, the extraction sludge presented the highest liquid yield (32%) with the lowest gas formation (18.2 wt.%) and the lowest heating value of 8.57 MJ/kg. Thus, the sludge could be a good feedstock for production of bio-oil and bio-char. [ABSTRACT FROM AUTHOR]

One of the environmental solutions employed in order to achieve circular economy goals is methane fermentation—a technology that is beneficial both for the stabilization and reduction of organic waste and for alternative energy generation. The article presents the results of research aimed at determining the biogas and methane potential of bio-waste which has been pre-thermally disintegrated, and determining the influence of variable process parameters of disintegration on the kinetics of fermentation. A first-order kinetic model was used to describe the fermentation as well as two mathematical models: logistic and Gompertz. It has been found that process parameters such as time (0.5, 1 and 2 h) and temperature (between 55 to 175 °C) have a significant effect on the solubilization efficiency of the bio-waste. The methane fermentation of thermally disintegrated bio-waste showed that the highest biogas potential is characterized by samples treated, respectively, for 0.5 h at 155 °C and for 2 h at 175 °C. The best match for the experimental data of biogas production from disintegrated substrates was demonstrated for the Gompertz model. [ABSTRACT FROM AUTHOR]

Municipal solid waste (MSW) collection is an important issue in the development and management of smart cities, having a significant influence on environmental sustainability. Door-to-door and pneumatic collection are two systems that represent a way of arranging waste collection in city´s historic areas in Spain where conventional street-side container collection is not feasible. Since door-to-door collection generates significant direct greenhouse gas emissions from trucks, pneumatic collection emerges as an alternative to the trucking system. While this technology apparently reduces local direct air emissions, it suffers from a large energy demand derived from vacuum production for waste suction. The introduction of new normative frameworks regarding the selective collection of the biodegradable fraction makes necessary a comprehensive analysis to assess the influence of this fraction collection and its subsequent recycling by anaerobic digestion. As a novelty, this work compares both conventional door-to-door and pneumatic collection systems from a life cycle approach focusing on the biodegradable waste. Results indicate that, in spite of the fact electricity production and consumption have a significant influence on the results, the energy savings from the recycling of the organic fraction are higher than the energy requirements. Therefore, the pneumatic collection could be an environmentally-friendly option for MSW management under a circular economy approach in Spanish city´s historic areas, since wastes could be a material or energy source opportunity. [ABSTRACT FROM AUTHOR]