1. Ethylenediaminetetraacetic acid mediated synthesis of palladium nanowire networks and their enhanced electrocatalytic performance for the hydrazine oxidation reaction
- Author
-
Yigang Ji, Shiman Wang, Shu-Ni Li, Fumin Li, and Yu Chen
- Subjects
General Chemical Engineering ,Inorganic chemistry ,chemistry.chemical_element ,Ethylenediaminetetraacetic acid ,Chronoamperometry ,engineering.material ,Electrocatalyst ,Combinatorial chemistry ,Catalysis ,Dielectric spectroscopy ,chemistry.chemical_compound ,chemistry ,Electrochemistry ,engineering ,Noble metal ,Cyclic voltammetry ,Palladium - Abstract
Noble metal network nanostructures with three-dimensionally (3D) interconnected architectures are attracting much attention because of their unique catalytic, electrical, and optical properties. In this work, we report a facile ethylenediaminetetraacetic acid (EDTA) mediated chemical reduction route for the synthesis of high-quality palladium (Pd) nanowire networks (Pd-NWNWs). During the synthesis, EDTA interacts with PdCl2 to generate EDTA-PdII complex, which efficiently decreases the reduction potential of PdII precursor. The slow reduction rate is crucial for the generation of Pd nanowires. The morphology, composition, and structure of Pd-NWNWs are fully investigated by various physical characterizations. The electrocatalytic activity of Pd-NWNWs for the hydrazine oxidation reaction (HOR) is also studied by cyclic voltammetry, electrochemical impedance spectroscopy, and chronoamperometry, etc. Compared to commercial Pd black, Pd-NWNWs exhibit remarkably improved electrocatalytic activity and stability for the HOR.
- Published
- 2015
- Full Text
- View/download PDF