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This study is focused on the modelling of the production of bio-oil by thermochemical liquefaction. Species Acacia melanoxylon was used as the source of biomass, the standard chemical 2-Ethylhexanol (2-EHEX) was used as solvent, p-Toluenesulfonic acid (pTSA) was used as the catalyst, and acetone was used for the washing process. This procedure consisted of a moderate acid-catalysed liquefaction process and was applied at 3 different temperatures to determine the proper model: 100, 135, and 170 °C, and at 30-, 115-, and 200-min periods with 0.5%, 5.25%, and 10% (m/m) catalyst concentrations of overall mass. Optimized results showed a bio-oil yield of 83.29% and an HHV of 34.31 MJ/kg. A central composite face-centred (CCF) design was applied to the liquefaction reaction optimization. Reaction time, reaction temperature, as well as catalyst concentration, were chosen as independent variables. The resulting model exhibited very good results, with a highly adjusted R-squared (1.000). The liquefied products and biochar samples were characterized by Fourier-transformed infrared (FTIR) and thermogravimetric analysis (TGA); scanning electron microscopy (SEM) was also performed. The results show that invasive species such as acacia may have very good potential to generate biofuels and utilize lignocellulosic biomass in different ways. Additionally, using acacia as feedstock for bio-oil liquefaction will allow the valorisation of woody biomass and prevent forest fires as well. Besides, this process may provide a chance to control the invasive species in the forests, reduce the effect of forest fires, and produce bio-oil as a renewable energy.

A two-trough parabolic-shaped concentrating photovoltaic solar collector with a vertical half-size ‘phosphorus-passivated emitter rear totally diffused’ bifacial cell string receiver was designed and built for household applications, with the aim of smooth the electrical ‘duck curve’. The study consisted in testing the concentrating photovoltaic solar collector outdoors, under real weather conditions, for its daily electrical peak power and efficiency, as well as for its electrical transversal and longitudinal Incidence Angle Modifier direction. The outdoor testing measurements were conducted in a parabolic trough with low concentration coupled with a central vertical half-size ‘phosphorus-passivated emitter rear totally diffused’ bifacial cell string receiver. Furthermore, the electrical transversal Incidence Angle Modifier showed to be very delicate due to the position and outline of the receiver, which led to an electrical peak efficiency close to 10% at ±25° (i.e., for an electrical power output of around 49.3 W/m2). To validate the measured parameters, a ray-tracing software has been used, where the measured Incidence Angle Modifiers have a very good agreement with the simulated Incidence Angle Modifiers (e.g., deviation of

The Clean Forest project aims to valorize forest biomass wastes (and then prevent their occurrence as a fuel source in forests), converting it to bioenergy, such as the production of 2nd generation synthetic biofuels, like bio-methanol, bio-DME, and biogas, depending on the process operating conditions. Valorization of potential forest waste biomass thus enhances the reduction of the probability of occurrence of forest fires and, therefore, presents a major value for local rural communities. The proposed process is easy to implement, and energetically, it shows significantly reduced costs than the conventional process of gasification. Additionally, the input of energy necessary to promote electrolysis can be achieved with solar energy, using photovoltaic panels. This paper refers to the actual progress of the project, as well as the further steps which consist of a set of measures aimed at the minimization of the occurrence of forest fires by the valorization of forest wastes into energy sources.

In an era where sustainability is becoming the main driving force for research and development, supercritical fluids-based techniques are presented as a very efficient alternative technology to conventional extraction, purification, and recrystallization processes. Supercritical antisolvent (SAS) precipitation is a novel technique that can replace liquid antisolvent precipitation techniques. Additionally, through the optimization of precipitation operating conditions, morphology, particle size, and particle size distribution of nanoparticles can be controlled. As an antisolvent, supercritical carbon dioxide (scCO2) is far more sustainable than its conventional liquid counterparts; not only does it have a critical point (304 K and 73.8 bar) on its phase diagram that allows for the precipitation processes to be developed so close to room temperature, but also its recovery and, consequently, the precipitated solute purification stage is considerably simpler. This technique can be used efficiently for preparing nanocatalysts to be used in biodiesel production processes.

Photovoltaics (PV) and Solar Thermal (ST) collectors are sometimes competitors, as investment capacity, energy demand, and roof space are limited. Therefore, a ratio that quantifies the difference in annual energy output between ST and PV for different locations is useful. A market survey assessing the average price and performance both in 2013 and 2021 was conducted, showing a factor of 3 cell price decrease combined with a 20% efficiency increase, while ST showed negligible variation. Winsun simulations were conducted, and the results were plotted on the world map. Despite variations due to local climate, the ratio of energy production (ST/PV) increases at lower latitudes mainly due to (a) higher air temperature increasing ST output but decreasing the PV output; (b) solar radiation reducing ST efficiency to zero while having a minor impact on PV efficiency. The ratio was calculated for several ST operating temperatures. For latitudes lower than 66°, the ratio of a flat plate at 50 °C to a PV module ranges from 1.85 to 4.46, while the ratio between a vacuum tube at 50 °C and a PV module ranges from 3.05 to 4.76. This ratio can support the decision between installing ST or PV while combining different factors such as energy value, system complexity, and installation cost.

The continuous increase of the world’s population results in an increased demand for energy drastically from the industrial and domestic sectors as well. Moreover, the current public awareness regarding issues such as pollution and overuse of petroleum fuel has resulted in the development of research approaches concerning alternative renewable energy sources. Amongst the various options for renewable energies used in transportation systems, biodiesel is considered the most suitable replacement for fossil-based diesel. In what concerns the industrial application for biodiesel production, homogeneous catalysts such as sodium hydroxide, potassium hydroxide, sulfuric acid, and hydrochloric acid are usually selected, but their removal after reaction could prove to be rather complex and sometimes polluting, resulting in increases on the production costs. Therefore, there is an open field for research on new catalysts regarding biodiesel production, which can comprise heterogeneous catalysts. Apart from that, there are other alternatives to these chemical catalysts. Enzymatic catalysts have also been used in biodiesel production by employing lipases as biocatalysts. For economic reasons, and reusability and recycling, the lipases urged to be immobilized on suitable supports, thus the concept of heterogeneous biocatalysis comes in existence. Just like other heterogeneous catalytic materials, this one also presents similar issues with inefficiency and mass-transfer limitations. A solution to overcome the said limitations can be to consider the use of nanostructures to support enzyme immobilization, thus obtaining new heterogeneous biocatalysts. This review mainly focuses on the application of enzymatic catalysts as well as nano(bio)catalysts in transesterification reaction and their multiple methods of synthesis.

Photovoltaic (PV) panels and thermal collectors are commonly known as mature technologies to capture solar energy. The efficiency of PV cells decreases as operating cell temperature increases. Photovoltaic Thermal Collectors (PVT) offer a way to mitigate this performance reduction by coupling solar cells with a thermal absorber that can actively remove the excess heat from the solar cells to the Heat Transfer Fluid (HTF). In order for PVT collectors to effectively counter the negative effects of increased operating cell temperature, it is fundamental to have an adequate heat transfer from the cells to the HTF. This paper analyzes the operating temperature of the cells in a low concentrating PVT solar collector, by means of both experimental and Computational Fluid Dynamics (CFD) simulation results on the Solarus asymmetric Compound Parabolic Concentrator (CPC) PowerCollector (PC). The PC solar collector features a Compound Parabolic Concentrator (CPC) reflector geometry called the Maximum Reflector Concentration (MaReCo) geometry. This collector is suited for applications such as Domestic Hot Water (DHW). An experimental setup was installed in the outdoor testing laboratory at Gävle University (Sweden) with the ability to measure ambient, cell and HTF temperature, flow rate and solar radiation. The experimental results were validated by means of an in-house developed CFD model. Based on the validated model, the effect of collector tilt angle, HTF, insulation (on the back side of the reflector), receiver material and front glass on the collector performance were considered. The impact of tilt angle is more pronounced on the thermal production than the electrical one. Furthermore, the HTF recirculation with an average temperature of 35.1 °C and 2.2 L/min flow rate showed that the electrical yield can increase by 25%. On the other hand, by using insulation, the thermal yield increases up to 3% when working at a temperature of 23 °C above ambient.

Energy security and environmental concerns, related to the increasing carbon emissions, have prompted in the last years the search for renewable and sustainable fuels. Biodiesel, a mixture of fatty acids alkyl esters shows properties, which make it a feasible substitute for fossil diesel. Biodiesel can be produced using different processes and different raw materials. The most common, first generation, biodiesel is produced by methanolysis of vegetable oils using basic or acid homogeneous catalysts. The use of vegetable oils for biodiesel production raises serious questions about biodiesel sustainability. Used cooking oils and animal fats can replace the vegetable oils in biodiesel production thus allowing to produce a more sustainable biofuel. Moreover, methanol can be replaced by ethanol being totally renewable since it can be produced by biomass fermentation. The substitution of homogeneous catalyzed processes, nowadays used in the biodiesel industry, by heterogeneous ones can contribute to improve the biodiesel sustainability with simultaneous cost reduction. From the existing literature on biodiesel production, it stands out that several strategies can be adopted to improve the sustainability of biodiesel. A literature review is presented to underline the strategies allowing to improve the biodiesel sustainability.

Concentrating Photovoltaic Thermal (C-PVT) solar collectors produce both thermal and electric power from the same area while concentrating sunlight. This paper studies a C-PVT design where strings of series-connected solar cells are encapsulated with silicone in an aluminium receiver, inside of which the heat transfer fluid flows, and presents an evaluation on structural integrity and performance, after reaching stagnation temperatures. Eight test receivers were made, in which the following properties were varied: Size of the PV cells, type of silicone used to encapsulate the cells, existence of a strain relief between the cells, size of the gap between cells, and type of cell soldering (line or point). The test receivers were placed eight times in an oven for one hour at eight different monitored temperatures. The temperature of the last round was set at 220 °C, which exceeds the highest temperature the panel design reaches. Before and after each round in the oven, the following tests were conducted to the receivers: Electroluminescence (EL) test, IV-curve tracing, diode function, and visual inspection. The test results showed that the receivers made with the transparent silicone and strain relief between cells experienced less microcracks and lower power degradation. No prototype test receiver lost more than 30% of its initial power, despite some receivers displaying a large number of cell cracks. The transparent and more elastic silicone is better at protecting the solar cells from the mechanical stress of thermal expansion than the compared silicone alternative, which was stiffer. As expected, larger cells are more prone to develop microcracks after exposure to thermal stress. Additionally, existing microcracks tend to grow in size relatively fast under thermal stress. EL imaging taken during our experiment leads us to conclude that it is far more likely for existing cracks to expand than for new cracks to appear.

Solar concentrator photovoltaic collectors are able to deliver energy at higher temperatures for the same irradiances, since they are related to smaller areas for which heat losses occur. However, to ensure the system reliability, adequate collector geometry and appropriate choice of the materials used in these systems will be crucial. The present work focuses on the re-design of the Concentrating Photovoltaic system (C-PV) collector reflector presently manufactured by the company Solarus, together with an analysis based on the annual assessment of the solar irradiance in the collector. An open-source ray tracing code (Soltrace) is used to accomplish the modelling of optical systems in concentrating solar power applications. Symmetric parabolic reflector configurations are seen to improve the PV system performance when compared to the conventional structures currently used by Solarus. The parabolic geometries, using either symmetrically or asymmetrically placed receivers inside the collector, accomplished both the performance and cost-effectiveness goals: for almost the same area or costs, the new proposals for the PV system may be in some cases 70% more effective as far as energy output is concerned.